Allyltributyltin

Product Name: Allyltributyltin
CAS No.: 24850-33-7
Chemical Name: Allyltributyltin
Synonyms: ALLYLTRIBUTYLSTANNANE;ALLYLTRI-N-BUTYLTIN;Tributylallylstannane;allyltri-n-butylstannane;2-Propenyltributylstannane;TRIBUTYL-2-PROPENYLSTANNANE;SKL1093;ALLYLTRIBUTYLTIN;Allytri-N-Butyltin;Allyltributyltin(Ⅳ)
CBNumber: CB3257937
Molecular Formula: C15H32Sn
Formula Weight: 331.12
MOL File: 24850-33-7.mol

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Allyltributyltin Property

Melting point:: 134-135 °C
Boiling point:: 88-92 °C0.2 mm Hg(lit.)
Density: 1.068 g/mL at 25 °C(lit.)
refractive index: n20/D 1.486(lit.)
Flash point:: >230 °F
storage temp.: 2-8°C
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Liquid
color: Clear colorless
Specific Gravity: 1.068
Water Solubility: Immiscible with water.
Hydrolytic Sensitivity: 1: no significant reaction with aqueous systems
Sensitive: Air Sensitive
BRN: 3588340
Exposure limits: ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
Stability:: Air Sensitive
InChIKey: YLGRTLMDMVAFNI-UHFFFAOYSA-N
CAS DataBase Reference: 24850-33-7(CAS DataBase Reference)
NIST Chemistry Reference: Allyltributyltin(24850-33-7)

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Safety

Hazard Codes: T,N
Risk Statements: 21-25-36/38-48/23/25-50/53-23/24/25
Safety Statements: 35-36/37/39-45-60-61-28-27-26
RIDADR: UN 2788 6.1/PG 2
WGK Germany: 3
F: 13
TSCA: No
HazardClass: 6.1
PackingGroup: II
HS Code: 29319019

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 271411
Product name: Allyltributylstannane
Purity: 97%
Packaging: 5g
Price: $62.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 271411
Product name: Allyltributylstannane
Purity: 97%
Packaging: 25g
Price: $136
Updated: 2024/03/01

Alfa Aesar

Product number: L14087
Product name: Allyltri-n-butyltin, 97%
Packaging: 5g
Price: $39.6
Updated: 2023/06/20

Alfa Aesar

Product number: L14087
Product name: Allyltri-n-butyltin, 97%
Packaging: 25g
Price: $136
Updated: 2023/06/20

Sigma-Aldrich

Product number: 271411
Product name: Allyltributylstannane
Purity: 97%
Packaging: 100g
Price: $290
Updated: 2024/03/01

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Allyltributyltin Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Allylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7

Uses

Allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595). Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones and allyl acetates.
Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.

Purification Methods

A possible impurity is tributylchlorostannane — test for Cl as Cl ion after hydrolysing. Dissolve it in *C6H6 (or toluene), shake this with dilute aqueous NaOH, dry (CaCl2), filter, evaporate and distil the residue in a vacuum [Jones et al. J Chem Soc 1446 1947, Bristow Aldrichimica Acta 17 75 1984, Yamamoto Aldrichimica Acta 20 45 1987]. [Beilstein 4 IV 4317.]

Allyltributyltin Preparation Products And Raw materials

Raw materials

Preparation Products

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Allyltributyltin Suppliers

Americas 1 Belgium 2 China 171 China Hong Kong 1 Europe 2 Germany 5 India 9 Japan 4 Singapore 1 Switzerland 1 United Kingdom 4 United States 21 Global 222

Pure Chemistry Scientific Inc.

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View Lastest Price from Allyltributyltin manufacturers

Nanjing Kaitian Chemical Co., LTD

Product: Allyltributyltin 24850-33-7
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1 ton
Release date: 2022-12-06

Career Henan Chemical Co

Product: Allyltributyltin 24850-33-7
Price: US $6.68/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 1kg-1000kg
Release date: 2020-01-08

24850-33-7, AllyltributyltinRelated Search:

Allyl chloride Tributyltin chloride Diallylamine Allyl bromide Sodium allylsulfonate Allyl glycidyl ether ALLYLOXY-T-BUTYLDIMETHYLSILANE ALLYLOXYTRIMETHYLSILANE POTASSIUM ALLYLTRIFLUOROBORATE Allyl methyl sulfide Allyltrimethylsilane allyltrimethylammonium chloride Allyltriphenylphosphonium bromide 3-Allyloxy-2-Hydroxy-1-Propane,Sodium Salt Allyltrimethoxysilane ALLYLTRIS(TRIMETHYLSILOXY)SILANE ALLYLTRIISOPROPYLSILANE ALLYLTRIETHOXYSILANE

Stannane, tributyl-2-propenyl-

ALLYLTRIBUTYLSTANNANE

ALLYLTRIBUTYLTIN

ALLYLTRIBUTYLTIN(IV)

ALLYLTRI-N-BUTYLTIN

TRIBUTYL-2-PROPENYLSTANNANE

3-(Tributylstannyl)prop-1-ene

Allytri-N-Butyltin

Allyltri-n-butyltin,97%

(2-Propenyl)tributylstannane

2-Propenyltributylstannane

Tributylallylstannane

Allyltributyltin,97%

Allyltributyltin(Ⅳ)

allyitri－n－butyltin

allyltri-n-butylstannane

tri-n-butyl-2-propenylstannane

Allyltributylstannane 97%

The threebutyltinpropenyl

Allyltributyltin, 97% 1GR

(Prop-2-en-1-yl)tributyl stannane, 3-(Tributylstannyl)prop-1-ene

Stannane, tributyl-2-propen-1-yl-

Allyltributyltin ISO 9001：2015 REACH

SKL1093

tributyl(prop-2-enyl)stannane

ributyl(prop-2-enyl)stannane

Allyl Tri n-butyl tin /stannane

24850-33-7

CH2CHCH2SnCH2CH2CH2CH33

Classes of Metal Compounds

Alkyl Metals

Sn (Tin) Compounds

Typical Metal Compounds

Grignard Reagents & Alkyl Metals

Organotin

Organotins

Organometallic Reagents

Chemical Synthesis

Organometallic Reagents

Alkyl Metals

Sn (Tin) Compounds

Classes of Metal Compounds

Grignard Reagents & Alkyl Metals

Synthetic Organic Chemistry

Typical Metal Compounds

Organometallic Reagents

Organotin

Organotins

Stannanes