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(4-BROMO-3-METHYLPHENYL)METHANOL

Product Name
(4-BROMO-3-METHYLPHENYL)METHANOL
CAS No.
149104-89-2
Chemical Name
(4-BROMO-3-METHYLPHENYL)METHANOL
Synonyms
4-bromo-3-methylbenzyl alcoho;4-Bromo-3-methylbenzyl alcohol;(4-BROMO-3-METHYLPHENYL)METHANOL;4-Bromo-3-methylbenzylalcohol,tech;Benzenemethanol, 4-bromo-3-methyl-;4-Bromo-3-methylbenzyl alcohol≥ 97% (GC)
CBNumber
CB32449446
Molecular Formula
C8H9BrO
Formula Weight
201.06
MOL File
149104-89-2.mol
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(4-BROMO-3-METHYLPHENYL)METHANOL Property

Melting point:
31-32℃
Boiling point:
283℃
Density 
1.481
Flash point:
125℃
storage temp. 
2-8°C
form 
fused solid
pka
14.16±0.10(Predicted)
color 
Orange/tan, waxy
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Safety

Hazard Codes 
Xn
Risk Statements 
22
HS Code 
2906290090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B5285
Product name
4-Bromo-3-methylbenzyl Alcohol
Purity
>98.0%(GC)
Packaging
1g
Price
$144
Updated
2025/07/31
TCI Chemical
Product number
B5285
Product name
4-Bromo-3-methylbenzyl Alcohol
Purity
>98.0%(GC)
Packaging
5g
Price
$470
Updated
2025/07/31
TRC
Product number
B697113
Product name
4-Bromo-3-methylbenzyl Alcohol
Packaging
500mg
Price
$95
Updated
2021/12/16
TRC
Product number
B697113
Product name
4-Bromo-3-methylbenzyl Alcohol
Packaging
250mg
Price
$60
Updated
2021/12/16
SynQuest Laboratories
Product number
2701-9-18
Product name
4-Bromo-3-methylbenzyl alcohol
Purity
tech%
Packaging
1g
Price
$64
Updated
2021/12/16
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(4-BROMO-3-METHYLPHENYL)METHANOL Chemical Properties,Usage,Production

Chemical Properties

White low melting crystalline solid

Synthesis

148547-19-7

149104-89-2

Procedure for the synthesis of 4-bromo-3-methylbenzyl alcohol: Methyl 4-bromo-3-methylbenzoate (2.0 g, 8.7 mmol) was dissolved in anhydrous THF (10 mL) and slowly added to a pre-cooled suspension of lithium aluminum hydride (400 mg, 10.4 mmol) in anhydrous THF (30 mL). After addition, the reaction mixture was allowed to gradually warm up to room temperature with continuous stirring for 3 hours. Upon completion of the reaction, water (0.4 mL), 15% NaOH aqueous solution (0.4 mL), and water (1.2 mL) were added sequentially to quench the excess lithium aluminum hydride under the cooling of an ice bath. Insoluble material was removed by diatomaceous earth filtration and the solid residue was washed with ethyl acetate (20 mL x 5). The filtrates were combined and washed with saturated saline (50 mL) and subsequently dried over anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure to afford the crude product 4-bromo-3-methylbenzyl alcohol (1.6 g, 100% yield), which could be used in the subsequent reaction without further purification.1H-NMR (CDCl3, 400 MHz) data were as follows: δ 7.53 (1H, d, J = 8.1 Hz), 7.26 (1H, d, J = 1.5 Hz), 6.40 (1H, dd, J = 8.1, 1.5 Hz). = 8.1, 1.5 Hz), 4.68 (2H, s), 2.44 (3H, s).

References

[1] Patent: US2014/51863, 2014, A1. Location in patent: Paragraph 0205; 0256-0257
[2] Patent: WO2011/143426, 2011, A1. Location in patent: Page/Page column 51
[3] Patent: US2013/131016, 2013, A1. Location in patent: Paragraph 0190
[4] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 1, p. 66 - 71
[5] Journal of Medicinal Chemistry, 2006, vol. 49, # 13, p. 3774 - 3789

(4-BROMO-3-METHYLPHENYL)METHANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(4-BROMO-3-METHYLPHENYL)METHANOL Suppliers

Americas 1 China 84 Europe 1 France 1 Germany 1 India 3 Japan 1 United Kingdom 2 United States 18 Global 112
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
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View Lastest Price from (4-BROMO-3-METHYLPHENYL)METHANOL manufacturers

Career Henan Chemical Co
Product
4-BROMO-3-METHYLPHENYL)METHANOL 149104-89-2
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
10000KGS
Release date
2020-01-09

149104-89-2, (4-BROMO-3-METHYLPHENYL)METHANOLRelated Search:

4-BROMO-2-FLUORO-5-METHYLBENZOIC ACID Methyl 4-bromo-3-methylbenzoate 4-Bromo-3-methylbenzoic acid Broxitalamic acid 4-Bromoisophthalic acid Ethyl 4-Bromo-3-methylbenzoate (4-BROMO-3-TRIFLUOROMETHYL-PHENYL)-METHANOL 4-BROMO-3-(TRIFLUOROMETHYL)BENZOIC ACID TERT-BUTYL 4-BROMO-3-METHYLBENZOATE Methyl 4-Bromo-3-(Trifluoromethyl)benzoate (4-BROMO-3-METHYLPHENYL)METHANOL 4-BROMO-3,5-DIMETHYL-BENZOIC ACID METHYL ESTER ethyl 4-bromo-3-(trifluoromethyl)benzoate ethyl 4-bromo-3-(trifluoromethyl)benzimidate 4-BROMO-3-CHLOROSULFONYL-5-METHYL-BENZOIC ACID ethyl 4-bromo-3-methylbenzimidate SPECS AE-562/12222711 [2-bromo-5-(hydroxymethyl)-3-methylphenyl]methanol

  • (4-BROMO-3-METHYLPHENYL)METHANOL
  • Benzenemethanol, 4-bromo-3-methyl-
  • 4-Bromo-3-methylbenzyl alcohol
  • 4-Bromo-3-methylbenzylalcohol,tech
  • 4-Bromo-3-methylbenzyl alcohol≥ 97% (GC)
  • 4-bromo-3-methylbenzyl alcoho
  • 149104-89-2