4-Iodobenzyl bromide

Product Name: 4-Iodobenzyl bromide
CAS No.: 16004-15-2
Chemical Name: 4-Iodobenzyl bromide
Synonyms: SKL242;EGFR-1（18-;R-Protopanoxadiol;p-odobenzyl bromide;P-IODOBENZYL BROMIDE;4-IODOBENZYL BROMIDE;à-bromo-4-iodotoluene;α-broMo-4-iodotoluene;4-IodobenzylBromide>4-Iodobenzyl bromide,97%
CBNumber: CB3421989
Molecular Formula: C7H6BrI
Formula Weight: 296.93
MOL File: 16004-15-2.mol

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4-Iodobenzyl bromide Property

Melting point:: 78-82 °C(lit.)
Boiling point:: 140°C 15mm
Density: 2.0672 (rough estimate)
refractive index: 1.6500 (estimate)
Flash point:: 140°C/15mm
storage temp.: 2-8°C
form: Adhering Crystalline Powder
color: Light yellow
Water Solubility: Insoluble in water.
Sensitive: Light Sensitive/Lachrymatory
BRN: 2325160
InChI: InChI=1S/C7H6BrI/c8-5-6-1-3-7(9)4-2-6/h1-4H,5H2
InChIKey: BQTRMYJYYNQQGK-UHFFFAOYSA-N
SMILES: C1(CBr)=CC=C(I)C=C1
CAS DataBase Reference: 16004-15-2(CAS DataBase Reference)

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Safety

Hazard Codes: C,T
Risk Statements: 34-63-42/43-36/37/38
Safety Statements: 26-36/37/39-45-23
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
Hazard Note: Corrosive/Lachrymatory/Light Sensitive
HazardClass: IRRITANT
HazardClass: 8
PackingGroup: Ⅱ
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 515604
Product name: 4-Iodobenzyl bromide
Purity: 95%
Packaging: 1g
Price: $34.8
Updated: 2025/07/31

Sigma-Aldrich

Product number: 515604
Product name: 4-Iodobenzyl bromide
Purity: 95%
Packaging: 5g
Price: $103.94
Updated: 2025/07/31

TCI Chemical

Product number: I0571
Product name: 4-Iodobenzyl Bromide
Packaging: 5G
Price: $62
Updated: 2025/07/31

TCI Chemical

Product number: I0571
Product name: 4-Iodobenzyl Bromide
Packaging: 25G
Price: $277
Updated: 2025/07/31

TRC

Product number: I737248
Product name: 4-Iodobenzyl Bromide
Packaging: 2.5g
Price: $75
Updated: 2021/12/16

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4-Iodobenzyl bromide Chemical Properties,Usage,Production

Chemical Properties

light yellow adhering crystalline powder

Uses

4-Iodobenzyl bromide is used as an organic chemical synthesis intermediate.

Synthesis

624-31-7

16004-15-2

4-Iodotoluene (Compound 1C, 25 g) was added with N-bromosuccinimide (23.5 g) and benzoyl peroxide (375 mg) in carbon tetrachloride (375 ml) and heated to reflux for 7 hours under light conditions. After completion of the reaction, the mixture was stirred at room temperature overnight. Subsequently, the insoluble material was removed by filtration and the filtrate was concentrated under reduced pressure. The concentrated residue was recrystallized with ethyl acetate and hexane to afford the target product 4-iodobenzyl bromide (Compound 1D) in 60.3% yield. [0027] NMR hydrogen spectral data (CDCl3, with TMS as internal standard): δ 7.72 (d, 2H), 7.14 (d, 2H), 4.39 (s, 2H).

References

[1] Macromolecules, 2013, vol. 46, # 12, p. 4754 - 4763
[2] Acta Crystallographica Section C: Crystal Structure Communications, 2003, vol. 59, # 4, p. o216-o218
[3] Journal of Materials Chemistry C, 2015, vol. 3, # 4, p. 734 - 741
[4] Chemistry - An Asian Journal, 2017, vol. 12, # 6, p. 690 - 697
[5] Journal of Organic Chemistry, 2014, vol. 79, # 1, p. 223 - 229

4-Iodobenzyl bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-Iodobenzyl bromide manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd

Product: 4-Iodobenzyl bromide 16004-15-2
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: Customise
Release date: 2025-11-07

Shenzhen Nexcon Pharmatechs Ltd.

Product: 4-Iodobenzyl bromide 16004-15-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 2000
Release date: 2025-09-04

Hebei Chuanghai Biotechnology Co., Ltd

Product: 4-Iodobenzyl bromide 16004-15-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-11-13

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EGFR-1（18-

4-Iodobenzyl bromide ISO 9001：2015 REACH

SKL242

16004-15-2

IC6H4CH2Br

C7

Aryl

Building Blocks

Halogenated Hydrocarbons

Organic Building Blocks

CMLLYL

Methyl Halides

Phenyls & Phenyl-Het

Halogenated Hydrocarbons

Aryl

C7

Aromatic Halides (substituted)

Methyl Halides

Phenyls & Phenyl-Het

Fluorobenzene