1-Bromopyrene

Product Name: 1-Bromopyrene
CAS No.: 1714-29-0
Chemical Name: 1-Bromopyrene
Synonyms: 2-Bromopyrene;DK4994;1-Bromopyene;1-BROMOPYRENE;Pyrene, 1-bromo-;1-Pyrenyl bromide;1-Bromopyrene >1-Bromopyrene 96%;1714-29-0 1-Bromopyrene;1-Bromopyrene in toluene
CBNumber: CB3285442
Molecular Formula: C16H9Br
Formula Weight: 281.15
MOL File: 1714-29-0.mol

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1-Bromopyrene Property

Melting point:: 102-105 °C (lit.)
Boiling point:: 255 °C / 7mmHg
Density: 1.4316 (rough estimate)
refractive index: 1.6000 (estimate)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Soluble), DMSO (Slightly, Heated, Sonicated), Methanol (Slightly)
form: Crystalline
color: White to Pale Yellow
InChIKey: HYGLETVERPVXOS-UHFFFAOYSA-N
CAS DataBase Reference: 1714-29-0(CAS DataBase Reference)
NIST Chemistry Reference: 1-Bromopyrene(1714-29-0)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 391573
Product name: 1-Bromopyrene
Purity: 96%
Packaging: 1g
Price: $66.6
Updated: 2024/03/01

TCI Chemical

Product number: B1495
Product name: 1-Bromopyrene
Purity: >95.0%(GC)
Packaging: 5g
Price: $69
Updated: 2024/03/01

TCI Chemical

Product number: B1495
Product name: 1-Bromopyrene
Purity: >95.0%(GC)
Packaging: 25g
Price: $207
Updated: 2024/03/01

Alfa Aesar

Product number: 018280
Product name: 1-Bromopyrene, 95%
Packaging: 1g
Price: $48.65
Updated: 2024/03/01

Alfa Aesar

Product number: 018280
Product name: 1-Bromopyrene, 95%
Packaging: 5g
Price: $177
Updated: 2024/03/01

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1-Bromopyrene Chemical Properties,Usage,Production

Chemical Properties

White to yellow to light brown powder

Uses

1-Bromopyrene is used in the cleavage of DNA in studies. It is also used in the preparation of DNA base analogs.

Uses

1-Bromopyrene is suitable reagent used in the comparative study of effect of substituents of some pyrene derivatives in inducing phototoxicity, DNA damage and repair in human skin keratinocytes and light-induced lipid peroxidation in methanol. It is suitable reagent used in the study to investigate the UV photon-assisted thermal decomposition of PAHs at elevated temperature.
1-Bromopyrene may be used as a standard to compare its spectral properties with that of pyrene based fluorescence probe. It may be used to study the effects of the addition of halogen hetero-atoms on the vapor pressures and thermodynamics of polycyclic aromatic hydrocarbons.
It may be used in the synthesis of the following:
2-methyl-4-pyren-1-yl-but-3-yn-2-ol
1-ethynylpyrene
silsesquioxane (SSQ) based hybrid
ruthenium nanoparticles functionalized with pyrene moiety
mono- and di-pyrenyl perfluoroalkanes
oligo(1-bromopyrene)(OBrP) films
dinitropyrene-derived DNA adduct

Preparation

1-Bromopyrene is an important intermediate in the OLED material industry. The synthesis method is as follows: pyrene is dissolved in an organic solvent dichloromethane, and dibromohydantoin is added for reaction, filtered, and the obtained solid is recrystallized to obtain 1-bromopyrene.

Synthesis Reference(s)

Synthetic Communications, 18, p. 2207, 1988 DOI: 10.1080/00397918808082362
Synthesis of 1-Bromopyrene and 1-Pyrenecarbaldehyde

General Description

1-Bromopyrene, a polycyclic aromatic hydrocarbon (PAH), is a mono bromo substituted pyrene derivative. Its synthesis has been reported. Its gas phase UV-absorption spectra in the UV wavelength range at elevated temperature has been studied. Electron affinitiy (EA) of 1-bromopyrene has been investigated using electron attachment desorption chemical ionization mass spectrometry (DCI-MS) and triple quadrupole tandem mass spectrometry. It participates in the synthesis of novel ruthenium (II) bipyridine or terpyridine complexes bearing pyrene moiety. The reaction of 1-bromopyrene cation radical with water in acetonitrile has been analyzed using the electron transfer stopped-flow (ETSF) method.

1-Bromopyrene Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Bromopyrene Suppliers

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View Lastest Price from 1-Bromopyrene manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: 1-Bromopyrene 1714-29-0
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5tons
Release date: 2024-12-05

Hebei Yanxi Chemical Co., Ltd.

Product: 1-Bromopyrene 1714-29-0
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%?min
Supply Ability: 20tons
Release date: 2023-09-15

Henan Fengda Chemical Co., Ltd

Product: 1-Bromopyrene 1714-29-0
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-26

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1-BROMOPYRENE

Pyrene, 1-bromo-

2-Bromopyrene

1-Pyrenyl bromide

1-Bromopyene

1-Bromopyrene 96%

1-Bromopyrene &gt

1-Bromopyrene, 95%, for synthesis

1-Bromopyrene ISO 9001：2015 REACH

DK4994

1714-29-0 1-Bromopyrene

Hlddsa（n-dodecylsuccinic anhydride）

1-Bromopyrene in toluene

1714-29-0

C16H9Br

C13 to C37+

Aryl

Building Blocks

Halogenated Hydrocarbons

Organic Building Blocks

Pyrenes

OLED materrials

OLED materials,pharm chemical,electronic

fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis

OLED

Electronic Chemicals

Pyrenes

Aryl

C13 to C37+

Halogenated Hydrocarbons

Aromatic Compounds