ChemicalBook > CAS DataBase List > 3-METHYLAZETIDINE HYDROCHLORIDE

3-METHYLAZETIDINE HYDROCHLORIDE

Product Name
3-METHYLAZETIDINE HYDROCHLORIDE
CAS No.
935669-28-6
Chemical Name
3-METHYLAZETIDINE HYDROCHLORIDE
Synonyms
EOS-60406;3-Methylazetidine;3-Methylazetidine HCl;3-Methylazetidine hydroch...;METHYLAZETIDINE HYDROCHLORIDE;3-METHYLAZETIDINE HYDROCHLORIDE;3-Methylazetidine hydrochlorate;3-methylazetidinium hydrochloride;3-METHYLAZETIDINE BENZENESULFONATE;Azetidine, 3-methyl-, hydrochloride
CBNumber
CB32449875
Molecular Formula
C4H10ClN
Formula Weight
107.58
MOL File
935669-28-6.mol
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3-METHYLAZETIDINE HYDROCHLORIDE Property

storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Appearance
Colorless to light yellow <150 °C Solid,>151 °C Liquid
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Safety

HS Code 
2933998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TRC
Product number
M286718
Product name
3-MethylazetidineBenzenesulfonicAcidSalt
Packaging
1g
Price
$200
Updated
2021/12/16
AK Scientific
Product number
W9623
Product name
3-Methylazetidinehydrochloride
Packaging
250mg
Price
$82
Updated
2021/12/16
Matrix Scientific
Product number
069355
Product name
3-Methylazetidine hydrochloride
Purity
>95%
Packaging
1g
Price
$109
Updated
2021/12/16
Synthonix
Product number
M1321
Product name
3-Methylazetidinehydrochloride
Purity
97.0%
Packaging
5g
Price
$130
Updated
2021/12/16
SynQuest Laboratories
Product number
3H31-5-32
Product name
3-Methylazetidinehydrochloride
Packaging
1g
Price
$190
Updated
2021/12/16
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3-METHYLAZETIDINE HYDROCHLORIDE Chemical Properties,Usage,Production

Synthesis

934664-23-0

935669-28-6

General procedure for the synthesis of 3-methylazetidine hydrochloride from benzyl 3-methylene azetidine-1-carboxylate: the product of step (iii) (14.1 g) was dissolved in ethanol (100 mL), 10% Pd/C (JM type 87L) (1.48 g) was added and treated under hydrogen atmosphere. The reaction mixture was stirred for 40 h at 20 °C under hydrogen pressure of 4.50 bar to remove the Cbz protecting groups. Subsequently, the mixture was transferred to ethanol (100 mL) containing palladium hydroxide (2 g) and continued to be hydrogenated at 4.50 bar hydrogen pressure for 24 hours. Upon completion of the reaction, the mixture was filtered through a pad of diatomaceous earth and the filtrate was cooled to 0°C in an ice bath. To the cooled filtrate was added dropwise a dioxane solution (26.0 mL) of 4 M HCl, followed by evaporation of the solution to dryness to give the title product 3-methylazetidine hydrochloride (7.46 g) as a light brown oil. The product was characterized by 1H NMR (400 MHz, CDCl3): δ 9.24 (s, 2H), 3.95 (ddd, J = 7.4, 9.8, 11.4 Hz, 2H), 3.55-3.45 (m, 2H), 2.85 (dt, J = 6.7, 14.2 Hz, 1H), 1.16 (d, 3H).

References

[1] Patent: EP2740458, 2016, B1. Location in patent: Paragraph 0052

3-METHYLAZETIDINE HYDROCHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-METHYLAZETIDINE HYDROCHLORIDE Suppliers

China 75 India 2 United Kingdom 2 United States 10 Global 89
Carbosynth Limited
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6581
Advantage
61
Apollo Scientific Ltd.
Tel
--
Fax
--
Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
Advantage
88
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View Lastest Price from 3-METHYLAZETIDINE HYDROCHLORIDE manufacturers

Career Henan Chemical Co
Product
3-METHYLAZETIDINE HYDROCHLORIDE 935669-28-6
Price
US $6.60/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg -1000kg
Release date
2020-01-02

935669-28-6, 3-METHYLAZETIDINE HYDROCHLORIDERelated Search:

Zetidoline 3-AZETIDINECARBOXYLIC ACID, METHYL ESTER, HYDROCHLORIDE 1-(2-CHLOROPYRIDIN-3-YL)-3,3-DIMETHYLAZETIDIN-2-ONE 3-(4-methoxybenzyl)azetidine 4-methylbenzenesulfonate 3-(4-fluorobenzyl)azetidine 4-methylbenzenesulfonate 3-(4-(trifluoromethyl)benzyl)azetidine 4-methylbenzenesulfonate TERT-BUTYL 3-(TOSYLOXYMETHYL)AZETIDINE-1-CARBOXYLATE 3-METHYLAZETIDINE HYDROCHLORIDE 3-(3-fluorobenzyl)azetidine 4-methylbenzenesulfonate 3-benzylazetidine 4-methylbenzenesulfonate 3-(2-fluorobenzyl)azetidine 4-methylbenzenesulfonate 1-(2-BENZOYL-4-CHLOROPHENYL)-3,3-DIMETHYL-2-AZETANONE 3-([(2-CHLORO-4-FLUOROBENZYL)OXY]IMINO)-2-[4-(3,3-DIMETHYL-2-OXO-1-AZETANYL)PHENYL]PROPANENITRILE 1-(4-[3-(4-CHLOROPHENYL)PYRAZOLO[1,5-A]PYRIMIDIN-7-YL]PHENYL)-3,3-DIMETHYL-2-AZETANONE 1-[[3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL](METHYL)AMINO]-3,3-DIMETHYL-2-AZETANONE 1-(3-([3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL]OXY)PHENYL)-3,3-DIMETHYL-2-AZETANONE 1-(4-[1-(4-CHLOROPHENYL)-1H-PYRAZOL-5-YL]PHENYL)-3,3-DIMETHYL-2-AZETANONE 1-(5-CHLORO-2-PYRIDINYL)-3,3-DIMETHYL-2-AZETANONE

  • 3-METHYLAZETIDINE HYDROCHLORIDE
  • 3-METHYLAZETIDINE BENZENESULFONATE
  • 3-METHYLAZETIDINE BENZENESULFONIC ACID SALT
  • 3-Methylazetidine hydroch...
  • 3-Methylazetidine
  • METHYLAZETIDINE HYDROCHLORIDE
  • 3-Methylazetidine HCl
  • Azetidine, 3-methyl-, hydrochloride
  • EOS-60406
  • Azetidine, 3-methyl-, hydrochloride (1:1)
  • 3-Methylazetidine hydrochloride 95%
  • 3-methylazetidinium hydrochloride
  • 3-Methylazetidine hydrochlorate
  • 3-Methylazetidine hydrochloride - [M1321]
  • 935669-28-6