ChemicalBook > CAS DataBase List > 4-Iodobenzyl bromide

4-Iodobenzyl bromide

Product Name
4-Iodobenzyl bromide
CAS No.
16004-15-2
Chemical Name
4-Iodobenzyl bromide
Synonyms
SKL242;EGFR-1（18-;R-Protopanoxadiol;p-odobenzyl bromide;P-IODOBENZYL BROMIDE;4-IODOBENZYL BROMIDE;à-bromo-4-iodotoluene;α-broMo-4-iodotoluene;4-IodobenzylBromide>4-Iodobenzyl bromide,97%
CBNumber
CB3421989
Molecular Formula
C7H6BrI
Formula Weight
296.93
MOL File
16004-15-2.mol
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4-Iodobenzyl bromide Property

Melting point:
78-82 °C(lit.)
Boiling point:
140°C 15mm
Density 
2.0672 (rough estimate)
refractive index 
1.6500 (estimate)
Flash point:
140°C/15mm
storage temp. 
2-8°C
form 
Adhering Crystalline Powder
color 
Light yellow
Water Solubility 
Insoluble in water.
Sensitive 
Light Sensitive/Lachrymatory
BRN 
2325160
InChI
InChI=1S/C7H6BrI/c8-5-6-1-3-7(9)4-2-6/h1-4H,5H2
InChIKey
BQTRMYJYYNQQGK-UHFFFAOYSA-N
SMILES
C1(CBr)=CC=C(I)C=C1
CAS DataBase Reference
16004-15-2(CAS DataBase Reference)
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Safety

Hazard Codes 
C,T
Risk Statements 
34-63-42/43-36/37/38
Safety Statements 
26-36/37/39-45-23
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
Hazard Note 
Corrosive/Lachrymatory/Light Sensitive
HazardClass 
IRRITANT
HazardClass 
8
PackingGroup 
Ⅱ
HS Code 
29039990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
515604
Product name
4-Iodobenzyl bromide
Purity
95%
Packaging
1g
Price
$34.8
Updated
2025/07/31
Sigma-Aldrich
Product number
515604
Product name
4-Iodobenzyl bromide
Purity
95%
Packaging
5g
Price
$103.94
Updated
2025/07/31
TCI Chemical
Product number
I0571
Product name
4-Iodobenzyl Bromide
Packaging
5G
Price
$62
Updated
2025/07/31
TCI Chemical
Product number
I0571
Product name
4-Iodobenzyl Bromide
Packaging
25G
Price
$277
Updated
2025/07/31
TRC
Product number
I737248
Product name
4-Iodobenzyl Bromide
Packaging
2.5g
Price
$75
Updated
2021/12/16
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4-Iodobenzyl bromide Chemical Properties,Usage,Production

Chemical Properties

light yellow adhering crystalline powder

Uses

4-Iodobenzyl bromide is used as an organic chemical synthesis intermediate.

Synthesis

624-31-7

16004-15-2

4-Iodotoluene (Compound 1C, 25 g) was added with N-bromosuccinimide (23.5 g) and benzoyl peroxide (375 mg) in carbon tetrachloride (375 ml) and heated to reflux for 7 hours under light conditions. After completion of the reaction, the mixture was stirred at room temperature overnight. Subsequently, the insoluble material was removed by filtration and the filtrate was concentrated under reduced pressure. The concentrated residue was recrystallized with ethyl acetate and hexane to afford the target product 4-iodobenzyl bromide (Compound 1D) in 60.3% yield. [0027] NMR hydrogen spectral data (CDCl3, with TMS as internal standard): δ 7.72 (d, 2H), 7.14 (d, 2H), 4.39 (s, 2H).

References

[1] Macromolecules, 2013, vol. 46, # 12, p. 4754 - 4763
[2] Acta Crystallographica Section C: Crystal Structure Communications, 2003, vol. 59, # 4, p. o216-o218
[3] Journal of Materials Chemistry C, 2015, vol. 3, # 4, p. 734 - 741
[4] Chemistry - An Asian Journal, 2017, vol. 12, # 6, p. 690 - 697
[5] Journal of Organic Chemistry, 2014, vol. 79, # 1, p. 223 - 229

4-Iodobenzyl bromide Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Iodobenzyl bromide Suppliers

Americas 1 Belgium 2 China 228 Europe 3 Germany 6 India 19 Japan 4 Poland 1 Slovakia 1 Switzerland 4 The Netherlands 1 Ukraine 1 United Kingdom 29 United States 42 Global 342
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View Lastest Price from 4-Iodobenzyl bromide manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd
Product
4-Iodobenzyl bromide 16004-15-2
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
Customise
Release date
2025-11-07
Shenzhen Nexcon Pharmatechs Ltd.
Product
4-Iodobenzyl bromide 16004-15-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
2000
Release date
2025-09-04
Hebei Chuanghai Biotechnology Co., Ltd
Product
4-Iodobenzyl bromide 16004-15-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-13

16004-15-2, 4-Iodobenzyl bromideRelated Search:

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