Methyl 3-bromobenzoate

ChemicalBook > CAS DataBase List > Methyl 3-bromobenzoate

Methyl 3-bromobenzoate

Product Name: Methyl 3-bromobenzoate
CAS No.: 618-89-3
Chemical Name: Methyl 3-bromobenzoate
Synonyms: RARECHEM AL BF 0052;3-Bromobenzoate Methyl;METHYL M-BROMOBENZOATE;METHYL 3-BROMOBENZOATE;Methyl-3-Bromobenzoate 98%;Methyl 3-Bromobenzoate >Methyl 3-bromobenzoate, 98+%;3-bromo-benzoicacimethylester;Methyl 3-broMobenzoate, 98% 5GR;m-Bromobenzoic acid methyl ester
CBNumber: CB4345734
Molecular Formula: C8H7BrO2
Formula Weight: 215.04
MOL File: 618-89-3.mol

Less

Methyl 3-bromobenzoate Property

Melting point:: 31-33 °C(lit.)
Boiling point:: 127-128 °C15 mm Hg(lit.)
Density: 1.5313 (rough estimate)
refractive index: 1.5575
Flash point:: >230 °F
storage temp.: Sealed in dry,Room Temperature
form: Crystalline Solid or Liquid
color: White to light yellow
Water Solubility: Slightly soluble in water.
BRN: 1940810
InChIKey: KMFJVYMFCAIRAN-UHFFFAOYSA-N
CAS DataBase Reference: 618-89-3(CAS DataBase Reference)
NIST Chemistry Reference: Benzoic acid, 3-bromo-, methyl ester(618-89-3)
EPA Substance Registry System: Benzoic acid, 3-bromo-, methyl ester (618-89-3)

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 37/39-26-24/25
WGK Germany: 3
TSCA: Yes
HS Code: 29163990

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 499625
Product name: Methyl 3-bromobenzoate
Purity: 98%
Packaging: 5g
Price: $40.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 499625
Product name: Methyl 3-bromobenzoate
Purity: 98%
Packaging: 25g
Price: $65
Updated: 2024/03/01

TCI Chemical

Product number: B0554
Product name: Methyl 3-Bromobenzoate
Purity: >99.0%(GC)
Packaging: 5g
Price: $33
Updated: 2024/03/01

TCI Chemical

Product number: B0554
Product name: Methyl 3-Bromobenzoate
Purity: >99.0%(GC)
Packaging: 25g
Price: $85
Updated: 2024/03/01

Alfa Aesar

Product number: A16174
Product name: Methyl 3-bromobenzoate, 98+%
Packaging: 10g
Price: $56.65
Updated: 2024/03/01

Less

Methyl 3-bromobenzoate Chemical Properties,Usage,Production

Chemical Properties

Methyl 3-bromobenzoate is white to light yellow low melting crystalline

Uses

Methyl 3-bromobenzoate is an halogenated benzoate derivative used as a reagent in organic synthesis.Methyl 3-bromobenzoate is used in the synthesis of a novel series of tetrahydro dibenzazocine as inhibitors of 17β-hydroxysteroid dehydrogenase type 3.

Uses

Methyl 3-bromobenzoate is used as a reagent in organic synthesis. It is used in the synthesis of tetrahydro dibenzazocine, which acts as an inhibitor of 17beta-hydroxysteroid dehydrogenase type 3. Further, it is used to prepare 3-tert-butylphosphanyl-benzoic acid methyl ester by reacting with tert-butyltrimethylsilylphosphine.

General Description

Methyl 3-bromobenzoate is an aryl bromide. It undergoes stereoconvergent cross-coupling with potassium trifluoro(1-phenylethyl)borate to form 1,1-diarylethane derivative. The Negishi cross-coupling reaction between methyl 3-bromobenzoate and diarylzinc reagents in the presence of a palladium catalyst has been reported. Methyl-3-bromobenzoate can be converted into the corresponding benzonitrile using dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium as a C-C cross-coupling catalyst and K₄[Fe(CN)₆] as a cyanating agent.

Methyl 3-bromobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

Less

Methyl 3-bromobenzoate Suppliers

Americas 1 Belgium 1 Canada 1 China 165 Cyprus 1 Europe 3 France 1 Germany 5 India 26 Japan 3 Slovakia 1 Switzerland 3 United Kingdom 19 United States 35 Global 265

Chongqing Xingcan Pharmaceutical Technology Co., Ltd.

Tel: 15523000485
Email: xingcanyaoye@sina.com
Country: China
ProdList: 1686
Advantage: 58

Ningbo Zeyu Chemical Technology Co., Ltd

Tel: 15066123231 15066123231
Email: 2278736577@qq.com
Country: China
ProdList: 506
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40240
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24539
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44751
Advantage: 61

Shijiazhuang Sdyano Fine Chemical Co., Ltd.

Tel: 0311-89250318 031166536426
Fax: 4000311741
Email: master@sjzsdyn.com
Country: China
ProdList: 2882
Advantage: 65

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18217
Advantage: 66

Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12458
Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9984
Advantage: 60

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11660
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel
Country: China
ProdList: 42982
Advantage: 64

Beijing Isomersyn Technology CO;LTD

Tel: 010-82954736 13391601435
Email: sales@isomersyn.com
Country: China
ProdList: 3296
Advantage: 57

Shandong Xiya Chemical Co., Ltd

Tel: 13355009207 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18739
Advantage: 57

Syntechem Co.,Ltd

Tel
Fax: E-Mail Inquiry
Email: info@syntechem.com
Country: China
ProdList: 12990
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14443
Advantage: 57

Hunan Hui Bai Shi Biotechnology Co., Ltd.

Tel: 0731-85526065 13308475853
Email: ivy@hnhbsj.com
Country: China
ProdList: 4550
Advantage: 62

Chengdu HappySyn Pharmaceutical Technology Co., Ltd.

Tel: 028-85114309 15881143215
Email: liangli@happysyn.com
Country: China
ProdList: 1722
Advantage: 55

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17779
Advantage: 75

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6139
Advantage: 55

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66099280 17798518460
Fax: (1)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 19918
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22519
Advantage: 55

AstaTech (Chengdu) Pharma. Co., Ltd.

Tel: 15928766785 15928766785
Fax: QQ961458712
Email: wupengcheng@astatech.cn
Country: China
ProdList: 1999
Advantage: 55

Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.

Tel: +86-28-85122536 85324413
Fax: +86-28-85326443
Email: market@astatech.cn
Country: China
ProdList: 8033
Advantage: 55

Shanghai Run-Biotech Co., Ltd.

Tel: 021-57171705 13817537615
Fax: QQ3095748324
Email: sales@run-biotech.com
Country: China
ProdList: 2586
Advantage: 58

Wuxi Zhangkun Biochemical Technology Co., Ltd.

Tel: +86 0510-85629785
Fax: +86 0510-85625359
Country: China
ProdList: 2331
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-1647117 15221909166
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 41438
Advantage: 60

Beijing FYF Chemicals Co., Ltd

Tel: 010-61647239; 15318973357
Fax: 010-57903446
Email: 1460285141@qq.com
Country: China
ProdList: 2946
Advantage: 58

HangZhou YuHao Chemical Technology Co., Ltd.

Tel: 0571-82693216
Fax: 0571-82880190
Email: info@yuhaochemical.com
Country: China
ProdList: 2031
Advantage: 58

Shanghai YuLue Chemical Co., Ltd.

Tel: 021-60345187 13671753212
Fax: 021-34702061
Email: lzz841106@aliyun.com
Country: China
ProdList: 10287
Advantage: 55

Shanghai Macklin Biochemical Co.,Ltd.

Tel: 15221275939 15221275939
Fax: 021-50706099
Email: shenlinxing@macklin.cn
Country: China
ProdList: 15878
Advantage: 55

Shanghai Yongye Biotechnology Co., Ltd.

Tel: 86-021-61559134 15921386130
Fax: 021-55068248
Email: 3423497944@qq.com
Country: China
ProdList: 8147
Advantage: 55

Cool Pharm, Ltd

Tel: 021-60455363 18019463053
Fax: 50966098
Email: sales@coolpharm.com
Country: China
ProdList: 12357
Advantage: 58

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51471
Advantage: 80

Watson Biotechnology Co.,Ltd

Tel: 027-027-59207879 18140587686
Fax: QQ：1972026995
Email: kf@3600chem.com
Country: China
ProdList: 4697
Advantage: 55

Changzhou Anxuan Chemical, Co., Ltd.

Tel: 13912302692 13912302692
Fax: 0519-88064678
Email: sales@anxuanchem.com
Country: China
ProdList: 4825
Advantage: 58

Giant chemicals

Tel: 028-85434334 18108076537
Fax: QQ：245797092
Email: market@gianthx.com
Country: China
ProdList: 4512
Advantage: 56

Dafeng Newti Pharmaceutical Technology Co., Ltd.

Tel: 18015586221
Email: 2760994703@qq.com
Country: China
ProdList: 278
Advantage: 55

Chengdu Research Accelerators Technology Co., Ltd.

Tel: 028-64353063
Fax: 028-64353063 QQ:784253935
Email: reacchemical@163.com
Country: China
ProdList: 5259
Advantage: 58

Chengdu RunZeBenTu Chemical Co., Ltd

Tel: 028-88469284 18000562381
Email: rzbtsj@163.com
Country: China
ProdList: 9958
Advantage: 56

Chengdu DingDang Pharmaceutical Co., Ltd.

Tel: 028-86040038 13980902949;
Fax: 028-85149890
Email: market@dingdangchem.com
Country: China
ProdList: 1745
Advantage: 55

Nanjing Vital Chemical Co., Ltd.

Tel: 025-87193546 18652950785
Fax: 025-87193546
Email: chemweiao@163.com
Country: China
ProdList: 9030
Advantage: 60

ShangHai Siyan Biological Technology Co., Ltd.

Tel: 021-50908862，442785678，326799392 18721037013
Fax: 021-50908862
Email: siyansales@126.com
Country: China
ProdList: 9638
Advantage: 58

Shanghai Qiao Chemical Science Co., Ltd

Tel: 021-58892003
Email: info@qiaochem.com
Country: China
ProdList: 5881
Advantage: 65

Shijiazhuang Sdyano Fine Chemical Co., Ltd.

Tel: 0311-89250318 031166536426
Fax: 4000311741
Email: master@sjzsdyn.com
Country: China
ProdList: 3496
Advantage: 58

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 27322
Advantage: 60

Changzhou Hopschain Chemical Co.,Ltd.

Tel: 0519-85528066 13775048983
Fax: 0519-85528066
Email: sales@hopschem.com
Country: China
ProdList: 31557
Advantage: 55

parabiochem

Tel: 025-83453382-8005
Fax: 025-83453382
Email: sale@parabiochem.com
Country: China
ProdList: 9604
Advantage: 55

Beijing Hechemist Technology CO.,LTD

Tel: 18511709189
Email: sales@hechemist.com
Country: China
ProdList: 3436
Advantage: 58

Less

View Lastest Price from Methyl 3-bromobenzoate manufacturers

Zibo Hangyu Biotechnology Development Co., Ltd

Product: Methyl 3-bromobenzoate 618-89-3
Price: US $70.00-700.00/kg
Min. Order: 10kg
Purity: 0.99
Supply Ability: 20tons
Release date: 2023-11-08

Shanghai Rlavie Technology Co ltd

Product: 3-bromobenzoate Methyl 618-89-3
Price: US $0.00-0.00/KG
Min. Order: 1g
Purity: 98%min
Supply Ability: 100kgs/month
Release date: 2022-01-03

Career Henan Chemical Co

Product: Methyl 3-bromobenzoate 618-89-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: Customized
Release date: 2019-07-02

618-89-3, Methyl 3-bromobenzoateRelated Search:

Methylparaben Methyl bromoacetate METHYL THIOPHENE-2-CARBOXYLATE Methyl benzoate Benzoic acid Bensulfuron methyl Methyl 2-bromo-2-methylpropionate 4-Bromomethylbenzoic acid Thiophanate-methyl Methyl 4-cyanobenzoate Methyl acrylate Methyl acetate Kresoxim-methyl METHYL 5-BROMOSALICYLATE 4-Bromobenzoic acid 3-BROMOISONICOTINIC ACID METHYL ESTER Methyl 3-bromopropionate methyl 3-bromopicolinate

METHYL 3-BROMOBENZOATE FOR SYNTHESIS

3-bromo-benzoicacimethylester

Benzoic acid, m-bromo-, methyl ester

Benzoicacid,3-bromo-,methylester

m-Bromobenzoic acid methyl ester

RARECHEM AL BF 0052

3-BROMOBENZOIC ACID METHYL ESTER

Methyl 3-bromobenzoate, 98+%

Methyl-3-Bromobenzoate 98%

Methyl 3-broMobenzoate, 98% 5GR

3-Bromobenzoate Methyl

METHYL M-BROMOBENZOATE

METHYL 3-BROMOBENZOATE

Methyl 3-Bromobenzoate &gt

618-89-3

Organic Building Blocks

Esters

Building Blocks

C8 to C9

Carbonyl Compounds

Aromatic Esters

API intermediates

Acids & Esters

Bromine Compounds

C8 to C9

Carbonyl Compounds

Esters

Acids and Derivatives

Building Blocks

C8 to C9

Carbonyl Compounds

Chemical Synthesis

Organic Building Blocks