ChemicalBook > CAS DataBase List > (1S)-(+)-(Camphorylsulfonyl)oxaziridine

(1S)-(+)-(Camphorylsulfonyl)oxaziridine

Product Name
(1S)-(+)-(Camphorylsulfonyl)oxaziridine
CAS No.
104322-63-6
Chemical Name
(1S)-(+)-(Camphorylsulfonyl)oxaziridine
Synonyms
(S)-(+)-(Camphorsulfonyl)Oxazi;(+)-(Camphorsulfonyl)oxaziridine;S-(10-Camphorsulfonyl)oxaziridine;(S)-(+)-(CAMPHORSULFONYL)OXAZIRIDINE;(S)-2,N-EPOXY-EXO-10,2-BORNANESULTAM;(+)-((CAMPHORYL)SULFONYL)OXAZIRIDINE;(S)-(+)-(Camphorylsulfonyl)oxaziridine;(1S)-(+)-(CAMPHORYLSULFONYL)OXAZIRIDINE;(1S)-(+)-(10-CAMPHORSULFONYL) OXAZIRINE;(1S)-(+)-(1-Camphorsulfonyl)oxaziridine
CBNumber
CB3447891
Molecular Formula
C10H15NO3S
Formula Weight
229.3
MOL File
104322-63-6.mol
More
Less

(1S)-(+)-(Camphorylsulfonyl)oxaziridine Property

Melting point:
172-174 °C(lit.)
alpha 
45 º (c=2, chloroform)
Boiling point:
317.6±25.0 °C(Predicted)
Density 
1.2486 (rough estimate)
refractive index 
1.5060 (estimate)
storage temp. 
2-8°C
solubility 
Chloroform (Sparingly), Methanol (Slightly)
pka
-11.75±0.40(Predicted)
form 
Crystals or Crystalline Powder
color 
White
optical activity
[α]28/D +45°, c = 2 in chloroform
BRN 
6274370
CAS DataBase Reference
104322-63-6(CAS DataBase Reference)
More
Less

Safety

Safety Statements 
22-24/25
WGK Germany 
3
10
HS Code 
29309090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
345350
Product name
(1S)-(+)-(10-Camphorsulfonyl)oxaziridine
Packaging
1g
Price
$153
Updated
2024/03/01
TCI Chemical
Product number
C1326
Product name
(2R,8aS)-(+)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
Purity
>95.0%(T)
Packaging
1g
Price
$46
Updated
2024/03/01
TCI Chemical
Product number
C1326
Product name
(2R,8aS)-(+)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
Purity
>95.0%(T)
Packaging
5g
Price
$147
Updated
2024/03/01
TRC
Product number
C175100
Product name
(1S)-(+)-(10-Camphorsulfonyl)oxaziridine
Packaging
5g
Price
$485
Updated
2021/12/16
ChemScene
Product number
CS-W008074
Product name
(1S)-(+)-(10-Camphorsulfonyl)oxaziridine
Purity
>98.0%
Packaging
100g
Price
$509
Updated
2021/12/16
More
Less

(1S)-(+)-(Camphorylsulfonyl)oxaziridine Chemical Properties,Usage,Production

Chemical Properties

(1S)-(+)-(Camphorylsulfonyl)oxaziridine is white crystall powder

Uses

(1S)-(+)-(Camphorylsulfonyl)oxaziridine is a useful synthetic intermediate. Used for asymmetric hydroxylation

Uses

(1S)-(+)-(10-Camphorsulfonyl)oxaziridine can be used:

  • To convert prochiral ketone enolates into optically active α-hydroxy ketones via enantioselective asymmetric oxidation.
  • In the synthesis of thymidine oligonucleotides connected through pyrophosphates.
  • In the asymmetric synthesis of proton pump inhibitors like (R)-Rabeprazole sodium and (R)-Lansoprazole sodium from the corresponding DBU salt of prochiral sulfide.
  • In the preparation of phosphonoacetate and thiophosphonoacetate oligodeoxynucleotides by oxidizing the corresponding phosphinoacetate.

(1S)-(+)-(Camphorylsulfonyl)oxaziridine Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(1S)-(+)-(Camphorylsulfonyl)oxaziridine Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
Advantage
66
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11655
Advantage
64
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9809
Advantage
59
More
Less

View Lastest Price from (1S)-(+)-(Camphorylsulfonyl)oxaziridine manufacturers

HebeiShuoshengImportandExportco.,Ltd
Product
(1S)-(+)-(Camphorylsulfonyl)oxaziridine 104322-63-6
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-05
Hebei Jingbo New Material Technology Co., Ltd
Product
(1S)-(+)-(Camphorylsulfonyl)oxaziridine 104322-63-6
Price
US $8.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20000
Release date
2023-12-27
Hebei Saisier Technology Co., LTD
Product
(1S)-(+)-(Camphorylsulfonyl)oxaziridine 104322-63-6
Price
US $6.00/KG
Min. Order
1KG
Purity
More than 99%
Supply Ability
2000KG/Month
Release date
2024-04-25

104322-63-6, (1S)-(+)-(Camphorylsulfonyl)oxaziridineRelated Search:


  • (+)-(2R,8AS)-(CAMPHORYLSULFONYL)OXAZIRIDINE
  • (2R,8AS)-(+)-(CAMPHORYLSULFONYL)OXAZIRIDINE
  • (1S)-(+)-2,N-EPOXY-EXO-10,2-BORNANESULTAM
  • (IS)-(+)-(10-Camphorsulfonyl)oxaziridine
  • S-(10-Camphorsulfonyl)oxaziridine
  • (4aS,7R,8aS)-9,9-DiMethyltetrahydro-4H-4a,7-Methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide
  • (+)-(2R,8aS)-10-(CaMphorylsulfonyl)oxaziridine
  • (4aS,7R,8aS)-Tetrahydro-9,9-diMethyl-4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole 3,3-Dioxide
  • (1S)-(+)-(Camphorylsulfonyl)oxaziridine, (1S)-(+)-2,N-Epoxy-exo-10,2-bornanesultam
  • (1α,5β,7α)-10,10-Dimethyl-4,5-epoxy-3-thia-4-azatricyclo[5.2.1.01,5]decane3,3-dioxide
  • (3aS)-9,9-Dimethyloctahydro-3aβ,6β-methano-1,7aα-epoxy-2,1-benzisothiazole 2,2-dioxide
  • (4aS,7R,8aS)-5,6,7,8-Tetrahydro-9,9-dimethyl-4H-4a,7-methanooxazirino[3,2-i][2,1]benzoisothiazole 3,3-dioxide
  • (4aS,7R,8aS)-9,9-Dimethyl-4H-4a,7-methanotetrahydrooxazirino[3,2-i][2,1]benzisothiazole 3,3-dioxide
  • (8aS)-5,6,7,8-Tetrahydro-9,9-dimethyl-4H-4aβ,7β-methanooxazirino[3,2-i][2,1]benzisothiazole 3,3-dioxide
  • (+)-(2R,8aS)-(Camphorylsulfonyl)oxaziridine,98+%
  • (4AS,7R,8aS)-9,9-Dimethyltetrahydro-4H-4a,7-methanobenzo-[c][1,2]oxazireno[2,3-b]isothiazole 3,3-
  • (1S)-(+)-(10-Camphorsulfonyl)oxaziridine (1S)-(+)-(Camphorylsulfonyl)oxaziridine
  • (S)-(+)-(Camphorylsulfonyl)oxaziridine
  • (4AS,7R,8aS)-9,9-Dimethyltetrahydro-4H-4a,7-methanobenzo-[c][1,2]oxazireno[2,3-b]isothiazole 3
  • (1S)-(+)-(CAMPHORYLSULFONYL)OXAZIRIDINE
  • (1S)-(+)-(10-CAMPHORSULFONYL)OXAZIRIDINE
  • (1S)-(+)-(10-CAMPHORSULPHONYL)OXAZIRIDINE
  • (S)-(+)-(CAMPHORSULFONYL)OXAZIRIDINE
  • (S)-2,N-EPOXY-EXO-10,2-BORNANESULTAM
  • (+)-((CAMPHORYL)SULFONYL)OXAZIRIDINE
  • (1S)-(+)-(10-Camphorsulfonyl)oxaziridine (1S)-(+)-2,N-Epoxy-exo-10,2-bornanesultam
  • (+)-(2R,8aS)-(Camphorylsulfonyl)oxaziridine, 99+% ee, 99+%
  • (S)-(+)-(Camphorsulfonyl)Oxazi
  • (1S)-(+)-(10-CAMPHORSULFONYL) OXAZIRINE
  • (2R 8AS)-(+)-(CAMPHORYLSULFONYL)OXAZIRIDINE [ASYMMETRIC OXIDIZING GR]
  • (2R,8aS)-(+)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
  • (S)-(10-Camphorsulfonyl)oxaziridine,99%e.e.
  • (+)-(2R, 8aS)-(Camphorylsulfonyl)oxaziridine, 99+%, (99+% e.e.)
  • (1S)-(+)-(1-Camphorsulfonyl)oxaziridine
  • (2R,8aS)-(+)-(Camphorylsulfonyl)oxaziridine[AsymmetricOxidizingReagent]&gt
  • 4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole, tetrahydro-9,9-dimethyl-, 3,3-dioxide, (4aS,7R,8aS)-
  • CAS104322-63-6 (1S)-(+)-(Camphorylsulfonyl)oxaziridine
  • (+)-(2R,8aS)-(Camphorylsulfonyl)oxaziridine
  • (+)-(Camphorsulfonyl)oxaziridine
  • (4aS,7S,8aS)-9,9-dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide
  • (1S,8R)-11,11-dimethyl-5-oxa-3λ?-thia-4-azatetracyclo[6.2.1.0?,?.0?,?]undecane-3,3-dione
  • (1S,8R)-11,11-dimethyl-5-oxa-3λ?-thia-4-azatetracyclo[6.2.1.01,?.0?,?]undecane-3,3-dione
  • 104322-63-6
  • C10H15NO3S
  • Hydroxylation
  • Asymmetric Synthesis
  • Sulfur Compounds (for Synthesis)
  • Bicyclic Monoterpenes
  • Oxidation
  • Terpenes
  • Chiral Catalysts, Ligands, and Reagents
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • Chiral Reagents
  • pharmacetical
  • chiral
  • Asymmetric Synthesis
  • Bicyclic Monoterpenes