Silver(I) trifluoromethanethiolate
- Product Name
- Silver(I) trifluoromethanethiolate
- CAS No.
- 811-68-7
- Chemical Name
- Silver(I) trifluoromethanethiolate
- Synonyms
- AgSCF3;ver(I) TrifL;uoromethanethioL;silver,trifluoromethanethiol;Silver trifluoromethanethiolate;(Trifluoromethylthio) silver(I);Silver(I)trifluoromethanethiolate;[(Trifluoromethyl)thio] silver(I);Trifluoromethanethiol Silver(I) Salt;Methanethiol,1,1,1-trifluoro-, silver(1+) salt (1:1)
- CBNumber
- CB32256985
- Molecular Formula
- CHAgF3S
- Formula Weight
- 209.94
- MOL File
- 811-68-7.mol
Silver(I) trifluoromethanethiolate Property
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- Water Solubility
- Insoluble in water
- solubility
- Methanol
- form
- powder to crystal
- color
- White to Light yellow to Light red
- InChI
- InChI=1S/CHF3S.Ag/c2-1(3,4)5;/h5H;
- InChIKey
- SVPQZGWGYCARGG-UHFFFAOYSA-N
- SMILES
- C(S)(F)(F)F.[Ag]
Safety
- HS Code
- 2843290090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- S0977
- Product name
- Silver(I) Trifluoromethanethiolate
- Purity
- >95.0%(T)
- Packaging
- 1g
- Price
- $148
- Updated
- 2025/07/31
- Product number
- S0977
- Product name
- Silver(I) Trifluoromethanethiolate
- Purity
- >95.0%(T)
- Packaging
- 5g
- Price
- $534
- Updated
- 2025/07/31
- Product number
- S465063
- Product name
- Silver(I) Trifluoromethanethiolate
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- AS448718
- Product name
- Silver(I) Trifluoromethanethiolate
- Purity
- 95%
- Packaging
- 1g
- Price
- $137
- Updated
- 2021/12/16
- Product number
- A139672
- Product name
- Silver(I) Trifluoromethanethiolate
- Purity
- 95%
- Packaging
- 1g
- Price
- $138
- Updated
- 2021/12/16
Silver(I) trifluoromethanethiolate Chemical Properties,Usage,Production
Uses
Silver(I) trifluoromethanethiolate is an important organic synthesis intermediate and pharmaceutical intermediate for the preparation of trifluoromethyl aryl sulfides and indanone derivatives[1-2].
Synthesis
14104-20-2
2926-29-6
811-68-7
Silver tetrafluoroborate (AgBF4, 19.77 g, 100 mmol) and sodium trifluoromethanesulfinate (CF3SO2Na, 18.73 g, 120 mmol) were dissolved in anhydrous acetonitrile (400 mL) under nitrogen protection. After cooling the reaction mixture to 0°C, triphenylphosphine (Ph3P, 62.95 g, 240 mmol) was slowly added. Subsequently, the reaction mixture was brought back to room temperature and heated to 50°C and maintained at this temperature for 12 hours. Upon completion of the reaction, the mixture was filtered through diatomaceous earth and the filtrate was cooled to -20°C to promote crystallization. After the crystals were sufficiently precipitated, the supernatant was decanted to remove most of the triphenylphosphine oxide. The supernatant was concentrated under reduced pressure to remove the solvent and the residue was washed well with ether and dried under vacuum. Finally, the resulting solid was recrystallized with tetrahydrofuran and benzene to afford silver trifluoromethane thiol (I) (18.60 g, 89% yield).
References
[1] DAVE J. ADAMS, James H C. ChemInform Abstract: Preparation of Trifluoromethyl Aryl Sulfides Using Silver(I) Trifluoromethanethiolate and an Inorganic Iodide.[J]. ChemInform, 2010, 31 23. DOI:10.1002/chin.200023091.
[2] YI-KANG SONG. Synthesis of 2-(trifluoromethylthio)-indenones by silver-mediated cascade trifluoromethylthiolation/cyclization of arylpropynones[J]. Tetrahedron, 2016, 72 47: Pages 7589-7593. DOI:10.1016/j.tet.2016.10.013.
Silver(I) trifluoromethanethiolate Preparation Products And Raw materials
Raw materials
Preparation Products
Silver(I) trifluoromethanethiolate Suppliers
- Tel
- +1-858-6993322
- Fax
- (+1)-858-876-1948
- info@accelachem.com
- Country
- United States
- ProdList
- 21193
- Advantage
- 58
- Tel
- tp@aladdinsci.com
- Country
- United States
- ProdList
- 57505
- Advantage
- 58
- Tel
- --
- Fax
- --
- sales@tciamerica.com
- Country
- United States
- ProdList
- 6909
- Advantage
- 75
View Lastest Price from Silver(I) trifluoromethanethiolate manufacturers
- Product
- (Trifluoromethylthio) silver(I) 811-68-7
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-09
- Product
- Silver(I) Trifluoromethanethiolate 811-68-7
- Price
- US $35.00/Kg/Bag
- Min. Order
- 25Kg/Bag
- Purity
- 99%
- Supply Ability
- 20 Tons
- Release date
- 2020-11-13