ChemicalBook > CAS DataBase List > Benzyl 2-chloroacetate

Benzyl 2-chloroacetate

Product Name
Benzyl 2-chloroacetate
CAS No.
140-18-1
Chemical Name
Benzyl 2-chloroacetate
Synonyms
AKOS B029322;monochloroacetate;benzyl chloracetate;Benzyl 2-chloroaceta;BENZYL CHLOROACETATE;BENZYL-(CHLORACETAT);benzyl 2-chloroacetate;benzylmonochloracetate;Benzyl chloroacetate,98%;Benzyl chloroacetate 99%
CBNumber
CB3245642
Molecular Formula
C9H9ClO2
Formula Weight
184.62
MOL File
140-18-1.mol
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Benzyl 2-chloroacetate Property

Boiling point:
90 °C/1 mmHg (lit.)
Density 
1.215 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.525(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
clear liquid
Specific Gravity
1.215
color 
Oil
Water Solubility 
insoluble
CAS DataBase Reference
140-18-1(CAS DataBase Reference)
EPA Substance Registry System
Acetic acid, chloro-, phenylmethyl ester (140-18-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
RTECS 
AF8750000
HS Code 
29154000
Toxicity
LDLo ipr-mus: 500 mg/kg CBCCT* 8,99,56
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
349712
Product name
Benzyl chloroacetate
Purity
99%
Packaging
5ml
Price
$50.9
Updated
2023/01/07
TCI Chemical
Product number
C1265
Product name
Benzyl Chloroacetate
Purity
>97.0%(GC)
Packaging
25g
Price
$103
Updated
2024/03/01
TCI Chemical
Product number
C1265
Product name
Benzyl Chloroacetate
Purity
>97.0%(GC)
Packaging
250g
Price
$646
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
HCH0013935
Product name
BENZYL CHLOROACETATE
Purity
95.00%
Packaging
2.5G
Price
$746.88
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0013935
Product name
BENZYL CHLOROACETATE
Purity
95.00%
Packaging
5G
Price
$808.96
Updated
2021/12/16
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Benzyl 2-chloroacetate Chemical Properties,Usage,Production

Chemical Properties

Benzyl 2-chloroacetate is a colorless, slightly viscous liquid. Insoluble in water, soluble in alcohol and oils. Sp.Gr = 1.22. Mild, Jasmin-type odor, floral-fruity, of considerable tenacity.

Uses

Benzyl chloroacetate may be used:

  • in the synthesis of monoesters of phosphonoacetic acid
  • in the synthesis of N-benzoyl-glycyl- hydroxyl acetic acid, ester substrate for carboxypeptidase Y catalyzed peptide synthesis
  • as reagent in the total syntheses of the (±)-di-O-methyl ethers of the norlignans sequirin-A, agatharesinol, and hinokiresinol, and of (±)-tri-O-methyl sequirin-E

Preparation

From Benzyl alcohol and Monochloroacetic acid by direct esterification under azeotropic conditions.

General Description

Benzyl chloroacetate is an ester. Could find usc in Jasmin, Lilac. Appleblossom fragrances, particularly for soap, where this ester has greater fixative effect than the Benzyl acetate. However, this ester must be absolutely acid-free to be permitted or recommended for use in any cosmetic product. The acid is highly corrosive. Older odor-descriptions of this ester seem to indicate that the product has not always been very pure.

Safety Profile

Moderately toxic byintraperitoneal route. When heated todecomposition it emits toxic fumes of Cl- .

Benzyl 2-chloroacetate Preparation Products And Raw materials

Raw materials

Benzyl alcohol Chloroacetyl chloride Dichloromethane Pyridine

Preparation Products

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Benzyl 2-chloroacetate Suppliers

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View Lastest Price from Benzyl 2-chloroacetate manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Benzyl 2-chloroacetate 140-18-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000KG
Release date
2024-07-18
Career Henan Chemical Co
Product
Benzyl 2-chloroacetate 140-18-1
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2018-12-25

140-18-1, Benzyl 2-chloroacetateRelated Search:

Chloroacetic acid Benzyl acetate Benzyl 2-chloroacetate Benzyl2-chloro-2-[2-(4-methylphenyl)hydrazono]acetate 3,4-DICHLORO-5-PHENYL-2(5H)-FURANONE Benzyl 2-chloro-2-[2-(3,5- Benzyl 2-chloro-2-[2-(4- Benzyl 2-chloro-2-[2-(3,4- 1-phenylethyl 2-chloroacetoacetate Benzyl 2-[2-(4-bromophenyl)hydrazono]-2- AURORA KA-5058 BENZYL CHLOROFLUOROACETATE AURORA KA-1002 AURORA KA-996 BUTTPARK 60\40-55 Benzyl 2-chloro-2-[2-(3- SALOR-INT L132187-1EA Benzyl 2-chloro-2-[2-(2,6-

  • AKOS B029322
  • CHLOROACETIC ACID BENZYL ESTER
  • BENZYL-(CHLORACETAT)
  • BENZYL CHLOROACETATE
  • benzyl 2-chloroacetate
  • Acetic acid, chloro-, phenylmethyl ester
  • benzyl chloracetate
  • Phenylmethyl 2-chloroacetate
  • Benzyl chloroacetate,98%
  • Benzyl 2-chloroaceta
  • Benzyl chloroacetate, 98% 25ML
  • Benzyl chloroacetate 99%
  • 2-chloroacetic acid (phenylmethyl) ester
  • 2-CHLORO ACETIC ACID BENZYLESTER
  • benzyl-alpha-chloroacetate
  • benzylmonochloracetate
  • chloro-aceticacibenzylester
  • chloro-aceticaciphenylmethylester
  • monochloroacetate
  • phenylmethylchloroacetate
  • Benzyl monochloroacetate
  • Benzyl Chloroacetate &gt
  • Acetic acid, 2-chloro-, phenylmethyl ester
  • 2-CHLORO ACETIC ACID BENZYLESTER (BENZYL CHLORO ACETATE)
  • 140-18-1
  • 140-18-0
  • ClCH2COOCH2C6H5
  • ClCH2CO2CH2C6H5
  • Carbonyl Compounds
  • C8 to C9
  • Building Blocks
  • HALOGEN
  • Organic Building Blocks
  • Esters
  • C8 to C9
  • Carbonyl Compounds
  • Esters