ChemicalBook > CAS DataBase List > METHYLDIPHENYLPHOSPHINE OXIDE

METHYLDIPHENYLPHOSPHINE OXIDE

Product Name
METHYLDIPHENYLPHOSPHINE OXIDE
CAS No.
2129-89-7
Chemical Name
METHYLDIPHENYLPHOSPHINE OXIDE
Synonyms
NSC 407134;AURORA KA-1600;JACS-2129-89-7;(C6H5)2(CH3)P=O;Methyldiphenyloxophosphine;diphenylmethylphosphineoxide;diphenylmethyl-phosphineoxid;METHYLDIPHENYLPHOSPHINE OXIDE;Diphenylmethylphosphine oxide;Phosphine oxide, methyldiphenyl-
CBNumber
CB3434640
Molecular Formula
C13H13OP
Formula Weight
216.22
MOL File
2129-89-7.mol
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METHYLDIPHENYLPHOSPHINE OXIDE Property

Melting point:
111-115 °C (lit.)
Boiling point:
180 °C / 1mmHg
Density 
1.12±0.1 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
almost transparency in Methanol
form 
solid
color 
White to Almost white
Sensitive 
Moisture Sensitive
BRN 
957291
CAS DataBase Reference
2129-89-7(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-37/39-36
WGK Germany 
3
RTECS 
SZ0199480
HS Code 
29029090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
454427
Product name
Methyldiphenylphosphine oxide
Purity
98%
Packaging
25g
Price
$281
Updated
2022/05/15
TCI Chemical
Product number
D2445
Product name
Methyl(diphenyl)phosphine Oxide
Purity
>98.0%(GC)
Packaging
10g
Price
$83
Updated
2024/03/01
Alfa Aesar
Product number
A11484
Product name
Methyldiphenylphosphine oxide, 98+%
Packaging
25g
Price
$114
Updated
2021/12/16
Alfa Aesar
Product number
A11484
Product name
Methyldiphenylphosphine oxide, 98+%
Packaging
5g
Price
$36.9
Updated
2021/12/16
TRC
Product number
M219488
Product name
Methyl(diphenyl)phosphine Oxide
Packaging
100mg
Price
$45
Updated
2021/12/16
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METHYLDIPHENYLPHOSPHINE OXIDE Chemical Properties,Usage,Production

Chemical Properties

white crystalline powder

Uses

Catalyst for:

  • Chlorination and bromination (halogenation) of alcohols under Appel conditions
  • Hydrosilylation reactions
  • Enantioselective cyanosilylation of ketones

Synthesis Reference(s)

Tetrahedron Letters, 32, p. 2493, 1991 DOI: 10.1016/S0040-4039(00)74363-2

METHYLDIPHENYLPHOSPHINE OXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYLDIPHENYLPHOSPHINE OXIDE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Methyl(diphenyl)phosphine Oxide 2129-89-7
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 Tons
Release date
2020-01-14
Career Henan Chemical Co
Product
METHYLDIPHENYLPHOSPHINE OXIDE 2129-89-7
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10 tons/month
Release date
2020-01-09

2129-89-7, METHYLDIPHENYLPHOSPHINE OXIDERelated Search:


  • (C6H5)2(CH3)P=O
  • Diphenylmethylphosphine oxide
  • diphenylmethyl-phosphineoxid
  • JACS-2129-89-7
  • diphenylmethylphosphineoxide
  • Phosphine oxide, methyldiphenyl-
  • AURORA KA-1600
  • METHYLDIPHENYLPHOSPHINE OXIDE
  • Methyl diphenyl phosphine oxide, 98+%
  • Methyl diphenyl phosphine oxide,99%
  • Methyldiphenyloxophosphine
  • NSC 407134
  • Methyldiphenylphosphine oxide 98%
  • Methyl(diphenyl)phosphineOxide&gt
  • [methyl(phenyl)phosphoryl]benzene
  • 2129-89-7
  • C13H13OP
  • CH3PC6H52O
  • Wittig & Horner-Emmons Reaction
  • Horner-Emmons Reaction
  • Catalysis and Inorganic Chemistry
  • Phosphine Ligands
  • Phosphorus Compounds
  • Horner-Emmons Reaction
  • Synthetic Organic Chemistry
  • Wittig & Horner-Emmons Reaction
  • Catalysis and Inorganic Chemistry
  • Phosphine Ligands
  • Phosphorus Compounds