2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

Product Name: 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
CAS No.: 898838-07-8
Chemical Name: 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
Synonyms: piperidinyL;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride;Magnesate(1-), dichloro(2,2,6,6-tetramethylpiperidinato)-, lithium (1:1);2,2,6,6-tetramethylpiperidin-1-ide;lithium,magnesium,2,2,6,6-tetramethylpiperidin-1-ide,dichloride;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution;2,2,6,6-tetramethylpiperidinato)magnesate lithium;2,2,6,6-Tetramethylpiperidinylmagnesium chloride l;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chl;Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium
CBNumber: CB32489918
Molecular Formula: C9H18Cl2LiMgN
Formula Weight: 242.4
MOL File: 898838-07-8.mol

More

Less

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Property

Boiling point:: 66°/759.8mm
Density: 0.96g/mLat 25℃
Flash point:: -15°C
storage temp.: 2-8°C
form: liquid
InChI: InChI=1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
InChIKey: JHBZAAACZVPPRQ-UHFFFAOYSA-L
SMILES: [Mg+2]([N-]1C(CCCC1(C)C)(C)C)([Cl-])[Cl-].[Li+]

More

Less

Safety

Hazard Codes: F,C
Risk Statements: 63-11-14-19-34-37-40
Safety Statements: 16-26-36/37/39-45
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 3
HazardClass: 3, 8
HS Code: 29333990

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 703540
Product name: 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
Purity: 1.0 M in THF/toluene
Packaging: 4x25ml
Price: $190
Updated: 2025/07/31

Sigma-Aldrich

Product number: 703540
Product name: 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
Purity: 1.0 M in THF/toluene
Packaging: 100ml
Price: $223
Updated: 2025/07/31

Sigma-Aldrich

Product number: 703540
Product name: 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
Purity: 1.0 M in THF/toluene
Packaging: 500ml
Price: $689
Updated: 2025/07/31

More

Less

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Chemical Properties,Usage,Production

Uses

2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride Complex is used in preparation of Pyridazinones as herbicides. Also, used in preparation of MCL-1 inhibitors useful for treatment of cancer.

Uses

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.

Uses

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex deprotonations using Knochel-Hauser-Base

reaction suitability

reaction type: Grignard Reaction

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Suppliers

China 83 India 3 United States 2 Global 88

Shanghai Chemart Chemical Technology Co., Ltd.

Tel: 021-021-50400622 15618790390
Email: info@chemart.cn
Country: China
ProdList: 239
Advantage: 58

Fuxin F-Block Pharmaceutical Co., Ltd.

Tel: 15901742157
Email: 609923428@qq.com
Country: China
ProdList: 69
Advantage: 58

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Beijing Ouhe Technology Co., Ltd

Tel: 010-010-82967028 13522913783
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12000
Advantage: 60

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9310
Advantage: 66

Nanjing Habo Medical Technology Co., Ltd.

Tel: 025-85760892 13376080562
Fax: 025-85766769
Email: sales@habotech.com
Country: China
ProdList: 884
Advantage: 60

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 15883
Advantage: 64

Lanzhou Hongsheng Fine Chemical Co., Ltd.

Tel: 15693160370; 15693160393
Fax: 028-37690518
Email: lzhschemical@163.com
Country: China
ProdList: 58
Advantage: 58

Yurui (Shanghai) Chemical Co., Ltd.

Tel: +86-02150456736 +86-18602143071
Fax: 021-50761379
Email: xin@riyngroup.com
Country: China
ProdList: 500
Advantage: 30

Cantotech Chemicals, Ltd.

Tel: 86-0755-86635001
Fax: 86-0755-22642228
Email: cantotech@126.com
Country: China
ProdList: 4566
Advantage: 55

898838-07-8, 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complexRelated Search:

2-NAPHTHYLMAGNESIUM BROMIDE 2-Thienylmagnesium bromide solution 2-METHYLBENZYLMAGNESIUM CHLORIDE 1-NAPHTHYLMAGNESIUM BROMIDE 1-METHYL-1-PROPENYLMAGNESIUM BROMIDE 2,5-DIMETHYLPHENYLMAGNESIUM BROMIDE 1-PROPENYLMAGNESIUM BROMIDE 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE Hexylmagnesium chloride 1-PROPYNYLMAGNESIUM BROMIDE 2-BUTENYLMAGNESIUM CHLORIDE ISOBUTYLMAGNESIUM CHLORIDE ISOPROPYLMAGNESIUM BROMIDE N-PROPYLMAGNESIUM BROMIDE Benzylmagnesium chloride PHENYLMAGNESIUM CHLORIDE Isopropylmagnesium chloride lithium chloride complex ISOBUTYLMAGNESIUM BROMIDE

Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium (1:1)

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution

2,2,6,6-TetraMethylpiperidinylMagnesiuM chloride lithiuM chloride coMplex solution 1.0 M in THF/toluene

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

piperidinyL

Magnesate(1-), dichloro(2,2,6,6-tetramethylpiperidinato)-, lithium (1:1)

lithium,magnesium,2,2,6,6-tetramethylpiperidin-1-ide,dichloride

Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chl

2,2,6,6-Tetramethylpiperidinylmagnesium chloride l

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution, 1.0 M in THF

2,2,6,6-tetramethylpiperidin-1-ide

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex 1.0 M solution in THF

2,2,6,6-TETRAMETHYLPIEPERIDINYL MAGNESIUM CHLORIDE, LITHIUM CHLORIDE COMPLEX

2,2,6,6-TETRAMETHYLPIEPERIDINYL MAGNESIUM CHLORIDE, LITHIUM CHLORIDE COMPLEX 1.0 M in THF

2,2,6,6-Tetramethyl piperidinyl Mag Chloride Lithium Chloride complex 1.M in THF

2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride (Complex 1.0 M in THF)

2,2,6,6-tetramethylpiperidinato)magnesate lithium

Magnesium dichloride (2,2,6,6-tetramethylpiperidine) lithium salt

898838-07-8

899938-07-8

C9H18Cl2LiMgN

C9H18Cl2MgNLi

Chemical Synthesis

Grignard Reagents

Heteroaryl

Organometallic Reagents