ChemicalBook > CAS DataBase List > Methyl 3-bromobenzoate
Methyl 3-bromobenzoate
- Product Name
- Methyl 3-bromobenzoate
- CAS No.
- 618-89-3
- Chemical Name
- Methyl 3-bromobenzoate
- Synonyms
- RARECHEM AL BF 0052;3-Bromobenzoate Methyl;METHYL M-BROMOBENZOATE;METHYL 3-BROMOBENZOATE;Methyl-3-Bromobenzoate 98%;Methyl 3-Bromobenzoate >Methyl 3-bromobenzoate, 98+%;3-bromo-benzoicacimethylester;Methyl 3-broMobenzoate, 98% 5GR;m-Bromobenzoic acid methyl ester
- CBNumber
- CB4345734
- Molecular Formula
- C8H7BrO2
- Formula Weight
- 215.04
- MOL File
- 618-89-3.mol
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Methyl 3-bromobenzoate Property
- Melting point:
- 31-33 °C(lit.)
- Boiling point:
- 127-128 °C15 mm Hg(lit.)
- Density
- 1.5313 (rough estimate)
- refractive index
- 1.5575
- Flash point:
- >230 °F
- storage temp.
- Sealed in dry,Room Temperature
- form
- Crystalline Solid or Liquid
- color
- White to light yellow
- Water Solubility
- Slightly soluble in water.
- BRN
- 1940810
- InChIKey
- KMFJVYMFCAIRAN-UHFFFAOYSA-N
- CAS DataBase Reference
- 618-89-3(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzoic acid, 3-bromo-, methyl ester(618-89-3)
- EPA Substance Registry System
- Benzoic acid, 3-bromo-, methyl ester (618-89-3)
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 37/39-26-24/25
- WGK Germany
- 3
- TSCA
- Yes
- HS Code
- 29163990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 499625
- Product name
- Methyl 3-bromobenzoate
- Purity
- 98%
- Packaging
- 5g
- Price
- $40.6
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 499625
- Product name
- Methyl 3-bromobenzoate
- Purity
- 98%
- Packaging
- 25g
- Price
- $65
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B0554
- Product name
- Methyl 3-Bromobenzoate
- Purity
- >99.0%(GC)
- Packaging
- 5g
- Price
- $33
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B0554
- Product name
- Methyl 3-Bromobenzoate
- Purity
- >99.0%(GC)
- Packaging
- 25g
- Price
- $85
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A16174
- Product name
- Methyl 3-bromobenzoate, 98+%
- Packaging
- 10g
- Price
- $56.65
- Updated
- 2024/03/01
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Methyl 3-bromobenzoate Chemical Properties,Usage,Production
Chemical Properties
Methyl 3-bromobenzoate is white to light yellow low melting crystalline
Uses
Methyl 3-bromobenzoate is an halogenated benzoate derivative used as a reagent in organic synthesis.Methyl 3-bromobenzoate is used in the synthesis of a novel series of tetrahydro dibenzazocine as inhibitors of 17β-hydroxysteroid dehydrogenase type 3.
Uses
Methyl 3-bromobenzoate is used as a reagent in organic synthesis. It is used in the synthesis of tetrahydro dibenzazocine, which acts as an inhibitor of 17beta-hydroxysteroid dehydrogenase type 3. Further, it is used to prepare 3-tert-butylphosphanyl-benzoic acid methyl ester by reacting with tert-butyltrimethylsilylphosphine.
General Description
Methyl 3-bromobenzoate is an aryl bromide. It undergoes stereoconvergent cross-coupling with potassium trifluoro(1-phenylethyl)borate to form 1,1-diarylethane derivative. The Negishi cross-coupling reaction between methyl 3-bromobenzoate and diarylzinc reagents in the presence of a palladium catalyst has been reported. Methyl-3-bromobenzoate can be converted into the corresponding benzonitrile using dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium as a C-C cross-coupling catalyst and K4[Fe(CN)6] as a cyanating agent.
Methyl 3-bromobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Methyl 3-bromobenzoate manufacturers
Zibo Hangyu Biotechnology Development Co., Ltd
- Product
- Methyl 3-bromobenzoate 618-89-3
- Price
- US $70.00-700.00/kg
- Min. Order
- 10kg
- Purity
- 0.99
- Supply Ability
- 20tons
- Release date
- 2023-11-08
Shanghai Rlavie Technology Co ltd
- Product
- 3-bromobenzoate Methyl 618-89-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- 100kgs/month
- Release date
- 2022-01-03
Career Henan Chemical Co
- Product
- Methyl 3-bromobenzoate 618-89-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2019-07-02
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