Methyl 4-Bromo-3-(Trifluoromethyl)benzoate

Product Name: Methyl 4-Bromo-3-(Trifluoromethyl)benzoate
CAS No.: 107317-58-8
Chemical Name: Methyl 4-Bromo-3-(Trifluoromethyl)benzoate
Synonyms: 2-Bromo-5-(methoxycarbon;Methyl 4-bromo-3-(trifluoromethyl);3-trifluoromethyl-methyl-4- bromobenzoate;Methyl 4-Bromo-3-trifluoromethyl benzonate;Methyl 4-Bromo-3-(Trifluoromethyl)benzoate;3-(Trifluoromethyl)-4-bromobenzoate methyl;2-Bromo-5-(methoxycarbonyl)benzotrifluoride;Methyl 4-bromo-3-(trifluoromethyl)benzoate 98%;4-Bromo-3-(trifluoromethyl)benzoicacidmethylest;4-BroMo-3-(trifluoroMethyl)benzoic acid Methyl ester
CBNumber: CB51270948
Molecular Formula: C9H6BrF3O2
Formula Weight: 283.04
MOL File: 107317-58-8.mol

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Methyl 4-Bromo-3-(Trifluoromethyl)benzoate Property

Boiling point:: 274℃
Density: 1.598
Flash point:: 120℃
storage temp.: 2-8°C
form: Solid
Appearance: White to off-white Solid
InChI: InChI=1S/C9H6BrF3O2/c1-15-8(14)5-2-3-7(10)6(4-5)9(11,12)13/h2-4H,1H3
InChIKey: DTVRLJMSCKUEEN-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=C(Br)C(C(F)(F)F)=C1

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Safety

HS Code: 2916310090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M295493
Product name: Methyl4-bromo-3-(trifluoromethyl)benzoate
Packaging: 1g
Price: $75
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2823-B-43
Product name: Methyl 4-bromo-3-(trifluoromethyl)benzoate
Purity: 98%
Packaging: 5G
Price: $95
Updated: 2021/12/16

Matrix Scientific

Product number: 119214
Product name: Methyl 4-bromo-3-(trifluoromethyl)benzoate
Purity: 95+%
Packaging: 5g
Price: $162
Updated: 2021/12/16

Apolloscientific

Product number: PC5880
Product name: Methyl4-bromo-3-(trifluoromethyl)benzoate
Purity: 98%
Packaging: 1g
Price: $15
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2823-B-43
Product name: Methyl 4-bromo-3-(trifluoromethyl)benzoate
Purity: 98%
Packaging: 1g
Price: $35
Updated: 2021/12/16

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Methyl 4-Bromo-3-(Trifluoromethyl)benzoate Chemical Properties,Usage,Production

Synthesis

67-56-1

1141473-97-3

107317-58-8

Thionyl chloride (16.2 mL, 223 mmol) was slowly added dropwise to a suspension of 4-bromo-3-(trifluoromethyl)benzoic acid (15.0 g, 55.8 mmol) in methanol (300 mL) over 15 minutes. The reaction mixture was stirred at room temperature for 12 hours. Subsequently, the reaction mixture was concentrated by distillation under reduced pressure. The concentrated residue was dissolved in ethyl acetate (500 mL) and washed sequentially with saturated aqueous sodium bicarbonate (200 mL), water (200 mL) and brine (200 mL). The organic layer was dried over anhydrous magnesium sulfate and the solvent was removed under reduced pressure to give methyl 3-trifluoromethyl-4-bromobenzoate as an orange solid (14.8 g, 94% yield). High performance liquid chromatography (Method A) showed a retention time of 4.7 min (purity: 99.0%).1H NMR (DMSO-d6, 300 MHz) δ 8.26 (m, 1H), 8.14 (m, 2H), 3.93 (s, 3H).

References

[1] Patent: WO2010/100142, 2010, A1. Location in patent: Page/Page column 54

Methyl 4-Bromo-3-(Trifluoromethyl)benzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 4-Bromo-3-(Trifluoromethyl)benzoate Suppliers

China 104 India 1 United Kingdom 1 United States 11 Global 117

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View Lastest Price from Methyl 4-Bromo-3-(Trifluoromethyl)benzoate manufacturers

Honest Joy Holdings Limited

Product: Methyl 4-bromo-3-(trifluoromethyl)benzoate 107317-58-8
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.3%
Supply Ability: 100 tons
Release date: 2022-01-14

Zhuozhou Wenxi import and Export Co., Ltd

Product: Methyl 4-Bromo-3-(Trifluoromethyl)benzoate 107317-58-8
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Chemwill Asia Co.,Ltd.

Product: Methyl 4-Bromo-3-(Trifluoromethyl)benzoate 107317-58-8 107317-58-8
Price: US $38.50/KG
Min. Order: 1KG
Purity: 99.50% IN STOCK
Supply Ability: 385 MT per month
Release date: 2019-08-21

107317-58-8, Methyl 4-Bromo-3-(Trifluoromethyl)benzoateRelated Search:

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Methyl 4-Bromo-3-(Trifluoromethyl)benzoate 107317-58-8

107317-58-8 Methyl 4-Bromo-3-(Trifluoromethyl)benzoate

3-(Trifluoromethyl)-4-bromobenzoate methyl

107317-58-8