Allyltributyltin
- Product Name
- Allyltributyltin
- CAS No.
- 24850-33-7
- Chemical Name
- Allyltributyltin
- Synonyms
- ALLYLTRIBUTYLSTANNANE;ALLYLTRI-N-BUTYLTIN;Tributylallylstannane;allyltri-n-butylstannane;2-Propenyltributylstannane;TRIBUTYL-2-PROPENYLSTANNANE;SKL1093;ALLYLTRIBUTYLTIN;Allytri-N-Butyltin;Allyltributyltin(Ⅳ)
- CBNumber
- CB3257937
- Molecular Formula
- C15H32Sn
- Formula Weight
- 331.12
- MOL File
- 24850-33-7.mol
Allyltributyltin Property
- Melting point:
- 134-135 °C
- Boiling point:
- 88-92 °C0.2 mm Hg(lit.)
- Density
- 1.068 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.486(lit.)
- Flash point:
- >230 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Liquid
- color
- Clear colorless
- Specific Gravity
- 1.068
- Water Solubility
- Immiscible with water.
- Hydrolytic Sensitivity
- 1: no significant reaction with aqueous systems
- Sensitive
- Air Sensitive
- BRN
- 3588340
- Exposure limits
- ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 - Stability:
- Air Sensitive
- InChIKey
- YLGRTLMDMVAFNI-UHFFFAOYSA-N
- CAS DataBase Reference
- 24850-33-7(CAS DataBase Reference)
- NIST Chemistry Reference
- Allyltributyltin(24850-33-7)
Safety
- Hazard Codes
- T,N
- Risk Statements
- 21-25-36/38-48/23/25-50/53-23/24/25
- Safety Statements
- 35-36/37/39-45-60-61-28-27-26
- RIDADR
- UN 2788 6.1/PG 2
- WGK Germany
- 3
- F
- 13
- TSCA
- No
- HazardClass
- 6.1
- PackingGroup
- II
- HS Code
- 29319019
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H372Causes damage to organs through prolonged or repeated exposure
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P201Obtain special instructions before use.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 271411
- Product name
- Allyltributylstannane
- Purity
- 97%
- Packaging
- 5g
- Price
- $62.7
- Updated
- 2024/03/01
- Product number
- 271411
- Product name
- Allyltributylstannane
- Purity
- 97%
- Packaging
- 25g
- Price
- $136
- Updated
- 2024/03/01
- Product number
- L14087
- Product name
- Allyltri-n-butyltin, 97%
- Packaging
- 5g
- Price
- $39.6
- Updated
- 2023/06/20
- Product number
- L14087
- Product name
- Allyltri-n-butyltin, 97%
- Packaging
- 25g
- Price
- $136
- Updated
- 2023/06/20
- Product number
- 271411
- Product name
- Allyltributylstannane
- Purity
- 97%
- Packaging
- 100g
- Price
- $290
- Updated
- 2024/03/01
Allyltributyltin Chemical Properties,Usage,Production
Chemical Properties
CLEAR COLOURLESS LIQUID
Uses
Allylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7
Uses
Allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595). Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones and allyl acetates.
Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.
Purification Methods
A possible impurity is tributylchlorostannane — test for Cl as Cl ion after hydrolysing. Dissolve it in *C6H6 (or toluene), shake this with dilute aqueous NaOH, dry (CaCl2), filter, evaporate and distil the residue in a vacuum [Jones et al. J Chem Soc 1446 1947, Bristow Aldrichimica Acta 17 75 1984, Yamamoto Aldrichimica Acta 20 45 1987]. [Beilstein 4 IV 4317.]
Allyltributyltin Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Allyltributyltin manufacturers
- Product
- Allyltributyltin 24850-33-7
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1 ton
- Release date
- 2022-12-06
- Product
- Allyltributyltin 24850-33-7
- Price
- US $6.68/KG
- Min. Order
- 1KG
- Purity
- 97%-99%
- Supply Ability
- 1kg-1000kg
- Release date
- 2020-01-08