ChemicalBook > CAS DataBase List > Methyl 4-Bromo-3-(Trifluoromethyl)benzoate

Methyl 4-Bromo-3-(Trifluoromethyl)benzoate

Product Name
Methyl 4-Bromo-3-(Trifluoromethyl)benzoate
CAS No.
107317-58-8
Chemical Name
Methyl 4-Bromo-3-(Trifluoromethyl)benzoate
Synonyms
2-Bromo-5-(methoxycarbon;Methyl 4-bromo-3-(trifluoromethyl);3-trifluoromethyl-methyl-4- bromobenzoate;Methyl 4-Bromo-3-trifluoromethyl benzonate;Methyl 4-Bromo-3-(Trifluoromethyl)benzoate;3-(Trifluoromethyl)-4-bromobenzoate methyl;2-Bromo-5-(methoxycarbonyl)benzotrifluoride;Methyl 4-bromo-3-(trifluoromethyl)benzoate 98%;4-Bromo-3-(trifluoromethyl)benzoicacidmethylest;4-BroMo-3-(trifluoroMethyl)benzoic acid Methyl ester
CBNumber
CB51270948
Molecular Formula
C9H6BrF3O2
Formula Weight
283.04
MOL File
107317-58-8.mol
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Methyl 4-Bromo-3-(Trifluoromethyl)benzoate Property

Boiling point:
274℃
Density 
1.598
Flash point:
120℃
storage temp. 
2-8°C
form 
Solid
Appearance
White to off-white Solid
InChI
InChI=1S/C9H6BrF3O2/c1-15-8(14)5-2-3-7(10)6(4-5)9(11,12)13/h2-4H,1H3
InChIKey
DTVRLJMSCKUEEN-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=C(Br)C(C(F)(F)F)=C1
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Safety

HS Code 
2916310090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M295493
Product name
Methyl4-bromo-3-(trifluoromethyl)benzoate
Packaging
1g
Price
$75
Updated
2021/12/16
Apolloscientific
Product number
PC5880
Product name
Methyl4-bromo-3-(trifluoromethyl)benzoate
Purity
98%
Packaging
1g
Price
$15
Updated
2021/12/16
SynQuest Laboratories
Product number
2823-B-43
Product name
Methyl 4-bromo-3-(trifluoromethyl)benzoate
Purity
98%
Packaging
1g
Price
$35
Updated
2021/12/16
Apolloscientific
Product number
PC5880
Product name
Methyl4-bromo-3-(trifluoromethyl)benzoate
Purity
98%
Packaging
5g
Price
$48
Updated
2021/12/16
Matrix Scientific
Product number
119214
Product name
Methyl 4-bromo-3-(trifluoromethyl)benzoate
Purity
95+%
Packaging
1g
Price
$54
Updated
2021/12/16
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Methyl 4-Bromo-3-(Trifluoromethyl)benzoate Chemical Properties,Usage,Production

Synthesis

67-56-1

1141473-97-3

107317-58-8

Thionyl chloride (16.2 mL, 223 mmol) was slowly added dropwise to a suspension of 4-bromo-3-(trifluoromethyl)benzoic acid (15.0 g, 55.8 mmol) in methanol (300 mL) over 15 minutes. The reaction mixture was stirred at room temperature for 12 hours. Subsequently, the reaction mixture was concentrated by distillation under reduced pressure. The concentrated residue was dissolved in ethyl acetate (500 mL) and washed sequentially with saturated aqueous sodium bicarbonate (200 mL), water (200 mL) and brine (200 mL). The organic layer was dried over anhydrous magnesium sulfate and the solvent was removed under reduced pressure to give methyl 3-trifluoromethyl-4-bromobenzoate as an orange solid (14.8 g, 94% yield). High performance liquid chromatography (Method A) showed a retention time of 4.7 min (purity: 99.0%).1H NMR (DMSO-d6, 300 MHz) δ 8.26 (m, 1H), 8.14 (m, 2H), 3.93 (s, 3H).

References

[1] Patent: WO2010/100142, 2010, A1. Location in patent: Page/Page column 54

Methyl 4-Bromo-3-(Trifluoromethyl)benzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl 4-Bromo-3-(Trifluoromethyl)benzoate manufacturers

Honest Joy Holdings Limited
Product
Methyl 4-bromo-3-(trifluoromethyl)benzoate 107317-58-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99.3%
Supply Ability
100 tons
Release date
2022-01-14
Zhuozhou Wenxi import and Export Co., Ltd
Product
Methyl 4-Bromo-3-(Trifluoromethyl)benzoate 107317-58-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Chemwill Asia Co.,Ltd.
Product
Methyl 4-Bromo-3-(Trifluoromethyl)benzoate 107317-58-8 107317-58-8
Price
US $38.50/KG
Min. Order
1KG
Purity
99.50% IN STOCK
Supply Ability
385 MT per month
Release date
2019-08-21

107317-58-8, Methyl 4-Bromo-3-(Trifluoromethyl)benzoateRelated Search:

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