Description
ChemicalBook > CAS DataBase List > DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

Description
Product Name
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
CAS No.
12148-71-9
Chemical Name
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
Synonyms
[Ir(OMe)(1,5-cod)]2;Bis(1,5-cyclooctadiene)dimethoxydiiridium;(1,5-Cyclooctadiene)(methoxy)iridium dimer;DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM;Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I);Bis(1,5-cyclooctadiene)di-mu-methoxydiiridium(I);5-cod)]2;[Ir(OMe)(1;Methoxy(cycL;Di-μ-methoxobis
CBNumber
CB3287961
Molecular Formula
C18H22Ir2O2
Formula Weight
654.81
MOL File
12148-71-9.mol
More
Less

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Property

Melting point:
154-179 °C (D)
storage temp. 
-20°C
form 
Powder
color 
yellow
Sensitive 
Light, Air & Moisture Sensitive
InChIKey
WLPGZWOTJGJODI-SXGOCSEPSA-N
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
TSCA 
No
HS Code 
2843909000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
685062
Product name
(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
Packaging
1g
Price
$214
Updated
2024/03/01
Sigma-Aldrich
Product number
685062
Product name
(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
Packaging
25g
Price
$3800
Updated
2024/03/01
TCI Chemical
Product number
C2662
Product name
(1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer
Packaging
1g
Price
$606
Updated
2024/03/01
TCI Chemical
Product number
C2662
Product name
(1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer
Packaging
200mg
Price
$122
Updated
2024/03/01
Alfa Aesar
Product number
044967
Product name
Methoxy(cyclooctadiene)iridium(I) dimer, Ir nominally 58%
Packaging
1g
Price
$429
Updated
2023/06/20
More
Less

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Chemical Properties,Usage,Production

Description

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I), also known as methoxy(cyclooctadiene)iridium(I) dimer, is used as a catalyst in the preparation of heteroaryl fused indole ring systems as inhibition of HCV NS5B polymerase and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration. It is a powerful C-H activation catalyst to prepare phenols from arenes. It is also the catalyst of ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation.

Chemical Properties

yellow solid

Uses

Methoxy(cyclooctadiene)iridium(I) dimer is used as a catalyst in the preparation of heteroaryl fused indole ring systems and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration.

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Suppliers

SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
More
Less

View Lastest Price from DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
(1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer 12148-71-9
Price
US $0.00/G
Min. Order
10G
Purity
98%min
Supply Ability
30kg/month
Release date
2023-02-02
henan kanbei chemical co.,ltd
Product
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) 12148-71-9
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-23
Zhuozhou Wenxi import and Export Co., Ltd
Product
(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer 12148-71-9
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

12148-71-9, DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)Related Search:


  • DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
  • Di-mu-methoxobis(1,5-cyclooctadiene)diiridium(I),min.98%
  • [Ir(OMe)(1,5-cod)]2
  • BIS(1,5-CYCLOOCTADIENE) DI-MU-METHOXYDII
  • [Ir(OMe)(1
  • 5-cod)]2
  • (1,5-Cyclooctadiene)(methoxy)iridium dimer
  • Bis(1,5-cyclooctadiene)dimethoxydiiridium
  • Bis[(1,5-cyclooctadiene)(methanolato)iridium]
  • -methoxy)iridium(I) dimer
  • (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
  • Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)
  • Methoxy(cyclooctadiene)iridium(I) dimer
  • Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I), min. 98%
  • Methoxy(cyclooctadiene)iridium(I) dimer, Ir nominally 58%
  • Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I),98%
  • Di-mu-methoxobis(1,5-cycloo
  • Bis(1,5-cyclooctadiene) di-u-methoxydiiridium
  • Di-Methoxobis(1,5-cyclooctadiene)diiridiuM(I)
  • Di-mu-methoxobis(1,5-cyclooctadiene)diiridium (I), min. 98%
  • DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM
  • (Cycloocta-1,5-diene)(methoxy)iridium(I) dimer
  • Bis(cycloocta-1,5-diene) di-u-methoxydiiridium
  • Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I),98% [Ir(COD)(OMe)]2
  • IridiuM, bis[(1,2,5,6-h)-1,5-cyclooctadiene]di-M-Methoxydi-
  • Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I),[Ir(COD)(OMe)]2
  • [Ir(Ome)(1,5-cod)Cl]2
  • (Cycloocta-1,5-diene)(methoxy)iridium(I) dimer 97%
  • Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(Ⅰ)
  • Methoxy(cycL
  • ooctadiene)iridium(I) dimer
  • Methoxy(cyclooctadiene)iridium(I)dimer,Irnominally58%
  • Methoxy(cyclooctadiene)iridium(I) dimerIr nominally
  • Bis(1,5-cyclooctadiene)di-mu-methoxydiiridium(I)
  • DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) ISO 9001:2015 REACH
  • 5-CYCLOOCTADIENE)DIIRIDIUM(I)
  • DI-MU-METHOXOBIS(1
  • Bis[(1,2,5,6-h)-1,5-cyclooctadiene]di-m- methoxydi-iridium
  • Di-(μ-methoxy)bis(1,5-cyclooctadiene)diiridium(I)
  • Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydiiridium
  • (1,5-Cyclooctadiene)(methoxy)iridium(I)dimer,Bis(1,5-cyclooctadiene)di-u-methoxydiiridium
  • (1,5-Cyclooctadiene)(methoxy)iridium(I)
  • Di-μ-methoxobis
  • bis((1Z,5Z)-cycloocta-1,5-diene) dimethyl-2,4-dioxa-1,3-diiridabicyclo[1.1.0]butane-2,4-diium-1,3-diuide
  • Di-u-methoxobis(1,5-cyclooctadiene)diiridium (I)
  • Tetrakis(acetonitrle)palladium(I)tetrafluoroborate
  • 12148-71-9
  • 121148-71-9
  • 2C8H12C2H6Ir2O2
  • IrOCH3C8H122
  • C18H30Ir2O2
  • C22H42Ir2O2
  • organometallic complex
  • Metal Catalysts
  • Ir