ChemicalBook > CAS DataBase List > (1R)-(-)-(10-Camphorsulfonyl)oxaziridine

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

Product Name
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
CAS No.
104372-31-8
Chemical Name
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
Synonyms
(-)-CAMPHORSULFONYLOXAZIRIDINE;(10-camphorsulfonyl)oxaziridine;R-(10-Camphorsulfonyl)oxaziridine;(R)-2,N-EPOXY-EXO-10,2-BORNANESULTAM;(-)-((CAMPHORYL) SULFONYL)OXAZIRIDINE;(1R)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE;(1R)-(-)-(10-Camphorsulfonyl)oxaziridin;(1R)-(-)-(10-CAMPHORSULFONYL)OXAZIRIDINE;(1R)-(-)-2,N-EPOXY-EXO-10,2-BORNANESULTAM;(1R)-(-)-(10-CAMPHORSULPHONYL)OXAZIRIDINE
CBNumber
CB9768000
Molecular Formula
C10H15NO3S
Formula Weight
229.3
MOL File
104372-31-8.mol
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(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Property

Melting point:
170-174 °C
alpha 
-46.6 º (c=2, CHCl3 25 ºC)
Boiling point:
317.6±25.0 °C(Predicted)
Density 
1.2486 (rough estimate)
refractive index 
1.5060 (estimate)
Flash point:
170℃
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
-11.75±0.40(Predicted)
form 
Powder
color 
White
optical activity
[α]20/D 44°, c = 2.2 in chloroform
BRN 
6274369
CAS DataBase Reference
104372-31-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25
WGK Germany 
3
10
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
349003
Product name
(1R)-(?)-(10-Camphorsulfonyl)oxaziridine
Packaging
1g
Price
$109.2
Updated
2024/03/01
TCI Chemical
Product number
C1327
Product name
(2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
Purity
>95.0%(T)
Packaging
1g
Price
$30
Updated
2024/03/01
TCI Chemical
Product number
C1327
Product name
(2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
Purity
>95.0%(T)
Packaging
5g
Price
$88
Updated
2024/03/01
Alfa Aesar
Product number
H59544
Product name
(1R,2S)-(-)-2,N-Epoxy-10,2-camphorsultam, 96%
Packaging
1g
Price
$93.65
Updated
2024/03/01
TRC
Product number
C175095
Product name
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
Packaging
50g
Price
$405
Updated
2021/12/16
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(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Uses

Reactant involved in:

  • Asymmetric synthesis of proton pump inhibitors
  • Asymmetric synthesis of polyhydroxylated pyrrolidines
  • Diastereoselective hydroxylation of chlorophylls a and b enolate anions

Used in impregnated silica nanoparticles for removal of sulfur mustard from wastewater

Used to modify blebbistatin for investigations of myosin inhibitor design

Uses

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine is a useful synthetic intermediate. Used for asymmetric hydroxylation.

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Preparation Products And Raw materials

Raw materials

Preparation Products

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(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
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40241
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Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
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sales@dhltchem.com
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China
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793
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3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15848
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
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81
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
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Capot Chemical Co., Ltd
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+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
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Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
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View Lastest Price from (1R)-(-)-(10-Camphorsulfonyl)oxaziridine manufacturers

Hebei Duling International Trade Co. LTD
Product
(1(R))-()-(10-Camphorsulfonyl)oxaziridine 104372-31-8
Price
US $20.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 tons
Release date
2022-09-16
Hebei Mojin Biotechnology Co., Ltd
Product
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine 104372-31-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-17
Aromsyn Co., Ltd.
Product
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine 104372-31-8
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
kgs
Release date
2023-02-17

104372-31-8, (1R)-(-)-(10-Camphorsulfonyl)oxaziridineRelated Search:


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  • 104372-31-8
  • Oxidation
  • Bicyclic Monoterpenes
  • Terpenes
  • Sulfur Compounds (for Synthesis)
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Hydroxylation
  • Biochemistry
  • Oxidation
  • Sulfur Compounds (for Synthesis)
  • Synthetic Organic Chemistry
  • Terpenes
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • Asymmetric Synthesis
  • Bicyclic Monoterpenes
  • chiral
  • Chiral Reagents