DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
Description- Product Name
- DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
- CAS No.
- 12148-71-9
- Chemical Name
- DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
- Synonyms
- [Ir(OMe)(1,5-cod)]2;Bis(1,5-cyclooctadiene)dimethoxydiiridium;(1,5-Cyclooctadiene)(methoxy)iridium dimer;DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM;Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I);Bis(1,5-cyclooctadiene)di-mu-methoxydiiridium(I);5-cod)]2;[Ir(OMe)(1;Methoxy(cycL;[Ir(COD)OMe]2
- CBNumber
- CB3287961
- Molecular Formula
- C18H22Ir2O2
- Formula Weight
- 654.81
- MOL File
- 12148-71-9.mol
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Property
- Melting point:
- 154-179 °C (D)
- storage temp.
- -20°C
- form
- Powder
- color
- yellow
- Sensitive
- Light, Air & Moisture Sensitive
- InChI
- InChI=1S/2C8H8.2CH3O.2Ir/c2*1-2-4-6-8-7-5-3-1;2*1-2;;/h2*1-2,7-8H2;2*1H3;;/q;;2*-1;2*+1
- InChIKey
- WLPGZWOTJGJODI-SXGOCSEPSA-N
- SMILES
- C[O-]1[Ir+]234(C5CCC2=C3CCC4=5)[O-](C)[Ir+]2341C1CCC2=C3CCC4=1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 685062
- Product name
- (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
- Packaging
- 1g
- Price
- $224
- Updated
- 2025/07/31
- Product number
- 685062
- Product name
- (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
- Packaging
- 25g
- Price
- $2744
- Updated
- 2025/07/31
- Product number
- C2662
- Product name
- (1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer
- Packaging
- 1g
- Price
- $750
- Updated
- 2025/07/31
- Product number
- C2662
- Product name
- (1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer
- Packaging
- 200mg
- Price
- $151
- Updated
- 2025/07/31
- Product number
- 77-1100
- Product name
- Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I), min. 98%
- Packaging
- 500mg
- Price
- $268
- Updated
- 2024/03/01
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Chemical Properties,Usage,Production
Description
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I), also known as methoxy(cyclooctadiene)iridium(I) dimer, is used as a catalyst in the preparation of heteroaryl fused indole ring systems as inhibition of HCV NS5B polymerase and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration. It is a powerful C-H activation catalyst to prepare phenols from arenes. It is also the catalyst of ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation.
Chemical Properties
yellow solid
Uses
Methoxy(cyclooctadiene)iridium(I) dimer is used as a catalyst in the preparation of heteroaryl fused indole ring systems and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration.
reaction suitability
core: iridium
reagent type: catalyst
reaction type: C-H Activation
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Preparation Products And Raw materials
Raw materials
Preparation Products
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Suppliers
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View Lastest Price from DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) manufacturers
- Product
- DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) 12148-71-9
- Price
- US $2.00-5.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-06-17
- Product
- DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) 12148-71-9
- Price
- US $0.00/G/KG
- Min. Order
- 1G/KG
- Purity
- 99%
- Supply Ability
- 100MT
- Release date
- 2025-04-22
- Product
- (1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer 12148-71-9
- Price
- US $0.00/G
- Min. Order
- 10G
- Purity
- 98%min
- Supply Ability
- 30kg/month
- Release date
- 2023-02-02