Ferrocenecarboxylic acid

Product Name: Ferrocenecarboxylic acid
CAS No.: 1271-42-7
Chemical Name: Ferrocenecarboxylic acid
Synonyms: FEPRAZONE;CARBOXYFERROCENE;Ferocene monocarboxylic acid;Ferroncene Monocarboxylic Acid;Cyclopentadienecarboxylic acid;cyclopenta-2,4-diene-1-carboxylic acid;(CARBOXYCYCLOPENTADIENYL)-CYCLOPENTADIENYLIRON;JACS-1271-42-7;Ferrocenoic acid;FerrocenecarboxyL
CBNumber: CB3215027
Molecular Formula: C11H10FeO210*
Formula Weight: 230.04
MOL File: 1271-42-7.mol

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Ferrocenecarboxylic acid Property

Melting point:: 210 °C (dec.)(lit.)
storage temp.: Inert atmosphere,Room Temperature
solubility: Chloroform (Sparingly), DMSO (Slightly), Methanol (Slightly)
form: crystal
color: yellow
Water Solubility: Insoluble in water.
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stability:: Stable. Incompatible with strong oxidizing agents.
InChI: InChI=1S/C6H5O2.C5H5.Fe/c7-6(8)5-3-1-2-4-5;1-2-4-5-3-1;/h1-4H,(H,7,8);1-5H;
InChIKey: VUJLGCHOGQEAED-UHFFFAOYSA-N
SMILES: [C]1(C(=O)O)[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1.[Fe] |^1:0,4,5,6,7,8,9,10,11,12|
CAS DataBase Reference: 1271-42-7(CAS DataBase Reference)
NIST Chemistry Reference: Ferrocene carboxylic acid(1271-42-7)

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Safety

Hazard Codes: Xn
Risk Statements: 36/37/38-22
Safety Statements: 37/39-26
WGK Germany: 3
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 106887
Product name: Ferrocenecarboxylic acid
Purity: 97%
Packaging: 1g
Price: $46.8
Updated: 2023/06/20

Sigma-Aldrich

Product number: 106887
Product name: Ferrocenecarboxylic acid
Purity: 97%
Packaging: 10g
Price: $241
Updated: 2023/06/20

Alfa Aesar

Product number: A16874
Product name: Ferrocenecarboxylic acid, 98%
Packaging: 1g
Price: $44.2
Updated: 2023/06/20

Alfa Aesar

Product number: A16874
Product name: Ferrocenecarboxylic acid, 98%
Packaging: 5g
Price: $143
Updated: 2023/06/20

Strem Chemicals

Product number: 26-1900
Product name: Ferrocene monocarboxylic acid, min. 97%
Packaging: 1g
Price: $46
Updated: 2024/03/01

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Ferrocenecarboxylic acid Chemical Properties,Usage,Production

Description

Ferrocenecarboxylic acid is a metal-organic compound characterized by connecting two ferrocene molecules through a carboxy ligand. Notably, ferrocene is a stable yet highly reactive metal-organic compound that has been extensively researched due to its potential applications in catalysis, materials science, and medicine. It serves as a catalyst in catalysis, facilitating the synthesis of diverse compounds through polymerization, oxidation, and reduction reactions. In materials science, it acts as a fundamental molecular building block for synthesizing polymers and nanomaterials. Although the precise mechanism of action of Ferrocenecarboxylic acid remains fully elucidated, it is believed that the carboxy ligand binds to the ferrocene molecules, forming a stable complex. This complex, in turn, engages with other molecules, including proteins, to facilitate various reactions[1-2].

Chemical Properties

dark brown powder

Uses

Ferrocenecarboxylic acid is used to esterify complex mixtures of phenols and alcohols for analysis by GCMS. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.

Purification Methods

It crystallises as yellow crystals from pet ether (m 225-230odec), CHCl3 (m 208.5odec), toluene/pet ether (m 195-205odec), or aqueous ethanol. [Matsue et al. J Am Chem Soc 107 3411 1985.] The acid chloride m 49o crystallises from pentane, and has max at 458nm [Lau & Hart J Org Chem 24 280 1959]. The methyl ester crystallises from aqueous MeOH with m 70-71o. The anhydride has m 143-145o when recrystallised from pet ether [Acton & Silverstein J Org Chem 24 1487 1959]. The amide has m 168-170o when crystallised from CHCl3/Et2O or m 167-169o when crystallised from *C6H6/MeOH. [Arimoto & Haven J Am Chem Soc 77 6295 1955, Benkeser et al. J Am Chem Soc 76 4025 1954.] [Beilstein 16 IV 1807.]

References

[1] C. Pess?a, L. Kubota, Y. Gushikem. “Ferrocenecarboxylic acid adsorbed on Nb2O5 film grafted on a SiO2 surface: NADH oxidation study.” Electrochimica Acta 46 1 (2001): 2499–2505.
[2] H. Tsukube, S. Shinoda, H. Fukui. “Synergistic binding and chirality sensing of unprotected amino acids with ferrocenecarboxylic acid–crown ether conjugate.” Tetrahedron Letters 42 1 (2001): 7583–7585.

Ferrocenecarboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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WUHAN FORTUNA CHEMICAL CO., LTD

Product: Ferrocenecarboxylic acid 1271-42-7
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-25

Hebei Weibang Biotechnology Co., Ltd

Product: Ferrocenecarboxylic acid 1271-42-7
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-04

Hebei Yanxi Chemical Co., Ltd.

Product: ferrocenecarboxylic acid 1271-42-7
Price: US $0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 20tons
Release date: 2023-10-10

1271-42-7, Ferrocenecarboxylic acidRelated Search:

Folic acid tert-Butylferrocene Stearic acid Aminoferrocene ETHYNYLFERROCENE Ferrocene Hyaluronic acid Ethyl 2-(Chlorosulfonyl)acetate Ferrocenecarboxaldehyde Acetylferrocene Citric acid Ferrocenemethanol Ferrocenecarboxamide Ascoric Acid Ethylboronic acid 7-Bromo-2,4-dichloropyrido[3,2-d]pyrimidine 2-HYDROXYTHIOPHENOL 3-Amino-6-methylpicolinic acid

(CARBOXYCYCLOPENTADIENYL)-CYCLOPENTADIENYLIRON

CARBOXYFERROCENE

FERROCENE MONOCARBOXYLIC ACID

FERROCENE, CARBOXY-

FERROCENECARBOXYLIC ACID

Ferroncene Monocarboxylic Acid

FERROENECARBOXYLIC ACID

Ferocene monocarboxylic acid

Ferrocenemonocarboxylicacid,min.97%

FERROCENECARBOXYLIC ACID (controlled chemical)

FEPRAZONE

Ferrocene monocarboxylic acid, min. 97%

FerrocenecarboxyL

Ferrocenecarboxylic acid,97%

Ferrocenecarboxylic acid ,98%

Ferrocenecarboxylic acid 97%

Cyclopentadienecarboxylic acid ferrocenoic acid

Ferrocenecarboxylic acid≥ 99% (HPLC)

Ferrocenecarboxylic acid puruM, >=97.0% (Fe)

Carboxylferrocene

Cyclopentadienecarboxylic acid

Ferrocenoic acid

Ferrocenecarboxylic acid, >=99%

JACS-1271-42-7

FerrocenecarboxylicAcid&gt

Ferrocenecarboxylic acid ISO 9001：2015 REACH

Ferrocene, carboxy- (9CI)

cyclopenta-2,4-diene-1-carboxylic acid

errocenecarboxylic acid

1271-42-7

HOOCC5H4FeC5H5

C11H10FeO2

Catalysis and Inorganic Chemistry

metallocene

Pyridines ,Heterocyclic Acids

Piperazine derivates

Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts

Ferrocene series

bc0001

1271-42-7