ChemicalBook > CAS DataBase List > (1R)-(-)-(10-Camphorsulfonyl)oxaziridine

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

Product Name
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
CAS No.
104372-31-8
Chemical Name
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
Synonyms
(-)-CAMPHORSULFONYLOXAZIRIDINE;(10-camphorsulfonyl)oxaziridine;R-(10-Camphorsulfonyl)oxaziridine;(R)-2,N-EPOXY-EXO-10,2-BORNANESULTAM;(-)-((CAMPHORYL) SULFONYL)OXAZIRIDINE;(1R)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE;(1R)-(-)-(10-Camphorsulfonyl)oxaziridin;(1R)-(-)-(10-CAMPHORSULFONYL)OXAZIRIDINE;(1R)-(-)-2,N-EPOXY-EXO-10,2-BORNANESULTAM;(1R)-(-)-(10-CAMPHORSULPHONYL)OXAZIRIDINE
CBNumber
CB9768000
Molecular Formula
C10H15NO3S
Formula Weight
229.3
MOL File
104372-31-8.mol
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(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Property

Melting point:
170-174 °C
alpha 
-46.6 º (c=2, CHCl3 25 ºC)
Boiling point:
317.6±25.0 °C(Predicted)
Density 
1.2486 (rough estimate)
refractive index 
1.5060 (estimate)
Flash point:
170℃
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
-11.75±0.40(Predicted)
form 
Powder
color 
White
optical activity
[α]20/D 44°, c = 2.2 in chloroform
BRN 
6274369
CAS DataBase Reference
104372-31-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25
WGK Germany 
3
F 
10
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
349003
Product name
(1R)-(?)-(10-Camphorsulfonyl)oxaziridine
Packaging
1g
Price
$109.2
Updated
2024/03/01
TCI Chemical
Product number
C1327
Product name
(2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
Purity
>95.0%(T)
Packaging
1g
Price
$30
Updated
2024/03/01
TCI Chemical
Product number
C1327
Product name
(2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
Purity
>95.0%(T)
Packaging
5g
Price
$88
Updated
2024/03/01
Alfa Aesar
Product number
H59544
Product name
(1R,2S)-(-)-2,N-Epoxy-10,2-camphorsultam, 96%
Packaging
1g
Price
$93.65
Updated
2024/03/01
TRC
Product number
C175095
Product name
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
Packaging
50g
Price
$405
Updated
2021/12/16
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(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Uses

Reactant involved in:

  • Asymmetric synthesis of proton pump inhibitors
  • Asymmetric synthesis of polyhydroxylated pyrrolidines
  • Diastereoselective hydroxylation of chlorophylls a and b enolate anions

Used in impregnated silica nanoparticles for removal of sulfur mustard from wastewater

Used to modify blebbistatin for investigations of myosin inhibitor design

Uses

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine is a useful synthetic intermediate. Used for asymmetric hydroxylation.

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Preparation Products And Raw materials

Raw materials

Preparation Products

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(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Suppliers

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View Lastest Price from (1R)-(-)-(10-Camphorsulfonyl)oxaziridine manufacturers

Hebei Duling International Trade Co. LTD
Product
(1(R))-()-(10-Camphorsulfonyl)oxaziridine 104372-31-8
Price
US $20.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 tons
Release date
2022-09-16
Hebei Mojin Biotechnology Co., Ltd
Product
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine 104372-31-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-17
Aromsyn Co., Ltd.
Product
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine 104372-31-8
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
kgs
Release date
2023-02-17

104372-31-8, (1R)-(-)-(10-Camphorsulfonyl)oxaziridineRelated Search:

Resin epoxy White camphor oil (1R)-(-)-10-Camphorsulfonic acid 2-Methylcyclohexylamine 2-CYCLOPENTYL-ETHYLAMINE Cyclopentylamine Ethanesulfonamide 3-METHYLCYCLOHEXYLAMINE BORNYLAMINE 2-Ethyl-1-hexanethiol (1S)-(+)-(10-CAMPHORSULFONYL)OXAZIRIDINE,(1S)-(+)-(10-Camphorsulfonyl)oxaziridine (1S)-(+)-2,N-Epoxy-exo-10,2-bornanesultam Camphor DL-Camphor EPOXY 1-PENTANESULFONAMIDE 4-04-00-00045 (Beilstein Handbook Reference) 1-HEXANESULFONAMIDE PROPANE-1-SULFONAMIDE

  • (-)-(2S,8AR)-(CAMPHORSULFONYL)OXAZIRIDINE
  • (2S,8AR)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE
  • (1R)-(-)-(10-CAMPHORSULFONYL)OXAZIRIDINE
  • (1R)-(-)-(10-CAMPHORSULPHONYL)OXAZIRIDINE
  • (1R)-(-)-2,N-EPOXY-EXO-10,2-BORNANESULTAM
  • (1R)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE
  • (R)-2,N-EPOXY-EXO-10,2-BORNANESULTAM
  • (-)-((CAMPHORYL) SULFONYL)OXAZIRIDINE
  • (2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]
  • (-)-CAMPHORSULFONYLOXAZIRIDINE
  • (-)-(2S,8aR)-(Camphorylsulfonyl)oxaziridine, 99+% ee, 99+%
  • 4H-4a,7-Methanooxazirino3,2-i2,1benzisothiazole, tetrahydro-9,9-dimethyl-, 3,3-dioxide, (4aR,7S,8aR)-
  • (2S,8AS)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE
  • (2S 8AR)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE [ASYMMETRIC OXIDIZING GRADE] 98+%
  • R-(10-Camphorsulfonyl)oxaziridine
  • Tetrahydro-9,9-dimethyl-4H-4a,7-methanooxazirino[3,2-i][2,1]benzisothiazole 3,3-dioxide
  • (10-camphorsulfonyl)oxaziridine
  • (1R)-(-)-(Camphorylsulfonyl)oxaziridine, (1R)-(-)-2,N-Epoxy-exo-10,2-bornanesultam
  • (-)-(2S,8AR)-(Camphorylsulfonyl)oxaziridine, 98%, ee:99+%
  • (-)-(2S,8aR)-(Camphorylsulfonyl)oxaziridine, 99+% ee
  • (-)-(2S,8aR)-(Camphorylsulfonyl)oxaziridine,98+%
  • (4aR,7S,8aR)-Tetrahydro-9,9-diMethyl-4H-4a,7-Methano-1,2-oxazirino[3,2-i]-2,1-benzisothiazole 3,3-Dioxide
  • (1R,2S)-(-)-2,N-Epoxy-10,2-caMphorsultaM, 96%
  • (1R)-(-)-(10-Camphorsulfonyl)oxaziridine 1R)-(-)-(Camphorylsulfonyl)oxaziridine
  • (R)-(10-Camphorsulfonyl)oxaziridine,99%e.e.
  • 7,7-dimethyl-4-(2-oxaziridinylsulfonylmethyl)-3-bicyclo[2.2.1]heptanone
  • (1R)-(-)-(10-Camphorsulfonyl)oxaziridin
  • (2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]&gt
  • (-)-(2S,8aR)-(Camphorylsulfonyl)oxaziridine
  • 4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole, tetrahydro-9,9-dimethyl-, 3,3-dioxide, (4aR,7S,8aR)- (9CI, ACI)
  • Tetrahydro-9,9-dimethyl-4H-4a,7-methanooxazirino3,2-i2,1benzisothiazole 3,3-dioxide (4aR,7S,8aR)-
  • 104372-31-8
  • Oxidation
  • Bicyclic Monoterpenes
  • Terpenes
  • Sulfur Compounds (for Synthesis)
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Hydroxylation
  • Biochemistry
  • Oxidation
  • Sulfur Compounds (for Synthesis)
  • Synthetic Organic Chemistry
  • Terpenes
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • Asymmetric Synthesis
  • Bicyclic Monoterpenes
  • chiral
  • Chiral Reagents