Benzyl 2-chloroacetate
- Product Name
- Benzyl 2-chloroacetate
- CAS No.
- 140-18-1
- Chemical Name
- Benzyl 2-chloroacetate
- Synonyms
- AKOS B029322;monochloroacetate;benzyl chloracetate;Benzyl 2-chloroaceta;BENZYL CHLOROACETATE;BENZYL-(CHLORACETAT);benzyl 2-chloroacetate;benzylmonochloracetate;Benzyl chloroacetate,98%;Benzyl chloroacetate 99%
- CBNumber
- CB3245642
- Molecular Formula
- C9H9ClO2
- Formula Weight
- 184.62
- MOL File
- 140-18-1.mol
Benzyl 2-chloroacetate Property
- Boiling point:
- 90 °C/1 mmHg (lit.)
- Density
- 1.215 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.525(lit.)
- Flash point:
- >230 °F
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- clear liquid
- Specific Gravity
- 1.215
- color
- Oil
- Water Solubility
- insoluble
- CAS DataBase Reference
- 140-18-1(CAS DataBase Reference)
- EPA Substance Registry System
- Acetic acid, chloro-, phenylmethyl ester (140-18-1)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-37/39
- WGK Germany
- 3
- RTECS
- AF8750000
- HS Code
- 29154000
- Toxicity
- LDLo ipr-mus: 500 mg/kg CBCCT* 8,99,56
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 349712
- Product name
- Benzyl chloroacetate
- Purity
- 99%
- Packaging
- 5ml
- Price
- $50.9
- Updated
- 2023/01/07
- Product number
- C1265
- Product name
- Benzyl Chloroacetate
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $103
- Updated
- 2024/03/01
- Product number
- C1265
- Product name
- Benzyl Chloroacetate
- Purity
- >97.0%(GC)
- Packaging
- 250g
- Price
- $646
- Updated
- 2024/03/01
- Product number
- I409
- Product name
- Benzyl chloroacetate
- Packaging
- 25g
- Price
- $81
- Updated
- 2021/12/16
- Product number
- HCH0013935
- Product name
- BENZYL CHLOROACETATE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $597.87
- Updated
- 2021/12/16
Benzyl 2-chloroacetate Chemical Properties,Usage,Production
Chemical Properties
Benzyl 2-chloroacetate is a colorless, slightly viscous liquid. Insoluble in water, soluble in alcohol and oils. Sp.Gr = 1.22. Mild, Jasmin-type odor, floral-fruity, of considerable tenacity.
Uses
Benzyl chloroacetate may be used:
- in the synthesis of monoesters of phosphonoacetic acid
- in the synthesis of N-benzoyl-glycyl- hydroxyl acetic acid, ester substrate for carboxypeptidase Y catalyzed peptide synthesis
- as reagent in the total syntheses of the (±)-di-O-methyl ethers of the norlignans sequirin-A, agatharesinol, and hinokiresinol, and of (±)-tri-O-methyl sequirin-E
Preparation
From Benzyl alcohol and Monochloroacetic acid by direct esterification under azeotropic conditions.
General Description
Benzyl chloroacetate is an ester. Could find usc in Jasmin, Lilac. Appleblossom fragrances, particularly for soap, where this ester has greater fixative effect than the Benzyl acetate. However, this ester must be absolutely acid-free to be permitted or recommended for use in any cosmetic product. The acid is highly corrosive. Older odor-descriptions of this ester seem to indicate that the product has not always been very pure.
Safety Profile
Moderately toxic byintraperitoneal route. When heated todecomposition it emits toxic fumes of Cl- .
Benzyl 2-chloroacetate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Benzyl 2-chloroacetate manufacturers
- Product
- Benzyl 2-chloroacetate 140-18-1
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000KG
- Release date
- 2024-07-18
- Product
- Benzyl 2-chloroacetate 140-18-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2018-12-25