ChemicalBook > CAS DataBase List > 1-(Bromomethyl)naphthalene

1-(Bromomethyl)naphthalene

Product Name
1-(Bromomethyl)naphthalene
CAS No.
3163-27-7
Chemical Name
1-(Bromomethyl)naphthalene
Synonyms
CL015;1-(Bromomethyl)napht;1-Naphtylmethyl bromide;(1-Naphtyl)bromomethane;1-(Bromomthy)Naphthalene;1-Naphthylmethyl bromide;1-(Bromomethyl)phthalene;1-(Brommethyl)naphthalen;1-broMo Methyl napthalene;1-(Bromomethy)naphthalene
CBNumber
CB3337682
Molecular Formula
C11H9Br
Formula Weight
221.09
MOL File
3163-27-7.mol
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1-(Bromomethyl)naphthalene Property

Melting point:
52-55°C
Boiling point:
213°C/100mmHg
Density 
1.44
refractive index 
1.6600
storage temp. 
Inert atmosphere,2-8°C
form 
Powder
color 
Off-white
Water Solubility 
Slightly soluble in water.
λmax
292nm(Cyclohexane)(lit.)
CAS DataBase Reference
3163-27-7(CAS DataBase Reference)
NIST Chemistry Reference
1-(Bromomethyl)naphthalene(3163-27-7)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36
RIDADR 
3261
HazardClass 
8
PackingGroup 
II
HS Code 
29036990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P390Absorb spillage to prevent material damage.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
B4563
Product name
1-(Bromomethyl)naphthalene
Purity
>98.0%(GC)
Packaging
5g
Price
$43
Updated
2025/07/31
TCI Chemical
Product number
B4563
Product name
1-(Bromomethyl)naphthalene
Purity
>98.0%(GC)
Packaging
25g
Price
$209
Updated
2025/07/31
TRC
Product number
B697350
Product name
1-(Bromomethyl)naphthalene
Packaging
250mg
Price
$55
Updated
2021/12/16
TRC
Product number
B697350
Product name
1-(Bromomethyl)naphthalene
Packaging
500mg
Price
$65
Updated
2021/12/16
TRC
Product number
B697350
Product name
1-(Bromomethyl)naphthalene
Packaging
100mg
Price
$45
Updated
2021/12/16
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1-(Bromomethyl)naphthalene Chemical Properties,Usage,Production

Chemical Properties

Off-white powder

Uses

It is employed as a intermediate for organic synthesis and pharmaceutical.

Synthesis

4780-79-4

3163-27-7

The general procedure for the synthesis of 1-bromomethylnaphthalene from 1-naphthalenemethanol: Ethyl α,α-diacetoacetate (0.41 mmol, 1.2 eq.), 1-naphthalenemethanol (0.34 mmol, 1.0 eq.), and triphenylphosphine (0.68 mmol, 2.0 eq.) were added to 3 mL of dichloroethane (DCE) at room temperature and the reaction took place in air. The progress of the reaction was monitored by thin layer chromatography (TLC) during the reaction. Upon completion of the reaction, the reaction was quenched by the addition of 3 mL of water, followed by extraction with ethyl acetate (3 x 3 mL). The organic phases were combined, washed with saturated saline, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography, and the eluent was petroleum ether or a mixed solvent of petroleum ether and ethyl acetate, and the target product 1-bromomethyl naphthalene was finally obtained.

References

[1] Synthetic Communications, 2010, vol. 40, # 11, p. 1646 - 1649
[2] Organic Letters, 2003, vol. 5, # 8, p. 1167 - 1169
[3] Tetrahedron Letters, 2014, vol. 55, # 1, p. 90 - 93
[4] Canadian Journal of Chemistry, 1981, vol. 59, p. 2629 - 2641
[5] Tetrahedron, 2003, vol. 59, # 52, p. 10453 - 10463

1-(Bromomethyl)naphthalene Preparation Products And Raw materials

Raw materials

Preparation Products

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1-(Bromomethyl)naphthalene Suppliers

Americas 1 Canada 1 China 150 Europe 3 Germany 3 India 10 Japan 1 Slovakia 1 Switzerland 1 The Netherlands 1 Ukraine 1 United Kingdom 8 United States 30 Global 211
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View Lastest Price from 1-(Bromomethyl)naphthalene manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
1-(Bromomethyl)naphthalene 3163-27-7
Price
US $1.00/Kg
Min. Order
1Kg
Purity
98%
Supply Ability
20T
Release date
2024-07-08
Zhuozhou Wenxi import and Export Co., Ltd
Product
1-(Bromomthy)Naphthalene 3163-27-7
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
1-(Bromomthy)Naphthalene 3163-27-7
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08

3163-27-7, 1-(Bromomethyl)naphthaleneRelated Search:

Methylnaphthalene Bromotrimethylsilane 1-Bromonaphthalene 2-Acetonaphthone 2,6-DIMETHYLNAPHTHALENE Naphthalene 2-(Bromomethyl)naphthalene Methyl bromide 1-BROMO-4-(BROMOMETHYL)NAPHTHALENE 1,4-BIS(BROMOMETHYL)NAPHTHALENE 1,8-BIS(BROMOMETHYL)NAPHTHALENE 4-(BROMOMETHYL)NAPHTHALENE-1-CARBONITRILE 1-(BROMOMETHYL)-4-NITRONAPHTHALENE 9,10-Bis(bromomethyl)anthracene ALPHA-BROMO-1-NAPHTHALENEACETIC ACID ETHYL ESTER 3-(BROMOMETHYL)PYRENE 4-(BROMOMETHYL)NAPHTHALENE-1-CARBOXYLIC ACID 1-Bromomethyl-7-fluoro-naphthalene

  • Naphthalene, 1-(bromomethyl)-
  • 1-BROMOMETHYL NAPHTHALENE
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  • 1-(Bromomthy)Naphthalene
  • 1-(Bromomethy)naphthalene
  • (1-Naphtyl)bromomethane
  • 1-Naphtylmethyl bromide
  • 1-(Bromomethyl)napht
  • 1-broMo Methyl napthalene
  • CL015
  • 1-(Bromomethyl)naphthalene, 98% off-white powder
  • 1-Naphthylmethyl bromide
  • 1-(Bromomethyl)phthalene
  • 1-(Bromomethyl)naphthalene &gt
  • 1-(Brommethyl)naphthalen
  • 3163-27-7
  • 3136-27-7
  • 3613-27-7
  • Naphthalene series