Ethyl propionate Property

Melting point:

-73 °C (lit.)

Boiling point:

99 °C (lit.)

Density 

0.888 g/mL at 25 °C (lit.)

vapor density 

3.52 (vs air)

vapor pressure 

40 mm Hg ( 27.2 °C)

refractive index 

n20/D 1.384(lit.)

FEMA 

2456 | ETHYL PROPIONATE

Flash point:

54 °F

storage temp. 

Flammables area

solubility 

2% soluble in water. miscible with alcohol, perfume and flavor oils.

form 

Liquid

color 

Clear colorless to pale yellow

Odor

at 10.00 % in dipropylene glycol. sweet fruity rum juicy fruit grape pineapple

PH

7 (H2O, 20℃)

explosive limit

1.8-11%(V)

Odor Type

fruity

Odor Threshold

0.007ppm

Water Solubility 

25 g/L (15 ºC)

Merck 

14,3847

JECFA Number

28

BRN 

506287

Dielectric constant

5.7（20℃）

InChIKey

FKRCODPIKNYEAC-UHFFFAOYSA-N

LogP

1.31 at 22.1℃

CAS DataBase Reference

105-37-3(CAS DataBase Reference)

NIST Chemistry Reference

Propanoic acid, ethyl ester(105-37-3)

EPA Substance Registry System

Ethyl propionate (105-37-3)

Safety

Hazard Codes 

F

Risk Statements 

11

Safety Statements 

16-23-24-29-33

RIDADR 

UN 1195 3/PG 2

WGK Germany 

1

RTECS 

UF3675000

Autoignition Temperature

887 °F

TSCA 

Yes

HazardClass 

3

PackingGroup 

II

HS Code 

29159000

Hazardous Substances Data

105-37-3(Hazardous Substances Data)

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Ethyl propionate Chemical Properties,Usage,Production

Chemical Properties

Ethyl Propionate is a clear colorless to pale yellow liquid that is found in many fruits and alcoholic beverages. It has a fruity odor reminiscent of rum and is used in flavor compositions for creating both fruity and rum notes.

Occurrence

Reported found in several types of wine, in white grape var. Sauvignon, cocoa, apple juice, orange juice, grapefruit juice, guava, melon, peach, pineapple, strawberry, tomato, various cheeses, beer, cognac, rum, whiskey, bourbon, malt whiskey, scotch, cider, brandy, kiwi fruit and mussels.

Uses

Solvent for cellulose ethers and esters, various natural and synthetic resins; flavoring agent; fruit syrups; cutting agent for pyroxylin.

Uses

Ethyl Propionate is a flavoring agent that is a transparent liquid, colorless, with an odor resembling rum. it is miscible in alcohol and propylene glycol, soluble in fixed oils, mineral oil, and alcohol, and sparingly soluble in water. it is obtained by chemical synthesis.

Definition

ChEBI: A propanoate ester of ethanol.

Production Methods

Ethyl propionate is produced by the esterification of ethyl alcohol with propionic acid or propionic anhydride.

Preparation

From propionic acid, ethyl alcohol and concentrated H2SO4 in chloroform at the boil

Aroma threshold values

Detection: 9 to 45 ppb

Taste threshold values

Taste characteristics at 25 ppm: sharp, fermented, rummy and fruity.

General Description

Ethyl propionate[105-37-3] appears as a clear colorless liquid with a pineapple-like odor. Flash point 54 °F. Less dense than water and insoluble in water. Vapors are heavier than air.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Ethyl propionate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Can react with oxidizing agents, bases, and acids. Polymerization: Will not polymerize [USCG, 1999].

Hazard

Flammable, dangerous fire risk.

Health Hazard

Exposure can cause irritation of eyes, nose and throat. May cause shortness of breath or coughing. High concentrations have a narcotic effect. May cause abdominal pain and vomiting if swallowed.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. A skin and eye irritant. A flammable liquid. A very dangerous fire and explosion hazard when exposed to heat or flame; can react vigorously with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.

Purification Methods

Treat the ester with anhydrous CuSO4 and distil it under nitrogen. [Beilstein 2 IV 205.]