ChemicalBook > CAS DataBase List > Methyl 3-bromobenzoate

Methyl 3-bromobenzoate

Product Name
Methyl 3-bromobenzoate
CAS No.
618-89-3
Chemical Name
Methyl 3-bromobenzoate
Synonyms
RARECHEM AL BF 0052;3-Bromobenzoate Methyl;METHYL M-BROMOBENZOATE;METHYL 3-BROMOBENZOATE;Methyl-3-Bromobenzoate 98%;Methyl 3-Bromobenzoate >Methyl 3-bromobenzoate, 98+%;3-bromo-benzoicacimethylester;Methyl 3-broMobenzoate, 98% 5GR;m-Bromobenzoic acid methyl ester
CBNumber
CB4345734
Molecular Formula
C8H7BrO2
Formula Weight
215.04
MOL File
618-89-3.mol
More
Less

Methyl 3-bromobenzoate Property

Melting point:
31-33 °C(lit.)
Boiling point:
127-128 °C15 mm Hg(lit.)
Density 
1.5313 (rough estimate)
refractive index 
1.5575
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Crystalline Solid or Liquid
color 
White to light yellow
Water Solubility 
Slightly soluble in water.
BRN 
1940810
InChIKey
KMFJVYMFCAIRAN-UHFFFAOYSA-N
CAS DataBase Reference
618-89-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzoic acid, 3-bromo-, methyl ester(618-89-3)
EPA Substance Registry System
Benzoic acid, 3-bromo-, methyl ester (618-89-3)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-24/25
WGK Germany 
3
TSCA 
Yes
HS Code 
29163990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
499625
Product name
Methyl 3-bromobenzoate
Purity
98%
Packaging
5g
Price
$40.6
Updated
2024/03/01
Sigma-Aldrich
Product number
499625
Product name
Methyl 3-bromobenzoate
Purity
98%
Packaging
25g
Price
$65
Updated
2024/03/01
TCI Chemical
Product number
B0554
Product name
Methyl 3-Bromobenzoate
Purity
>99.0%(GC)
Packaging
5g
Price
$33
Updated
2024/03/01
TCI Chemical
Product number
B0554
Product name
Methyl 3-Bromobenzoate
Purity
>99.0%(GC)
Packaging
25g
Price
$85
Updated
2024/03/01
Alfa Aesar
Product number
A16174
Product name
Methyl 3-bromobenzoate, 98+%
Packaging
10g
Price
$56.65
Updated
2024/03/01
More
Less

Methyl 3-bromobenzoate Chemical Properties,Usage,Production

Chemical Properties

Methyl 3-bromobenzoate is white to light yellow low melting crystalline

Uses

Methyl 3-bromobenzoate is an halogenated benzoate derivative used as a reagent in organic synthesis.Methyl 3-bromobenzoate is used in the synthesis of a novel series of tetrahydro dibenzazocine as inhibitors of 17β-hydroxysteroid dehydrogenase type 3.

Uses

Methyl 3-bromobenzoate is used as a reagent in organic synthesis. It is used in the synthesis of tetrahydro dibenzazocine, which acts as an inhibitor of 17beta-hydroxysteroid dehydrogenase type 3. Further, it is used to prepare 3-tert-butylphosphanyl-benzoic acid methyl ester by reacting with tert-butyltrimethylsilylphosphine.

General Description

Methyl 3-bromobenzoate is an aryl bromide. It undergoes stereoconvergent cross-coupling with potassium trifluoro(1-phenylethyl)borate to form 1,1-diarylethane derivative. The Negishi cross-coupling reaction between methyl 3-bromobenzoate and diarylzinc reagents in the presence of a palladium catalyst has been reported. Methyl-3-bromobenzoate can be converted into the corresponding benzonitrile using dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium as a C-C cross-coupling catalyst and K4[Fe(CN)6] as a cyanating agent.

Methyl 3-bromobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Methyl 3-bromobenzoate Suppliers

Chongqing Xingcan Pharmaceutical Technology Co., Ltd.
Tel
15523000485
Email
xingcanyaoye@sina.com
Country
China
ProdList
1686
Advantage
58
Ningbo Zeyu Chemical Technology Co., Ltd
Tel
15066123231 15066123231
Email
2278736577@qq.com
Country
China
ProdList
505
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3576
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2882
Advantage
65
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
Advantage
66
More
Less

View Lastest Price from Methyl 3-bromobenzoate manufacturers

Zibo Hangyu Biotechnology Development Co., Ltd
Product
Methyl 3-bromobenzoate 618-89-3
Price
US $70.00-700.00/kg
Min. Order
10kg
Purity
0.99
Supply Ability
20tons
Release date
2023-11-08
Shanghai Rlavie Technology Co ltd
Product
3-bromobenzoate Methyl 618-89-3
Price
US $0.00-0.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
100kgs/month
Release date
2022-01-03
Career Henan Chemical Co
Product
Methyl 3-bromobenzoate 618-89-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2019-07-02

618-89-3, Methyl 3-bromobenzoateRelated Search:


  • METHYL 3-BROMOBENZOATE FOR SYNTHESIS
  • 3-bromo-benzoicacimethylester
  • Benzoic acid, m-bromo-, methyl ester
  • Benzoicacid,3-bromo-,methylester
  • m-Bromobenzoic acid methyl ester
  • RARECHEM AL BF 0052
  • 3-BROMOBENZOIC ACID METHYL ESTER
  • Methyl 3-bromobenzoate, 98+%
  • Methyl-3-Bromobenzoate 98%
  • Methyl 3-broMobenzoate, 98% 5GR
  • 3-Bromobenzoate Methyl
  • METHYL M-BROMOBENZOATE
  • METHYL 3-BROMOBENZOATE
  • Methyl 3-Bromobenzoate &gt
  • 618-89-3
  • Organic Building Blocks
  • Esters
  • Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Aromatic Esters
  • API intermediates
  • Acids & Esters
  • Bromine Compounds
  • C8 to C9
  • Carbonyl Compounds
  • Esters
  • Acids and Derivatives
  • Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Chemical Synthesis
  • Organic Building Blocks