ChemicalBook > CAS DataBase List > (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)

(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)

Product Name
(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)
CAS No.
126613-06-7
Chemical Name
(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)
Synonyms
SKL667;BINOL-TF2;96.0%(LC);R-BINOL-TF2;(R)-(-)-1,1-Bi-2-Naphthol Bis;1,1'-BIS(2-NAPHTHOL) DITRIFLATE;(R)-(-)-1,1'-BIS(2-NAPHTHOL) DITRIFLATE;(S)-(+)-1,1'-BIS(2-NAPHTHOL) DITRIFLATE;1,1-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE);bis(trifluoromethanesulfonate) (R)-(-)-BINOL-TF2
CBNumber
CB3272817
Molecular Formula
C22H12F6O6S2
Formula Weight
550.45
MOL File
126613-06-7.mol
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(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) Property

Melting point:
83-85 °C(lit.)
alpha 
-149 º (c=1, CHCl3)
Boiling point:
578.8±50.0 °C(Predicted)
Density 
1.5402 (estimate)
storage temp. 
Sealed in dry,Room Temperature
form 
Powder
color 
White
optical activity
[α]23/D 146°, c = 1 in chloroform
Water Solubility 
Insoluble
Sensitive 
moisture sensitive
BRN 
4282753
InChI
InChI=1S/C22H12F6O6S2/c23-21(24,25)35(29,30)33-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)34-36(31,32)22(26,27)28/h1-12H
InChIKey
OYJLCOSEYYZULE-UHFFFAOYSA-N
SMILES
C1(=C(OS(=O)(=O)C(F)(F)F)C=CC2C=CC=CC1=2)C1C(OS(=O)(=O)C(F)(F)F)=CC=C2C=CC=CC=12
CAS DataBase Reference
126613-06-7(CAS DataBase Reference)
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Safety

Hazard Codes 
C,Xi
Risk Statements 
34
Safety Statements 
26-36/37/39-45-27
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
F 
10-21
Hazard Note 
Irritant
HazardClass 
8
PackingGroup 
II
HS Code 
29072990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
440590
Product name
(R)-(?)-1,1′-Bi-2-naphthol bis(trifluoromethanesulfonate)
Purity
97%
Packaging
1g
Price
$31.4
Updated
2023/06/20
TCI Chemical
Product number
B2230
Product name
(R)-(-)-1,1'-Binaphthyl-2,2'-diyl Bis(trifluoromethanesulfonate)
Purity
>96.0%(HPLC)
Packaging
1g
Price
$35
Updated
2025/07/31
Strem Chemicals
Product number
08-0160
Product name
(R)-(-)-1,1'-Bi-2-naphthol bis(trifluoromethanesulfonate), 98%
Packaging
250mg
Price
$31
Updated
2024/03/01
Strem Chemicals
Product number
08-0160
Product name
(R)-(-)-1,1'-Bi-2-naphthol bis(trifluoromethanesulfonate), 98%
Packaging
1g
Price
$91
Updated
2024/03/01
Strem Chemicals
Product number
08-0160
Product name
(R)-(-)-1,1'-Bi-2-naphthol bis(trifluoromethanesulfonate), 98%
Packaging
5g
Price
$355
Updated
2024/03/01
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(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) Chemical Properties,Usage,Production

Chemical Properties

white powder

Uses

(R)-(?)-1,1′-Bi-2-naphthol bis(trifluoromethanesulfonate) can be used:

  • In the synthesis of heterobidentate ligands for asymmetric catalysis.
  • To prepare 2-(diphenylphosphino)-2′-alkoxy-1,1′-binaphthyls by reacting with bis(aryl) phosphonic acids.
  • As a starting material for the synthesis of binaphthyl based rhodium catalysts used in the hydrogenation of styrene.

(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) Suppliers

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View Lastest Price from (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) manufacturers

Career Henan Chemical Co
Product
(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) 126613-06-7
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
10 tons
Release date
2020-01-10

126613-06-7, (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)Related Search:

Levofloxacin Methylate Trifluoromethanesulfonic anhydride Pefloxacin mesylate COPPER(II) TRIFLUOROMETHANESULFONATE YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Trifluoromethanesulfonic acid Gabexate mesylate (S)-(-)-1,1'-Bi-2-naphthol Lithium trifluoromethanesulfonate Sodium trifluoromethanesulfonate 1,1'-Bi-2-naphthol Danofloxacin mesylate Scandium trifluoromethanesulfonate (R)-(+)-1,1'-Bi-2-naphthol (S)-(+)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) Trifluoromethane 1,1'-BINAPHTHYL Methyl trifluoromethanesulfonate

  • 1,1'-BIS(2-NAPHTHOL) DITRIFLATE
  • 1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANESULPHONATE)
  • 1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
  • 1,1-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
  • 1,1'-BI-2-NAPHTHOL-BIS(TRIFLUOROMETHANESULPHONATE)
  • (R)-(-)-1,1`-Bi-2-naphthyl bis(trifluoromethanesulphonate)
  • (R)1,1'-BINAPHTHALENE-2,2'-DIYL BIS(TRI- FLUOROMETHANESULF.)
  • (R)-(-9-1,1'-BINAPHTHYL-2,2'-DIYL BIS-(TRIFLUOROMETHANESULFONATE)
  • (R)-(-)-1,1'-Bi-2-naphtholbis(trifluoromethanesulfonate),98%
  • 1,1'-Binaphthol-2,2'-bis(trifluoroMethanesulfonate)
  • (R)-(-)-1,1''-BINAPHTHOL-2,2''-BIS(TRIFLUOROMETHANESULFONATE) / R-BINOL-TF2
  • (R)-1,1μ-Bi(2-naphthol) bis(trifluoromethanesulfonate), (R)-1,1μ-Binaphthalene-2,2μ-diyl bis(trifluoromethanesulfonate)
  • (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate),97%
  • (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate),96%
  • bis(trifluoromethanesulfonate) (R)-(-)-BINOL-TF2
  • Methanesulfonic acid,1,1,1-trifluoro-, 1,1'-(1R)-[1,1'-binaphtha
  • (R)-(-)-1,1'-Bi-2,2'-naphthol Bis(trifluoromethanesulfonate)
  • trifluoromethanesulfonic acid [1-[2-(trifluoromethylsulfonyloxy)-1-naphthalenyl]-2-naphthalenyl] ester
  • TRIFLUOROMETHANESULFONIC ACID 2'-TRIFLUOROMETHANESULFONYLOXY-[1,1']BINAPHTHALENYL-2-YL ESTER
  • (R)-1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANE)SULPHONATE
  • (R)-(-)-1,1'-BIS(2-NAPHTHOL) DITRIFLATE
  • (R)-1,1'-BINAPHTHALENE-2,2'-DIYL BIS(TRIFLUOROMETHANESULFONATE)
  • (R)-(-)-1,1'-BI-2-NAPHTHYL BIS-TRIFLUOROMETHANESULFONATE
  • (R)-(-)-1,1'-BI-2-NAPHTHOL-BIS(TRIFLUOROMETHANESULPHONATE)
  • (RS)-TRIFLUOROMETHANESULFONIC ACID 2'-TRIFLUOROMETHANESULFONYLOXY-[1,1']BINAPTHALENYL-2-YL ESTER
  • (R)-TRIFLUOROMETHANESULFONIC ACID 2'-TRIFLUOROMETHANSULFONYLOXY-[1,1']BINAPHTHALENYL-2-YL ESTER
  • (S)-(-)-1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
  • (S)-(+)-1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
  • (S)-(+)-1,1'-BI-2-NAPHTHOL-BIS(TRIFLUOROMETHANESULPHONATE)
  • (S)-(+)-1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANESULFONATE)
  • (S)-1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANESULPHONATE)
  • (S)-(+)-1,1'-BIS(2-NAPHTHOL) DITRIFLATE
  • (S)-(+)-1,1'-BI-2-NAPHTHYL BIS-TRIFLUOROMETHANESULFONATE
  • R-BINOL-TF2
  • BINOL-TF2
  • (R)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate), 99%e.e.
  • 96.0%(LC)
  • (R)-(-)-1,1'-Binaphthyl-2,2'-diyl Bis(trifluoromethanesulfonate) &gt
  • Methanesulfonic acid, 1,1,1-trifluoro-, 1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diyl ester, stereoisomer
  • SKL667
  • (R)-(-)-1,1'-Bi(2-naphthol) bis(trifluoromethanesulfonate), 97%,
  • (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)
  • (R)-(-)-1,1'-Bi-2-naphthol Bis(trifluoromethanesulfonate)
  • (R)-[1,1'-Binaphthalene]-2,2'-diyl bis(trifluoromethanesulfonate)
  • (R)-(-)-1,1'-Binaphthyl-2,2'-diyl Bis(trifluoromethanesulfonate)
  • (R)-(-)-1,1'-Bi-2-naphthol bis(trifluoromethanesulfonate),98%
  • (<i>R</i>)-(?)-1,1′-Bi-2-naphthol bis(trifluoromethanesulfonate)
  • (R)-(-)-1,1′-Bi-2-naphthol bis(trifluoromethanesulfonate), CAS 126613-06-7
  • (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)
  • (R)-(-)-1,1-Bi-2-Naphthol Bis
  • 126613-06-7
  • Chiral Catalysts, Ligands, and Reagents
  • Building Blocks
  • Asymmetric Synthesis
  • BINOLs
  • Organic Building Blocks
  • Privileged Ligands
  • Organic Triflates