4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
- Product Name
- 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
- CAS No.
- 17129-06-5
- Chemical Name
- 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
- Synonyms
- (E)-4-ethoxy-1,1,1-trifluorobut-3-en-2-one;AKOS B022234;uoro-3-buten-2-one;ART-CHEM-BB B022234;4-Ethoxy-1,1,1-trifL;2-ethoxyvinyltrifluoroMethylketone;4-ethoxy-1,1,1-trifluoro-3-buten-2-on;4-Ethoxy-1,1,1-trifluorobut-3-en-2-on;4-Ehoxy-1,1,1-trifluoro-3-buten-2-one;4-Ethoxy-1,1,1-trifluoro-3-butan-2-one
- CBNumber
- CB3315617
- Molecular Formula
- C6H7F3O2
- Formula Weight
- 168.11
- MOL File
- 17129-06-5.mol
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one Property
- Melting point:
- -30℃
- Boiling point:
- 51-53 °C/12 mmHg (lit.)
- Density
- 1.18 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.406(lit.)
- Flash point:
- 125 °F
- storage temp.
- 2-8°C
- solubility
- soluble in Chloroform, Methanol
- form
- Liquid
- color
- Colorless to yellow
- Sensitive
- Moisture Sensitive
- InChIKey
- YKYIFUROKBDHCY-ONEGZZNKSA-N
- LogP
- 1.414 (est)
- CAS DataBase Reference
- 17129-06-5(CAS DataBase Reference)
Safety
- Hazard Codes
- Xn,F
- Risk Statements
- 10-40
- Safety Statements
- 16-36-36/37
- RIDADR
- UN 1224 3/PG 3
- WGK Germany
- 3
- Hazard Note
- Flammable/Harmful
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29147000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H351Suspected of causing cancer
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P201Obtain special instructions before use.
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273Avoid release to the environment.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 407771
- Product name
- 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
- Purity
- contains 0.5% BHT as stabilizer, technical grade
- Packaging
- 5g
- Price
- $90.2
- Updated
- 2024/03/01
- Product number
- JK380337
- Product name
- 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
- Purity
- 95%
- Packaging
- 1g
- Price
- $53
- Updated
- 2021/12/16
- Product number
- 057760
- Product name
- (E)-4-Ethoxy-1,1,1-trifluorobut-3-en-2-one
- Purity
- 95%
- Packaging
- 1g
- Price
- $14
- Updated
- 2021/12/16
- Product number
- 2317-3-41
- Product name
- 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
- Purity
- 95%
- Packaging
- 1g
- Price
- $15
- Updated
- 2021/12/16
- Product number
- 2317-3-41
- Product name
- 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
- Purity
- 95%
- Packaging
- 5G
- Price
- $40
- Updated
- 2021/12/16
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one Chemical Properties,Usage,Production
Chemical Properties
light yellow liquid
Uses
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one may be used in the synthesis of 4-dialkylamino-1,1,1-trifluorobut-3-ene-2-ones. It may be used for the synthesis of β-alkyl- or dialkylamino substituted enones bearing a CF3 group.
General Description
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one reacts with phenylmagnesium bromide to afford ethoxy group substitution products, while it reacts with organozinc compounds to yield products arising from 1,2-addition to the carbonyl group. 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one on heating with triethyl phosphite affords [4+2] cycloaddition product, 2,2,2-triethoxy 2,3-dihydro-3-ethoxy-5-trifluoromethyl-1,2λ5-oxaphospholene, which on hydrolysis affords a 2-oxo-2-hydroxy-2, 3-dihydro-3-hydroxy 5-trifluoromethyl-1,2λ5-oxaphospholen. It reacts with amino to give the N-protected amino acids, which is useful for the peptide synthesis.
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one Preparation Products And Raw materials
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View Lastest Price from 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one manufacturers
- Product
- 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one 17129-06-5
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-09
- Product
- 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one 17129-06-5
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2018-12-22