ChemicalBook > CAS DataBase List > 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
- Product Name
- 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
- CAS No.
- 898838-07-8
- Chemical Name
- 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
- Synonyms
- piperidinyL;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride;Magnesate(1-), dichloro(2,2,6,6-tetramethylpiperidinato)-, lithium (1:1);2,2,6,6-tetramethylpiperidin-1-ide;lithium,magnesium,2,2,6,6-tetramethylpiperidin-1-ide,dichloride;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution;2,2,6,6-Tetramethylpiperidinylmagnesium chloride l;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chl;Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium;Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium (1:1)
- CBNumber
- CB32489918
- Molecular Formula
- C9H18Cl2LiMgN
- Formula Weight
- 242.4
- MOL File
- 898838-07-8.mol
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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Property
- Density
- 0.96g/mLat 25℃
- Flash point:
- -15°C
- storage temp.
- 2-8°C
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Safety
- Hazard Codes
- F,C
- Risk Statements
- 63-11-14-19-34-37-40
- Safety Statements
- 16-26-36/37/39-45
- RIDADR
- UN 3399 4.3/PG 1
- WGK Germany
- 3
- HS Code
- 29333990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H335May cause respiratory irritation
H351Suspected of causing cancer
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 703540
- Product name
- 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
- Purity
- 1.0 M in THF/toluene
- Packaging
- 4x25ml
- Price
- $184
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 703540
- Product name
- 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
- Purity
- 1.0 M in THF/toluene
- Packaging
- 100ml
- Price
- $216
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 703540
- Product name
- 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
- Purity
- 1.0 M in THF/toluene
- Packaging
- 500ml
- Price
- $668
- Updated
- 2024/03/01
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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Chemical Properties,Usage,Production
Uses
2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride Complex is used in preparation of Pyridazinones as herbicides. Also, used in preparation of MCL-1 inhibitors useful for treatment of cancer.
Uses
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.
Uses
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex deprotonations using Knochel-Hauser-Base
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Preparation Products And Raw materials
Raw materials
Preparation Products
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