TOLYLFLUANID
- Product Name
- TOLYLFLUANID
- CAS No.
- 731-27-1
- Chemical Name
- TOLYLFLUANID
- Synonyms
- B-49854;bay5212;BAY 5212;bay49854;bay5712a;EUPAREN M;ELVARON M;BAY 49854;BAY 5712a;kue13183b
- CBNumber
- CB3438572
- Molecular Formula
- C10H13Cl2FN2O2S2
- Formula Weight
- 347.26
- MOL File
- 731-27-1.mol
TOLYLFLUANID Property
- Melting point:
- 96°C
- Boiling point:
- 93℃
- Density
- 1.5132 (rough estimate)
- vapor pressure
- 2 x 10-5 Pa (20 °C)
- refractive index
- 1.6000 (estimate)
- storage temp.
- -20°C
- solubility
- soluble in DMSO, Methanol
- Colour Index
- 45430
- Water Solubility
- 0.9 mg l-1 (20 °C)
- pka
- -5.06±0.50(Predicted)
- BRN
- 2949607
- LogP
- 3.900
- EPA Substance Registry System
- Tolylfluanid (731-27-1)
Safety
- Hazard Codes
- T,N,T+
- Risk Statements
- 23-36/37/38-43-48/20-50/53-50-48/23-26
- Safety Statements
- 24-26-37-38-45-60-61-63-36/37/39-28
- RIDADR
- 2588
- WGK Germany
- 3
- RTECS
- WO6560000
- HazardClass
- 6.1(b)
- PackingGroup
- III
- Hazardous Substances Data
- 731-27-1(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H315Causes skin irritation
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H330Fatal if inhaled
H335May cause respiratory irritation
H372Causes damage to organs through prolonged or repeated exposure
H400Very toxic to aquatic life
- Precautionary statements
-
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P314Get medical advice/attention if you feel unwell.
N-Bromosuccinimide Price
- Product number
- 90619
- Product name
- Tolylfluanid
- Purity
- certified reference material, TraceCERT
- Packaging
- 50mg
- Price
- $247
- Updated
- 2024/03/01
- Product number
- 32060
- Product name
- Tolylfluanid
- Purity
- PESTANAL , analytical standard
- Packaging
- 250mg
- Price
- $130
- Updated
- 2024/03/01
- Product number
- T536730
- Product name
- Tolylfluanide
- Packaging
- 250mg
- Price
- $130
- Updated
- 2021/12/16
- Product number
- T536730
- Product name
- Tolylfluanide
- Packaging
- 2.5g
- Price
- $1050
- Updated
- 2021/12/16
- Product number
- 99614
- Product name
- Tolylfluanide
- Packaging
- 2.5g
- Price
- $1400
- Updated
- 2021/12/16
TOLYLFLUANID Chemical Properties,Usage,Production
Uses
Tolylfluanid is used to control a wide range of fungal diseases on apples, grapes, strawberries and other fruit and storage diseases on many crops.
Uses
Tolylfluanid may be used as a reference standard for the determination of the analyte in nutraceutical formulations using dispersive liquid-liquid microextraction(DLLME) coupled with gas chromatography-mass spectrometry method.
Definition
ChEBI: A member of the class of sulfamides that is dichlofluanid in which the hydrogen at the para position of the phenyl group is replaced by a methyl group. A fungicide first marketed in 1971 and used in the cultivation of fruit and vegetables, as ell as in wood preservatives, it is no longer approved for use in the European Union.
Metabolic pathway
Tolylfluanid contains an unstable dichlorofluoromethylthio (sulfenyl) moiety that has been shown to undergo rapid hydrolytic and metabolic degradation to dimethylaminosulfotoluidide (2). By analogy with captan, presumably the dichlorofluoromethylthio moiety can be transferred to the sulfur atoms of cellular thiols such as cysteine and glutathione. Thus, in the presence of thiols tolylfluanid is probably cleaved at the N-S bond to form thiophosgene or its monofluoro analogue (3) and other gaseous products such as hydrogen sulfide, hydrogen chloride and carbonyl sulfide. Thiophosgene or its monofluoro analogue is rapidly hydrolysed by water. The dichlorofluoromethylthio group and thiophosgene may be intermediates in the formation of addition products, for example addition to cysteine affords thiazolidine-2-thione-4-carboxylica cid (4). A thiazolidine derivative of glutathione may also be formed. The main metabolic reactions in all media were cleavage of the N-S bond to give dimethylaminosulfotoluidide (2) followed by hydroxylation of the phenyl ring and oxidation of the methyl substituent on the phenyl ring. Glucoside conjugates were detected in plants and the cysteine adduct, thiazolidine-2- thione-4-carboxylic acid (4), was formed in rats.
Degradation
Tolylfluanid is hydrolysed rapidly in alkaline conditions. The hydrolytic DT50 is about 12 days, 29 hours and <10 minutes at pH 4,7 and 9, respectively, at 22 °C. In the environment, hydrolysis is faster than photolysis (PM; PSD, 1995). Tolylfluanid does not absorb light of wavelength >295 nm and so photodegradation is unlikely to occur in the absence of photosensitisers.
TOLYLFLUANID Preparation Products And Raw materials
Raw materials
Preparation Products
TOLYLFLUANID Suppliers
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 94657
- Advantage
- 76
- Tel
- 025-57798810
- Fax
- 025-57019371
- sales@sunlidabio.com
- Country
- China
- ProdList
- 3239
- Advantage
- 55
- Tel
- 0755-89396905
- admin@nexconn.com
- Country
- China
- ProdList
- 299
- Advantage
- 55
- Tel
- 021-61415566 800-8193336
- orderCN@merckgroup.com
- Country
- China
- ProdList
- 51456
- Advantage
- 80
- Tel
- 022-6537-8550 15522853686
- Fax
- 022-2532-9655
- sales@altasci.com.cn
- Country
- China
- ProdList
- 4511
- Advantage
- 55
- Tel
- 4009903999 13395398332
- Fax
- 0539-6365991
- sales@xiyashiji.com
- Country
- China
- ProdList
- 20806
- Advantage
- 60
- Tel
- sales@njromanme.com
- Country
- China
- ProdList
- 4529
- Advantage
- 58
- Tel
- 10106090
- jjlchem2@163.com
- Country
- China
- ProdList
- 9981
- Advantage
- 58
- Tel
- 0755-0755-85201366 18938635012
- Fax
- 0755-85201366
- sales@regentsciences.com
- Country
- China
- ProdList
- 9590
- Advantage
- 58
- Tel
- 021-58111628 15800915896
- Fax
- QQ 3285589261
- sales@twochem.com
- Country
- China
- ProdList
- 1788
- Advantage
- 58
- Tel
- 010-52889049
- 2250970673@qq.com
- Country
- CHINA
- ProdList
- 1132
- Advantage
- 58
- Tel
- +86-400-002-6226 +86-13028896684;
- sales@rrkchem.com
- Country
- China
- ProdList
- 57423
- Advantage
- 58
- Tel
- 18081075745
- chemflowtech@sina.com
- Country
- China
- ProdList
- 1886
- Advantage
- 58
- Tel
- 18871490254
- Fax
- 027-59599243
- linda@hubeijusheng.com
- Country
- CHINA
- ProdList
- 28172
- Advantage
- 58
- Tel
- +86-023-6139-8061 +86-86-13650506873
- sales@chemdad.com
- Country
- China
- ProdList
- 39894
- Advantage
- 58
- Tel
- 18501792038; 18501792038
- shanpel@anpel.com.cn
- Country
- China
- ProdList
- 9611
- Advantage
- 58
- Tel
- 021-021-61109150
- Fax
- 021-61105897
- sales@tcisct.com
- Country
- China
- ProdList
- 31121
- Advantage
- 58
- Tel
- 029-81120477 17792793610
- 1033@dideu.com
- Country
- China
- ProdList
- 10011
- Advantage
- 58
- Tel
- 4001650900 13817534909
- 3003940895@qq.com
- Country
- China
- ProdList
- 10717
- Advantage
- 58
- Tel
- 021-021-59178156 15300768757
- 359382369@qq.com
- Country
- China
- ProdList
- 10674
- Advantage
- 58
- Tel
- 18516304666
- christina.feng@cpachem-sh.com
- Country
- China
- ProdList
- 3100
- Advantage
- 58
- Tel
- 021-34675735 19147740836
- 1986399151@qq.com
- Country
- China
- ProdList
- 9844
- Advantage
- 58
- Tel
- 13003551299 13003551299
- 2369399482@qq.com
- Country
- China
- ProdList
- 7566
- Advantage
- 58
- Tel
- 13795480948 13795480948
- 3450865996@qq.com
- Country
- China
- ProdList
- 4958
- Advantage
- 58
- Tel
- 4008-099-669
- 23419001name@qq.com
- Country
- CHINA
- ProdList
- 73043
- Advantage
- 58
- Tel
- 58896805
- 7993601name@qq.com
- Country
- CHINA
- ProdList
- 15620
- Advantage
- 58
- Tel
- 18153089275
- 3032079623@qq.com
- Country
- China
- ProdList
- 22695
- Advantage
- 58
- Tel
- +8618950047208
- ellena@amitychem.com
- Country
- China
- ProdList
- 43416
- Advantage
- 58
- Tel
- +8613817748580
- Fax
- 021-50175322
- cooperation@kean-chem.com
- Country
- China
- ProdList
- 40066
- Advantage
- 58
- Tel
- +86-0512-83500002 +8615195660023
- sales@senfeida.com
- Country
- China
- ProdList
- 23046
- Advantage
- 58
- Tel
- +86-18621343501; +undefined18621343501
- product@acmec-e.com
- Country
- China
- ProdList
- 33338
- Advantage
- 58
- Tel
- +86-852-30606658
- market18@leapchem.com
- Country
- China
- ProdList
- 43340
- Advantage
- 58
- Tel
- +86-89586680 +86-13289823923
- 1026@dideu.com
- Country
- China
- ProdList
- 8670
- Advantage
- 58
- Tel
- +86-057181025280; +8617767106207
- Fax
- 0571-85806285
- sales@molcore.com
- Country
- China
- ProdList
- 49734
- Advantage
- 58
- Tel
- --
- Fax
- --
- chenjw@absin.cn
- Country
- CHINA
- ProdList
- 6705
- Advantage
- 58
- Tel
- --
- Fax
- --
- info@zzsrm.com
- Country
- CHINA
- ProdList
- 6650
- Advantage
- 58
- Tel
- --
- Fax
- --
- Country
- CHINA
- ProdList
- 6672
- Advantage
- 58
- Tel
- --
- Fax
- --
- info@f-biology.com
- Country
- CHINA
- ProdList
- 6025
- Advantage
- 58
- Tel
- --
- Fax
- --
- kexianxun@gmail.com
- Country
- China
- ProdList
- 1037
- Advantage
- 50
- Tel
- --
- Fax
- --
- shxiyuanbio@163.com
- Country
- CHINA
- ProdList
- 6906
- Advantage
- 58
- Tel
- --
- Fax
- --
- 1562893815@qq.com
- Country
- CHINA
- ProdList
- 6936
- Advantage
- 58
- Tel
- --
- Fax
- --
- Country
- CHINA
- ProdList
- 6973
- Advantage
- 58
- Tel
- --
- Fax
- --
- 344843571@qq.com
- Country
- CHINA
- ProdList
- 6318
- Advantage
- 58
- Tel
- --
- Fax
- --
- 2453006496@qq.com
- Country
- CHINA
- ProdList
- 6184
- Advantage
- 58
- Tel
- --
- Fax
- --
- service@huadr.com
- Country
- China
- ProdList
- 750
- Advantage
- 43