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Benzyl 2-chloroacetate

Product Name
Benzyl 2-chloroacetate
CAS No.
140-18-1
Chemical Name
Benzyl 2-chloroacetate
Synonyms
AKOS B029322;monochloroacetate;benzyl chloracetate;Benzyl 2-chloroaceta;BENZYL CHLOROACETATE;BENZYL-(CHLORACETAT);benzyl 2-chloroacetate;benzylmonochloracetate;Benzyl chloroacetate,98%;Benzyl chloroacetate 99%
CBNumber
CB3245642
Molecular Formula
C9H9ClO2
Formula Weight
184.62
MOL File
140-18-1.mol
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Benzyl 2-chloroacetate Property

Boiling point:
90 °C/1 mmHg (lit.)
Density 
1.215 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.525(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
clear liquid
Specific Gravity
1.215
color 
Oil
Water Solubility 
insoluble
CAS DataBase Reference
140-18-1(CAS DataBase Reference)
EPA Substance Registry System
Acetic acid, chloro-, phenylmethyl ester (140-18-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
RTECS 
AF8750000
HS Code 
29154000
Toxicity
LDLo ipr-mus: 500 mg/kg CBCCT* 8,99,56
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
349712
Product name
Benzyl chloroacetate
Purity
99%
Packaging
5ml
Price
$50.9
Updated
2023/01/07
TCI Chemical
Product number
C1265
Product name
Benzyl Chloroacetate
Purity
>97.0%(GC)
Packaging
25g
Price
$103
Updated
2024/03/01
TCI Chemical
Product number
C1265
Product name
Benzyl Chloroacetate
Purity
>97.0%(GC)
Packaging
250g
Price
$646
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
HCH0013935
Product name
BENZYL CHLOROACETATE
Purity
95.00%
Packaging
2.5G
Price
$746.88
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0013935
Product name
BENZYL CHLOROACETATE
Purity
95.00%
Packaging
5G
Price
$808.96
Updated
2021/12/16
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Benzyl 2-chloroacetate Chemical Properties,Usage,Production

Chemical Properties

Benzyl 2-chloroacetate is a colorless, slightly viscous liquid. Insoluble in water, soluble in alcohol and oils. Sp.Gr = 1.22. Mild, Jasmin-type odor, floral-fruity, of considerable tenacity.

Uses

Benzyl chloroacetate may be used:

  • in the synthesis of monoesters of phosphonoacetic acid
  • in the synthesis of N-benzoyl-glycyl- hydroxyl acetic acid, ester substrate for carboxypeptidase Y catalyzed peptide synthesis
  • as reagent in the total syntheses of the (±)-di-O-methyl ethers of the norlignans sequirin-A, agatharesinol, and hinokiresinol, and of (±)-tri-O-methyl sequirin-E

Preparation

From Benzyl alcohol and Monochloroacetic acid by direct esterification under azeotropic conditions.

General Description

Benzyl chloroacetate is an ester. Could find usc in Jasmin, Lilac. Appleblossom fragrances, particularly for soap, where this ester has greater fixative effect than the Benzyl acetate. However, this ester must be absolutely acid-free to be permitted or recommended for use in any cosmetic product. The acid is highly corrosive. Older odor-descriptions of this ester seem to indicate that the product has not always been very pure.

Safety Profile

Moderately toxic byintraperitoneal route. When heated todecomposition it emits toxic fumes of Cl- .

Benzyl 2-chloroacetate Preparation Products And Raw materials

Raw materials

Preparation Products

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Benzyl 2-chloroacetate Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
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76
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9413
Advantage
66
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9815
Advantage
79
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
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View Lastest Price from Benzyl 2-chloroacetate manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Benzyl 2-chloroacetate 140-18-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000KG
Release date
2024-07-18
Career Henan Chemical Co
Product
Benzyl 2-chloroacetate 140-18-1
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2018-12-25

140-18-1, Benzyl 2-chloroacetateRelated Search:


  • AKOS B029322
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  • BENZYL-(CHLORACETAT)
  • BENZYL CHLOROACETATE
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  • Benzyl chloroacetate,98%
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  • chloro-aceticacibenzylester
  • chloro-aceticaciphenylmethylester
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  • Acetic acid, 2-chloro-, phenylmethyl ester
  • 2-CHLORO ACETIC ACID BENZYLESTER (BENZYL CHLORO ACETATE)
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  • ClCH2CO2CH2C6H5
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