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Dichlorotriphenyl bismuth

Product Name
Dichlorotriphenyl bismuth
CAS No.
594-30-9
Chemical Name
Dichlorotriphenyl bismuth
Synonyms
triphenylbismuth(2+);DICHLOROTRIPHENYLBISMUTH;Triphenyldichlorobismuth;Triphenyldichlorobismuthine;Triphenyldichlorobismuth(V);Dichlorotriphenylbismuthine;Dichlorotriphenylbismuth(V);TRIPHENYLBISMUTH DICHLORIDE;TTIPHENYLBISMUTH DICHLORIDE;Triphenylbismuthine dichloride
CBNumber
CB4214582
Molecular Formula
C18H15BiCl2
Formula Weight
511.2
MOL File
594-30-9.mol
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Dichlorotriphenyl bismuth Property

Melting point:
128-142°C
storage temp. 
Refrigerator
solubility 
soluble in Tetrahydrofuran
form 
powder to crystal
color 
White to Almost white
EPA Substance Registry System
Triphenylbismuthine dichloride (594-30-9)
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Safety

Hazard Codes 
Xi
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36/37/39
HS Code 
2931.90.6000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TCI Chemical
Product number
T1837
Product name
Triphenylbismuth Dichloride
Purity
>98.0%(T)
Packaging
5g
Price
$239
Updated
2025/07/31
Usbiological
Product number
291662
Product name
Triphenylbismuth Dichloride
Packaging
1g
Price
$312
Updated
2021/12/16
Chem-Impex
Product number
40587
Product name
Triphenylbismuthdichloride,98%(Assaybytitration)
Purity
98%(Assaybytitration)
Packaging
5G
Price
$252
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0008362
Product name
TRIPHENYLBISMUTH DICHLORIDE
Purity
95.00%
Packaging
5G
Price
$281.72
Updated
2021/12/16
AK Scientific
Product number
R192
Product name
Triphenylbismuth Dichloride
Packaging
5g
Price
$356
Updated
2021/12/16
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Dichlorotriphenyl bismuth Chemical Properties,Usage,Production

Uses

Dichlorotriphenyl bismuth is used for phenylation of phenols, ketones and enols, and nitro compounds.

Preparation

Dichlorotriphenyl bismuth is easily prepared by oxidation of Triphenylbismuthine either by bubbling Chlorine gas into an ethereal solution of Ph3Bi at 0°C, or by addition of 1 equiv of Sulfuryl Chloride to a solution of Ph3Bi in CH2Cl2 at -78°C. The action of Phenyllithium on Ph3BiCl2 leads to pentaphenylbismuth (mp 77-78 °C). Addition of 1 equiv of a carboxylic or sulfonic acid to Ph5Bi affords compounds of the type Ph4BiX.(Ph4BiOCOCF3: mp 120-132 °C; Ph4BiOTs: mp 155-162 °C).

Definition

ChEBI: Dichloro(triphenyl)bismuthorane is an organobismuth compound. It derives from a hydride of a bismuthorane.

storage

Dichlorotriphenyl bismuth is a stable white solid; can be stored in the refrigerator in the absence of moisture.

Dichlorotriphenyl bismuth Preparation Products And Raw materials

Raw materials

Preparation Products

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Dichlorotriphenyl bismuth Suppliers

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J & K SCIENTIFIC LTD.
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View Lastest Price from Dichlorotriphenyl bismuth manufacturers

Career Henan Chemical Co
Product
Dichlorotriphenyl bismuth 594-30-9
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2020-02-18

594-30-9, Dichlorotriphenyl bismuthRelated Search:

Bismuth Cobalt chloride 2,3,5-Triphenyltetrazolium chloride Bismuth trioxide DICHLOROTRIPHENYLPHOSPHORANE Chlorodiphenylphosphine Triphenylphosphine Bismuth trichloride Triphenylbismuth Difluoride TRIPHENYLBISMUTH CARBONATE BIS(ACETATO-O)TRIPHENYLBISMUTH Benzyltriphenylphosphonium chloride Triphenylbismuth BISMUTH TRIMETHYL DICHLORO(TRI-O-TOLYL)BISMUTH DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH DICHLOROTRIS(4-TRIFLUOROMETHYLPHENYL)BISMUTH Dichlorotriphenyl bismuth

  • DICHLOROTRIPHENYLBISMUTH
  • TRIPHENYLBISMUTH(V) DICHLORIDE
  • TTIPHENYLBISMUTH DICHLORIDE
  • TRIPHENYLBISMUTH DICHLORIDE
  • Triphenylbismuthine dichloride
  • dichloro(triphenyl)bismuthorane
  • Dichlorotriphenylbismuth(V)
  • Dichlorotriphenylbismuthine
  • Triphenyldichlorobismuth
  • Triphenyldichlorobismuth(V)
  • Triphenyldichlorobismuthine
  • triphenylbismuth(2+)
  • Bismuth,dichlorotriphenyl-,cas:594-30-9
  • 594-30-9
  • C6H53BiCl2
  • C18H15BiCl2
  • Classes of Metal Compounds
  • Bi (Bismuth) Compounds
  • Semimetal Compounds
  • Hypervalent Bismuth Compounds
  • Semimetal Compounds
  • Synthetic Organic Chemistry
  • Bi (Bismuth) Compounds
  • Classes of Metal Compounds
  • Hypervalent Bismuth Compounds