methyl 3-bromopicolinate
- Product Name
- methyl 3-bromopicolinate
- CAS No.
- 53636-56-9
- Chemical Name
- methyl 3-bromopicolinate
- Synonyms
- methyl 3-bromopicolinate;Methyl 3-broMopyridine-2-carboxylate;Methyl 3-bromo-2-pyridinecarboxylate;3-Bromopyridine-2-carboxylic acid methy ester;3-Bromopyridine-2-carboxylic acid methyl ester;3-Bromo-2-pyridinecarboxylic acid methyl ester;2-Pyridinecarboxylic acid, 3-bromo-, methyl ester;Methyl 3-bromopicolinate, 3-Bromo-2-(methoxycarbonyl)pyridine
- CBNumber
- CB32106158
- Molecular Formula
- C7H6BrNO2
- Formula Weight
- 216.03
- MOL File
- 53636-56-9.mol
methyl 3-bromopicolinate Property
- Boiling point:
- 267.4±20.0 °C(Predicted)
- Density
- 1.579±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,2-8°C
- pka
- -0.91±0.10(Predicted)
- form
- solid
- color
- Pale yellow
- InChI
- InChI=1S/C7H6BrNO2/c1-11-7(10)6-5(8)3-2-4-9-6/h2-4H,1H3
- InChIKey
- GSTYLUGZSCVBTJ-UHFFFAOYSA-N
- SMILES
- C1(C(OC)=O)=NC=CC=C1Br
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M296035
- Product name
- Methyl3-bromopicolinate
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 4H23-9-W0
- Product name
- Methyl 3-bromopyridine-2-carboxylate
- Packaging
- 1g
- Price
- $77
- Updated
- 2021/12/16
- Product number
- 048299
- Product name
- Methyl 3-bromo-2-pyridinecarboxylate
- Purity
- 97%
- Packaging
- 5g
- Price
- $78
- Updated
- 2021/12/16
- Product number
- OR16874
- Product name
- Methyl3-bromopyridine-2-carboxylate
- Packaging
- 1g
- Price
- $15
- Updated
- 2021/12/16
- Product number
- 048299
- Product name
- Methyl 3-bromo-2-pyridinecarboxylate
- Purity
- 97%
- Packaging
- 1g
- Price
- $20
- Updated
- 2021/12/16
methyl 3-bromopicolinate Chemical Properties,Usage,Production
Synthesis
30683-23-9
53636-56-9
a) To a methanolic solution of 3-bromo-2-pyridinecarboxylic acid (1 g, 4.9 mmol), a few drops of concentrated sulfuric acid were slowly added as a catalyst at room temperature. The reaction mixture was stirred at room temperature for 12 hours to ensure complete reaction. Upon completion of the reaction, methanol was removed by rotary evaporation to give the crude product. The crude product was purified by a CombiFlash fast chromatography system on a silica gel column with the eluent being a hexane solution of 20-50% ethyl acetate, resulting in methyl 3-bromopyridinecarboxylate (450 mg, 41% yield). Subsequently, compound 17 (82% yield) was synthesized in a series of reaction steps according to the method described in Example 1 using methyl 3-bromopyridinecarboxylate as starting material, and compound 4 was finally prepared.
References
[1] Patent: US2011/136833, 2011, A1. Location in patent: Page/Page column 27
[2] Journal of Medicinal Chemistry, 2011, vol. 54, # 2, p. 635 - 654
[3] Patent: US3963733, 1976, A
methyl 3-bromopicolinate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from methyl 3-bromopicolinate manufacturers
- Product
- methyl 3-bromopicolinate 53636-56-9
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-05-30
- Product
- methyl 3-bromopicolinate 53636-56-9
- Price
- US $5.00-0.10/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-08
- Product
- methyl 3-bromopicolinate 53636-56-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2019-05-25