Description
ChemicalBook > CAS DataBase List > DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

Description
Product Name
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
CAS No.
12148-71-9
Chemical Name
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
Synonyms
[Ir(OMe)(1,5-cod)]2;Bis(1,5-cyclooctadiene)dimethoxydiiridium;(1,5-Cyclooctadiene)(methoxy)iridium dimer;DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM;Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I);Bis(1,5-cyclooctadiene)di-mu-methoxydiiridium(I);5-cod)]2;[Ir(OMe)(1;Methoxy(cycL;Di-μ-methoxobis
CBNumber
CB3287961
Molecular Formula
C18H22Ir2O2
Formula Weight
654.81
MOL File
12148-71-9.mol
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DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Property

Melting point:
154-179 °C (D)
storage temp. 
-20°C
form 
Powder
color 
yellow
Sensitive 
Light, Air & Moisture Sensitive
InChIKey
WLPGZWOTJGJODI-SXGOCSEPSA-N
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
TSCA 
No
HS Code 
2843909000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
685062
Product name
(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
Packaging
1g
Price
$214
Updated
2024/03/01
Sigma-Aldrich
Product number
685062
Product name
(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
Packaging
25g
Price
$3800
Updated
2024/03/01
TCI Chemical
Product number
C2662
Product name
(1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer
Packaging
1g
Price
$606
Updated
2024/03/01
TCI Chemical
Product number
C2662
Product name
(1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer
Packaging
200mg
Price
$122
Updated
2024/03/01
Alfa Aesar
Product number
044967
Product name
Methoxy(cyclooctadiene)iridium(I) dimer, Ir nominally 58%
Packaging
1g
Price
$429
Updated
2023/06/20
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DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Chemical Properties,Usage,Production

Description

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I), also known as methoxy(cyclooctadiene)iridium(I) dimer, is used as a catalyst in the preparation of heteroaryl fused indole ring systems as inhibition of HCV NS5B polymerase and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration. It is a powerful C-H activation catalyst to prepare phenols from arenes. It is also the catalyst of ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation.

Chemical Properties

yellow solid

Uses

Methoxy(cyclooctadiene)iridium(I) dimer is used as a catalyst in the preparation of heteroaryl fused indole ring systems and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration.

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Preparation Products And Raw materials

Raw materials

Preparation Products

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DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Suppliers

Alkemi BVBA
Tel
--
Fax
--
Email
nfo@alkemi.be
Country
Belgium
ProdList
2201
Advantage
58
TCI EUROPE N.V.
Tel
--
Fax
--
Email
sales@tcieurope.be
Country
Belgium
ProdList
2200
Advantage
66
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View Lastest Price from DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
(1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer 12148-71-9
Price
US $0.00/G
Min. Order
10G
Purity
98%min
Supply Ability
30kg/month
Release date
2023-02-02
henan kanbei chemical co.,ltd
Product
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) 12148-71-9
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-23
Zhuozhou Wenxi import and Export Co., Ltd
Product
(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer 12148-71-9
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

12148-71-9, DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)Related Search:


  • DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
  • Di-mu-methoxobis(1,5-cyclooctadiene)diiridium(I),min.98%
  • [Ir(OMe)(1,5-cod)]2
  • BIS(1,5-CYCLOOCTADIENE) DI-MU-METHOXYDII
  • [Ir(OMe)(1
  • 5-cod)]2
  • (1,5-Cyclooctadiene)(methoxy)iridium dimer
  • Bis(1,5-cyclooctadiene)dimethoxydiiridium
  • Bis[(1,5-cyclooctadiene)(methanolato)iridium]
  • -methoxy)iridium(I) dimer
  • (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
  • Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)
  • Methoxy(cyclooctadiene)iridium(I) dimer
  • Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I), min. 98%
  • Methoxy(cyclooctadiene)iridium(I) dimer, Ir nominally 58%
  • Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I),98%
  • Di-mu-methoxobis(1,5-cycloo
  • Bis(1,5-cyclooctadiene) di-u-methoxydiiridium
  • Di-Methoxobis(1,5-cyclooctadiene)diiridiuM(I)
  • Di-mu-methoxobis(1,5-cyclooctadiene)diiridium (I), min. 98%
  • DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM
  • (Cycloocta-1,5-diene)(methoxy)iridium(I) dimer
  • Bis(cycloocta-1,5-diene) di-u-methoxydiiridium
  • Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I),98% [Ir(COD)(OMe)]2
  • IridiuM, bis[(1,2,5,6-h)-1,5-cyclooctadiene]di-M-Methoxydi-
  • Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I),[Ir(COD)(OMe)]2
  • [Ir(Ome)(1,5-cod)Cl]2
  • (Cycloocta-1,5-diene)(methoxy)iridium(I) dimer 97%
  • Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(Ⅰ)
  • Methoxy(cycL
  • ooctadiene)iridium(I) dimer
  • Methoxy(cyclooctadiene)iridium(I)dimer,Irnominally58%
  • Methoxy(cyclooctadiene)iridium(I) dimerIr nominally
  • Bis(1,5-cyclooctadiene)di-mu-methoxydiiridium(I)
  • DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) ISO 9001:2015 REACH
  • 5-CYCLOOCTADIENE)DIIRIDIUM(I)
  • DI-MU-METHOXOBIS(1
  • Bis[(1,2,5,6-h)-1,5-cyclooctadiene]di-m- methoxydi-iridium
  • Di-(μ-methoxy)bis(1,5-cyclooctadiene)diiridium(I)
  • Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydiiridium
  • (1,5-Cyclooctadiene)(methoxy)iridium(I)dimer,Bis(1,5-cyclooctadiene)di-u-methoxydiiridium
  • (1,5-Cyclooctadiene)(methoxy)iridium(I)
  • Di-μ-methoxobis
  • bis((1Z,5Z)-cycloocta-1,5-diene) dimethyl-2,4-dioxa-1,3-diiridabicyclo[1.1.0]butane-2,4-diium-1,3-diuide
  • Di-u-methoxobis(1,5-cyclooctadiene)diiridium (I)
  • Tetrakis(acetonitrle)palladium(I)tetrafluoroborate
  • 12148-71-9
  • 121148-71-9
  • 2C8H12C2H6Ir2O2
  • IrOCH3C8H122
  • C18H30Ir2O2
  • C22H42Ir2O2
  • organometallic complex
  • Metal Catalysts
  • Ir