4'-Hydroxy-3'-methoxypropiophenone

ChemicalBook > CAS DataBase List > 4'-Hydroxy-3'-methoxypropiophenone

4'-Hydroxy-3'-methoxypropiophenone

Product Name: 4'-Hydroxy-3'-methoxypropiophenone
CAS No.: 1835-14-9
Chemical Name: 4'-Hydroxy-3'-methoxypropiophenone
Synonyms: Propioguaiacone;PROPIOVANILLONE;Eugenol Impurity 21;4-HYDROXY-3-METHOXYPROPIOPHENONE;3-METHOXY-4-HYDROXYPROPIOPHENONE;4'-hydroxy-3'-methoxypropiophenone;Propiophenone, 4'-hydroxy-3'-methoxy;1-(4-hydroxy-3-methoxyphenyl)-1-propanone;1-Propanone, 1-(4-hydroxy-3-methoxyphenyl)-;1-(4-HYDROXY-3-METHOXY-PHENYL)-PROPAN-1-ONE
CBNumber: CB3205110
Molecular Formula: C10H12O3
Formula Weight: 180.2
MOL File: 1835-14-9.mol

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4'-Hydroxy-3'-methoxypropiophenone Property

Melting point:: 61-62 °C
Boiling point:: 180-185 °C(Press: 15 Torr)
Density: 1.126±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
solubility: DMSO (Slightly), Methanol (Slightly)
form: Solid
pka: 8.92±0.31(Predicted)
color: White to Dark Beige
LogP: 2.020 (est)
CAS DataBase Reference: 1835-14-9(CAS DataBase Reference)
NIST Chemistry Reference: 1-(4-hydroxy-3-methoxyphenyl)propanone(1835-14-9)
EPA Substance Registry System: 1-Propanone, 1-(4-hydroxy-3-methoxyphenyl)- (1835-14-9)

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Safety

Hazard Codes: T,N
Risk Statements: 25-51/53
Safety Statements: 45-61
HS Code: 2914500090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: H947600
Product name: 1-(4-Hydroxy-3-methoxyphenyl)-1-propanone
Packaging: 50mg
Price: $185
Updated: 2021/12/16

Matrix Scientific

Product number: 126754
Product name: 1-(4-Hydroxy-3-methoxyphenyl)propan-1-one
Purity: >95%
Packaging: 1g
Price: $252
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: APN0000263
Product name: 4-HYDROXY-3-METHOXYPROPIOPHENONE
Purity: 95.00%
Packaging: 1G
Price: $278.25
Updated: 2021/12/16

AK Scientific

Product number: Q284
Product name: 3-Methoxy-4-hydroxypropiophenone
Packaging: 250mg
Price: $118
Updated: 2021/12/16

Medical Isotopes, Inc.

Product number: 95813
Product name: 1-(4-Hydroxy-3-methoxyphenyl)-1-propanone
Packaging: 10mg
Price: $450
Updated: 2021/12/16

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4'-Hydroxy-3'-methoxypropiophenone Chemical Properties,Usage,Production

Uses

1-(4-Hydroxy-3-methoxyphenyl)-1-propanone is a derivative of Guaiacol, a precursor to various flavorants, such as eugenol and vanillin.

Preparation

Preparation by Fries rearrangement of 2-methoxyphenyl propionate, (b.p.20 140–143°)
with aluminium chloride in nitrobenzene, first at 60–80° for 1 h, then at r.t. overnight, at 60° for 1 h or at 50° for 5 h (44%) ;
with aluminium chloride (2 mol) in nitromethane at r.t. for 24 h (65%)
with aluminium chloride in carbon disulfide
with titanium tetrachloride (2 mol) in nitromethane at r.t. for 24 h (62%)
with stannic chloride (2 mol) in nitromethane at r.t. for 24 h (69%)
with antimony pentachloride (2 mol) in nitromethane at r.t. for 24 h (28%) with formation of important tars.

Synthesis Reference(s)

The Journal of Organic Chemistry, 15, p. 227, 1950 DOI: 10.1021/jo01148a001

4'-Hydroxy-3'-methoxypropiophenone Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4'-Hydroxy-3'-methoxypropiophenone manufacturers

Career Henan Chemical Co

Product: 4'-Hydroxy-3'-methoxypropiophenone 1835-14-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kg
Release date: 2019-08-29

1835-14-9, 4'-Hydroxy-3'-methoxypropiophenoneRelated Search:

CHLOROPHOSPHONAZO III Citric acid monohydrate 1-Bromo-1-phenyl-2-propanone 2-CHLORO-3' 4'-DIMETHOXYBENZIL 97 CINOXACIN Ethyl 3,4,5-trimethoxybenzoylacetate CI 15511 Propiophenone 5,6-Dimethoxy-1-indanone 3′,4′-(Methylenedioxy)propiophenone 4',6,7-Trimethoxyisoflavone Glycitein Cryptopine 4-(3,4-DIMETHOXYPHENYL)-4-OXOBUTYRIC ACID Oxolinic acid Methoxypropiophenone 4'-Hydroxypropiophenone Protopine

3-METHOXY-4-HYDROXYPROPIOPHENONE

4-HYDROXY-3-METHOXYPROPIOPHENONE

PROPIOVANILLONE

1-(4-Hydroxy-3-methoxyphenyl)-1-propanone (propiovanillone)

Propioguaiacone

Propiophenone, 4'-hydroxy-3'-methoxy

1-(4-hydroxy-3-methoxyphenyl)-1-propanone

1-(4-HYDROXY-3-METHOXY-PHENYL)-PROPAN-1-ONE

Eugenol Impurity 21

1-Propanone, 1-(4-hydroxy-3-methoxyphenyl)-

4'-hydroxy-3'-methoxypropiophenone

1835-14-9

Aromatic Propiophenones (substituted)