ChemicalBook > CAS DataBase List > 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one

4-Ethoxy-1,1,1-trifluoro-3-buten-2-one

Product Name
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
CAS No.
17129-06-5
Chemical Name
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
Synonyms
(E)-4-ethoxy-1,1,1-trifluorobut-3-en-2-one;AKOS B022234;uoro-3-buten-2-one;ART-CHEM-BB B022234;4-Ethoxy-1,1,1-trifL;2-ethoxyvinyltrifluoroMethylketone;4-ethoxy-1,1,1-trifluoro-3-buten-2-on;4-Ethoxy-1,1,1-trifluorobut-3-en-2-on;4-Ehoxy-1,1,1-trifluoro-3-buten-2-one;4-Ethoxy-1,1,1-trifluoro-3-butan-2-one
CBNumber
CB3315617
Molecular Formula
C6H7F3O2
Formula Weight
168.11
MOL File
17129-06-5.mol
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4-Ethoxy-1,1,1-trifluoro-3-buten-2-one Property

Melting point:
-30℃
Boiling point:
51-53 °C/12 mmHg (lit.)
Density 
1.18 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.406(lit.)
Flash point:
125 °F
storage temp. 
2-8°C
solubility 
soluble in Chloroform, Methanol
form 
Liquid
color 
Colorless to yellow
Sensitive 
Moisture Sensitive
InChIKey
YKYIFUROKBDHCY-ONEGZZNKSA-N
LogP
1.414 (est)
CAS DataBase Reference
17129-06-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,F
Risk Statements 
10-40
Safety Statements 
16-36-36/37
RIDADR 
UN 1224 3/PG 3
WGK Germany 
3
Hazard Note 
Flammable/Harmful
HazardClass 
3
PackingGroup 
III
HS Code 
29147000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H351Suspected of causing cancer

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
407771
Product name
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
Purity
contains 0.5% BHT as stabilizer, technical grade
Packaging
5g
Price
$90.2
Updated
2024/03/01
Frontier Specialty Chemicals
Product number
JK380337
Product name
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
Purity
95%
Packaging
1g
Price
$53
Updated
2021/12/16
Matrix Scientific
Product number
057760
Product name
(E)-4-Ethoxy-1,1,1-trifluorobut-3-en-2-one
Purity
95%
Packaging
1g
Price
$14
Updated
2021/12/16
SynQuest Laboratories
Product number
2317-3-41
Product name
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
Purity
95%
Packaging
1g
Price
$15
Updated
2021/12/16
SynQuest Laboratories
Product number
2317-3-41
Product name
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
Purity
95%
Packaging
5G
Price
$40
Updated
2021/12/16
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4-Ethoxy-1,1,1-trifluoro-3-buten-2-one Chemical Properties,Usage,Production

Chemical Properties

light yellow liquid

Uses

4-Ethoxy-1,1,1-trifluoro-3-buten-2-one may be used in the synthesis of 4-dialkylamino-1,1,1-trifluorobut-3-ene-2-ones. It may be used for the synthesis of β-alkyl- or dialkylamino substituted enones bearing a CF3 group.

General Description

4-Ethoxy-1,1,1-trifluoro-3-buten-2-one reacts with phenylmagnesium bromide to afford ethoxy group substitution products, while it reacts with organozinc compounds to yield products arising from 1,2-addition to the carbonyl group. 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one on heating with triethyl phosphite affords [4+2] cycloaddition product, 2,2,2-triethoxy 2,3-dihydro-3-ethoxy-5-trifluoromethyl-1,2λ5-oxaphospholene, which on hydrolysis affords a 2-oxo-2-hydroxy-2, 3-dihydro-3-hydroxy 5-trifluoromethyl-1,2λ5-oxaphospholen. It reacts with amino to give the N-protected amino acids, which is useful for the peptide synthesis.

4-Ethoxy-1,1,1-trifluoro-3-buten-2-one Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Ethoxy-1,1,1-trifluoro-3-buten-2-one Suppliers

Belgium 1 Canada 1 China 186 Germany 8 India 9 Ireland 1 Japan 4 Russia 2 Slovakia 2 Switzerland 2 The Netherlands 1 United Kingdom 12 United States 31 USA 1 Global 261
P&M-Invest
Tel
--
Fax
--
Email
notes@fluorine.ru
Country
Russia
ProdList
877
Advantage
66
ART-CHEM GmbH
Tel
--
Fax
--
Email
art-chem@art-chem.com
Country
Russia
ProdList
6560
Advantage
30
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View Lastest Price from 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one 17129-06-5
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-09
Career Henan Chemical Co
Product
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one 17129-06-5
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-22

17129-06-5, 4-Ethoxy-1,1,1-trifluoro-3-buten-2-oneRelated Search:

Methyl vinyl ketone Ethoxyquin Ethoxyamine hydrochloride DIETHOXYMETHANE Flucarbazone sodium 4-Fluoroacetophenone 1-(4,5-DIHYDROFURAN-3-YL)-2,2,2-TRIFLUOROETHAN-1-ONE Ethyl 2-(ethoxymethylene)-4,4,4-trifluoroacetoacetate 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one Ethoxy TRIFLUOROACETYLKETENEDIETHYLACETAL 3-BROMO-4-ETHOXY-1,1,1-TRIFLUORO-BUT-3-EN-2-ONE 3-CHLORO-4-ETHOXY-1,1,1-TRIFLUORO-BUT-3-EN-2-ONE (E)-4-AMINO-4-ETHOXY-1,1,1-TRIFLUOROBUT-3-EN-2-ONE 1-(5,6-DIHYDRO-4H-PYRAN-3-YL)-2,2,2-TRIFLUORO-ETHANONE RARECHEM AL FK 0077 2,2,2-TRIFLUORO-1-(6-METHOXY-5,6-DIHYDRO-4H-PYRAN-3-YL)-ETHANONE 3-[3,3,3-TRIFLUORO-2-OXOPROP-(Z)-YLIDENE]-3H-ISOBENZOFURAN-1-ONE

  • 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one, 94%, stab.
  • (E)-4-ethoxy-1,1,1-trifluorobut-3-en-2-one
  • 4-Ethoxy-1,1,1-Trifluoro-3-Buten-2-One, Stab.
  • 2-ethoxyvinyltrifluoroMethylketone
  • (2-Ethoxyvinyl) trifluoromethyl ketone, 1-Ethoxy-3-oxo-4,4,4-trifluorobut-1-ene
  • 4-ETHOXY-1,1,1-TRIFLUORO-3-BUTEN-2-ONE, TECH.
  • 4-ethoxy-1,1,1-trifluoro-3-buten-2-on
  • (3E)-4-Ethoxy-1,1,1-trifluorobut-3-en-2-one
  • 4-<WBR>Ethoxy-<WBR>1,1,1-<WBR>trifluoro-<WBR>3-<WBR>buten-<WBR>2-<WBR>one
  • 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one contains 0.5% BHT as stabilizer, technical grade
  • 4-Ethoxy-1,1,1-trifluoro-3-butan-2-one
  • 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one, stabilized
  • 4-ETHOXY-1,1,1-TRIFLUORO-3-BUTEN-2-ONE
  • 4-ETHOXY-1,1,1-TRIFLUORO-BUT-3-EN-2-ONE
  • AKOS B022234
  • ART-CHEM-BB B022234
  • 4-Ethoxy-1,1,1-trifL
  • uoro-3-buten-2-one
  • 3-Buten-2-one, 4-ethoxy-1,1,1-trifluoro-
  • TIANFU-CHEM - 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
  • 4-Ethoxy-1,1,1-trifluorobut-3-en-2-on
  • 4-Ehoxy-1,1,1-trifluoro-3-buten-2-one
  • 17129-06-5
  • 59983-06-6
  • C2H5OCHCHCOCF3
  • Organic Building Blocks
  • Ketones
  • C3 to C6
  • Carbonyl Compounds
  • Building Blocks
  • C3 to C6
  • Carbonyl Compounds
  • Ketones
  • Alcohol& Phenol& Ethers