ChemicalBook > CAS DataBase List > Triphenylbismuth

Triphenylbismuth

Product Name: Triphenylbismuth
CAS No.: 603-33-8
Chemical Name: Triphenylbismuth
Synonyms: TPB;Aerotex;(C6H5)3Bi;Trifenylbismutin;TRIPHENYLBISMUTH;BISMUTH TRIPHENYL;triphenyl-bismuthin;TRIPHENYLBISMUTHINE;Triphenylbismuth,99%;Triphenylbismuth,98%
CBNumber: CB7478628
Molecular Formula: C18H15Bi
Formula Weight: 440.29
MOL File: 603-33-8.mol

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Triphenylbismuth Property

Melting point:: 78-80 °C
Boiling point:: 310°C
Density: 1,585 g/cm³
refractive index: 1.7040
Flash point:: 242°C/14mm
storage temp.: Inert atmosphere,Room Temperature
solubility: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form: crystal
color: white
Specific Gravity: 1.585
Water Solubility: insoluble
Sensitive: Moisture Sensitive
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
CAS DataBase Reference: 603-33-8(CAS DataBase Reference)
NIST Chemistry Reference: Bismuthine, triphenyl-(603-33-8)
EPA Substance Registry System: Triphenylbismuth (603-33-8)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22
Safety Statements: 24/25-36/37
WGK Germany: 3
RTECS: EB2980000
TSCA: Yes
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P330Rinse mouth.

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 93-8350
Product name: Triphenylbismuth, 99%
Packaging: 10g
Price: $96
Updated: 2024/03/01

Strem Chemicals

Product number: 93-8350
Product name: Triphenylbismuth, 99%
Packaging: 50g
Price: $432
Updated: 2024/03/01

TRC

Product number: T895953
Product name: Triphenylbismuth
Packaging: 2.5g
Price: $85
Updated: 2021/12/16

Matrix Scientific

Product number: 099616
Product name: Triphenylbismuthine
Purity: 95+%
Packaging: 5g
Price: $30
Updated: 2021/12/16

Matrix Scientific

Product number: 099616
Product name: Triphenylbismuthine
Purity: 95+%
Packaging: 10g
Price: $42
Updated: 2021/12/16

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Triphenylbismuth Chemical Properties,Usage,Production

Chemical Properties

white to off-white crystalline powder

Uses

Triphenylbismuth, as an volatile organometallic used in the preparation of thin films of superconducting oxides by CVD. It is also added to the fuel of rocket as cruing agent. It acts as a solidifying catalyst for butyl hydroxyl propellants.

Preparation

Triphenylbismuth is conveniently prepared by reaction of Phenylmagnesium Bromide with BiCl3 in ether.

storage

It ?must be stored in dark bottles in the absence of moisture or acidic vapors. Use in a fume hood.

Purification Methods

Dissolve it in EtOH, precipitate it with H2O, extract with Et2O, dry and evaporate till the residue crystallises. It has been recrystallised from EtOH and Et2O/EtOH and is a stable compound. [Forward et al. J Chem Soc suppl p121 1949, Pfeiffer et al. Chem Ber 37 4620 1904, Gilman & Yablunky J Am Chem Soc 62 665 1940, UV: Jaffé J Chem Phys 22 1430 1954, Beilstein 4 III 1841.]

Triphenylbismuth Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Triphenylbismuth manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Triphenylbismuth 603-33-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-08

Henan Aochuang Chemical Co.,Ltd.

Product: Triphenylbismuth 603-33-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-30

Hebei Yanxi Chemical Co., Ltd.

Product: Triphenylbismuth 603-33-8
Price: US $0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 20tons
Release date: 2023-10-09

603-33-8, TriphenylbismuthRelated Search:

Triphenylphosphine (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Triphenyltin acetate Lactulose Triphenylmethyl Chloride Triphenylantimony 2,3,5-Triphenyltetrazolium chloride TRIPHENYLBORANE Trityl olmesartan DICHLORO(TRI-O-TOLYL)BISMUTH TRI-P-TOLYLBISMUTHINE BIS(ACETATO-O)TRIPHENYLBISMUTH Tetrachloro-o-benzoquinone TRIPHENYLBISMUTH(V) DICHLORIDE,TRIPHENYLBISMUTH DICHLORIDE Bismuth Triphenylbismuth TRIS(4-ETHOXYPHENYL)BISMUTH TRIS(2-METHOXYPHENYL)BISMUTHINE

BISMUTH TRIPHENYL

Triphenylbismuth,99%

Bismuthine, triphenyl-

TRIPHENYLBISMUTH

TRIPHENYLBISMUTHINE

TPB

(C6H5)3Bi

Aerotex

Trifenylbismutin

triphenyl-bismuthin

TRIPHENYLBISMUTH(III) 99%

TRIPHENYL BISMUTH ANHYDROUS

Tri(phenyl)bismuthane

Triphenylbismuth,98%

Triphenylbismuthine &gt

Triphenylbismuth ISO 9001：2015 REACH

1,1',1''-Methanetriyltris(1H-benzotriazole)

Triphenylbismuth 98%

603-33-8

BiC6H53

C18H15Bi

Furans

Organometallics

organobismuth compound

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