ChemicalBook > CAS DataBase List > (Methoxymethyl)triphenylphosphonium chloride

(Methoxymethyl)triphenylphosphonium chloride

Product Name
(Methoxymethyl)triphenylphosphonium chloride
CAS No.
4009-98-7
Chemical Name
(Methoxymethyl)triphenylphosphonium chloride
Synonyms
MMC;MTPPC;DOMIT-012;AURORA KA-1153;(MethoxymethyL;phosphonium chL;Methoxymethyl triphe;Triphenyl(methoxymethyl)phosphonium;METHOXYMETHYL-TRIPHENYLPHOSPHONIUM-;methoxymethyl(triphenyl)phosphanium
CBNumber
CB3455456
Molecular Formula
C20H20ClOP
Formula Weight
342.8
MOL File
4009-98-7.mol
More
Less

(Methoxymethyl)triphenylphosphonium chloride Property

Melting point:
185-195 °C (dec.)(lit.)
bulk density
450-500kg/m3
vapor pressure 
<1 hPa ( 20 °C)
Flash point:
>250°C
storage temp. 
Store below +30°C.
solubility 
>1100g/l soluble,(decomposition)
form 
Crystalline Powder
color 
White to almost white
PH
2.2 (1100g/l, H2O, 20℃)
Water Solubility 
decomposes
Sensitive 
Hygroscopic
BRN 
924215
InChIKey
SJFNDMHZXCUXSA-UHFFFAOYSA-M
LogP
-1.17
CAS DataBase Reference
4009-98-7(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38
Safety Statements 
26-36-24/25
RIDADR 
UN 1390 4.3/PG 2
WGK Germany 
3
3-10
Hazard Note 
Harmful
HS Code 
29310095
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
309567
Product name
(Methoxymethyl)triphenylphosphonium chloride
Purity
97%
Packaging
25g
Price
$65.1
Updated
2025/07/31
Sigma-Aldrich
Product number
8.18580
Product name
Methoxymethyl-triphenylphosphonium chloride
Purity
for synthesis
Packaging
50G
Price
$103
Updated
2025/07/31
Sigma-Aldrich
Product number
309567
Product name
(Methoxymethyl)triphenylphosphonium chloride
Purity
97%
Packaging
100g
Price
$135
Updated
2025/07/31
TCI Chemical
Product number
M0828
Product name
(Methoxymethyl)triphenylphosphonium Chloride
Purity
>99.0%(HPLC)
Packaging
25g
Price
$27
Updated
2025/07/31
TCI Chemical
Product number
M0828
Product name
(Methoxymethyl)triphenylphosphonium Chloride
Purity
>99.0%(HPLC)
Packaging
100g
Price
$75
Updated
2025/07/31
More
Less

(Methoxymethyl)triphenylphosphonium chloride Chemical Properties,Usage,Production

Chemical Properties

WHITE TO ALMOST WHITE FINE CRYSTALLINE POWDER

Uses

(Methoxymethyl)triphenylphosphonium chloride is used as a phase transfer catalyst and in the synthesis of taxol-A fragment. It is widely used in the synthesis of pharmaceutical product cephalotaxine, which is used as an antiviral and antitumor agent.

Uses

Intermediates of Liquid Crystals

Uses

PTC catalyst

reaction suitability

reaction type: C-C Bond Formation

Synthesis

107-30-2

603-35-0

4009-98-7

The general procedure for the synthesis of (methoxymethyl)triphenylphosphonium chloride from chloromethyl methyl ether and triphenylphosphine was as follows: 20.0 g of triphenylphosphine was placed in a round-bottomed flask, dissolved in an appropriate amount of toluene, and heated to 95°C. The reaction was carried out at a constant temperature for 16 hours. Subsequently, 6.37 mL of chloromethyl methyl ether was slowly added dropwise and the reaction was kept at temperature for 16 hours. Upon completion of the reaction, the reaction mixture was cooled to room temperature and the solid product was collected by filtration. The filter cake was washed three times with toluene to remove impurities and then dried to give 25.4 g of white phosphonium salt in 97.3% yield.

References

[1] Synthesis (Germany), 2013, vol. 45, # 5, p. 596 - 600
[2] Patent: CN107936009, 2018, A. Location in patent: Paragraph 0042; 0087-0088
[3] Bulletin of the Chemical Society of Japan, 1980, vol. 53, # 12, p. 3436 - 3438
[4] Patent: CN106588982, 2017, A. Location in patent: Paragraph 0008; 0017; 0018; 0019; 0020; 0021; 0022-0025
[5] Journal of the American Chemical Society, 1976, vol. 98, p. 6613 - 6623

(Methoxymethyl)triphenylphosphonium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(Methoxymethyl)triphenylphosphonium chloride Suppliers

Nanjing Yihua Biotechnology Co., Ltd
Tel
13429882898
Email
1096323105@qq.com
Country
China
ProdList
291
Advantage
58
Shouguang Jiasheng Chemical Co., Ltd.
Tel
0536-7971999 13583611556
Fax
0536-7971999
Email
sgjiasheng@hotmail.com
Country
China
ProdList
300
Advantage
58
Nanjing Dilu Pharmaceutical Co., Ltd
Tel
18014482516; 18014482516
Email
977144864@qq.com
Country
China
ProdList
419
Advantage
58
Hebei Han'en New Material Technology Co., Ltd
Tel
18032751346
Email
2929218726@qq.com
Country
China
ProdList
27
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15838
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2338
Advantage
56
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
18515581800 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
9400
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2805
Advantage
65
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12000
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9310
Advantage
66
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
Advantage
64
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9883
Advantage
59
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
16077
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527621225
Email
1791901229@qq.com
Country
China
ProdList
6945
Advantage
52
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Tangshan Moneide Trading Co., Ltd.
Tel
0315-8309571 15633399667
Fax
+86-315-7726572
Email
sales@moneidechem.com
Country
China
ProdList
704
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11705
Advantage
57
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9815
Advantage
79
Nanjing Vital Chemical Co., Ltd.
Tel
Please Send Email 18652950785
Fax
025-87193546
Email
chemweiao@163.com
Country
China
ProdList
4378
Advantage
65
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Spectrum Chemical Manufacturing Corp.
Tel
021-021-021-67601398-809-809-809 15221380277
Fax
021-57711696
Email
marketing_china@spectrumchemical.com
Country
China
ProdList
9658
Advantage
60
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
Shanghai civi chemical technology co.,Ltd
Tel
86-21-34053660
Fax
86-21-34053661
Email
sale@labgogo.com
Country
China
ProdList
9865
Advantage
52
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Shanghai Topbiochem Technology Co., Ltd
Tel
021-58170097
Email
info@topbiochem.com
Country
China
ProdList
9510
Advantage
58
Shanghai T&W Pharmaceutical Co., Ltd.
Tel
+86 21 61551611
Fax
+86 21 50676805
Country
China
ProdList
9891
Advantage
58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19913
Advantage
55
Shanghai Jian Chao Chemical Technology Co., Ltd.
Tel
150-2103-5486 18017383231
Fax
qq:2817624287
Email
983544897@qq.com
Country
China
ProdList
9342
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
18209
Advantage
56
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-6206333 13167063860
Fax
021-50323701
Email
anhua.mao@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
The future of Shanghai Industrial Co., Ltd.
Tel
021-61552785
Fax
021-55660885
Email
sales@shshiji.com
Country
China
ProdList
9546
Advantage
55
Cantotech Chemicals, Ltd.
Tel
86-0755-86635001
Fax
86-0755-22642228
Email
cantotech@126.com
Country
China
ProdList
4566
Advantage
55
Wuxi QianFeng Chemical Technology Co., Ltd.
Tel
0510-82860650
Fax
0510-82025215
Email
qfhg@qianfengchem.com
Country
China
ProdList
36
Advantage
55
Shandong Xinhua Pharmceutical Co.,LTD
Tel
0533-0533-2196801
Fax
0533-2196817
Email
yaojianyong@xhzy.com
Country
China
ProdList
70
Advantage
60
Shanghai Huikai Chemical Technology Co., Ltd.
Tel
021-61995394 18916691159
Email
chemicalsea@163.com
Country
China
ProdList
1972
Advantage
58
Quzhou Juhua Friendship Co., Ltd
Tel
0570-3066667
Fax
0570-3063388
Country
China
ProdList
3930
Advantage
58
Shanghai GAOXIANG Chemical Co., Ltd.
Tel
021-57816257 18930243658
Fax
021-57816257
Email
fecpo@139.com
Country
China
ProdList
295
Advantage
55
Shanghai JONLN Reagent Co., Ltd.
Tel
400-0066400 13621662912
Fax
021-55660885
Email
422131432@qq.com
Country
China
ProdList
9979
Advantage
55
More
Less

View Lastest Price from (Methoxymethyl)triphenylphosphonium chloride manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
(Methoxymethyl)triphenylphosphonium chloride 4009-98-7
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-23
Hebei Chuanghai Biotechnology Co., Ltd
Product
(Methoxymethyl)triphenylphosphonium chloride 4009-98-7
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-25
Henan Aochuang Chemical Co.,Ltd.
Product
(Methoxymethyl)triphenylphosphonium chloride 4009-98-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-10

4009-98-7, (Methoxymethyl)triphenylphosphonium chlorideRelated Search:


  • MMC
  • AURORA KA-1153
  • (METHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE
  • METHOXYMETHYL-TRIPHENYLPHOSPHONIUM-
  • [1aS-(1aa,8b,8aa,8ba)-6-Amino-8-[[(aminocarbonyl)oxy]methyl]-1,1a,2,8,8a,8b-hexahydro-8a-methoxy-5-methylazirino[2,3,4]pyrrolo[1,2-a]indole-4,7-dione
  • Phosphonium, (methoxymethyl)triphenyl-, chloride
  • METHOXY METHYL TRIPHENYL PHOSPHONIUM CHLORIDE LOW WATER
  • (METHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE, 98+%
  • Triphenyl(methoxymethyl)phosphonium
  • Triphenyl(methoxymethyl)phosphonium·chloride
  • Methoxymethyl triphe
  • (Methoxymethyl)triphenylphosphonium chloride ,97.5%
  • (Methoxymethyl)tris(phenyl)phosphonium chloride
  • Methoxymethyl-triphenylphosphomium Chloride
  • PhosphoniuM,(MethoxyMethyl)triphenyl-, chloride (1:1)
  • (MethoxyMethyl)triphenylphosphoniuM chloride 97%
  • (MethoxyMethyl)triphenylphosphoniuM chloride, 97.5%, 97.5%
  • Methoxymethyl-triphenylphosphanium chloride
  • (Methoxymethyl)triphenylphodphonium Chloride
  • [1aS-(1aa,8b,8aa,8ba)-6-Amino-8-[[(aminocarbonyl)oxy]methyl]-1,1a,2,8,8a,8b-hexahydro-8a-methoxy-5-m
  • DOMIT-012
  • (MethoxymethyL
  • phosphonium chL
  • MTPPC
  • (Methoxymethyl)triphenylphosphonium Chloride &gt
  • (Methoxymethyl)triphenylphosphonium chloride, 97.5%, for synthesis
  • (Methoxymethyl)Triphenylphosphonium Chloride,>99%
  • METHOXYMETHYL-TRIPHENYLPHOSPHONIUM CHLOR
  • (METOXMETHYL) TRIPHENYL PHOSPHONIUM CHLORIDE
  • Methoxy methyl triphenyl phosphorus chloride
  • Methoxy methyl triphenylphosphine chloride
  • (Methoxymethyl) triphenyl phosphonium Chloride Solid
  • methoxymethyl(triphenyl)phosphanium
  • (Methoxymethyl)triphenylphosphonium chloride (6CI, 7CI)
  • Triphenylphosphine chloromethyl ether
  • (Methoxymethyl)triphenylphosphonium Chloride(TPP-MOC)
  • 4009-98-7
  • 10399-39-2
  • C20H20OClP
  • C20H20ClOP
  • CH3OCH2PC6H53Cl
  • C6H53PClCH2OCH3
  • C-C Bond Formation
  • Wittig Reaction
  • Phosphonium Compounds
  • Wittig & Horner-Emmons Reaction
  • Olefination
  • Synthetic Reagents
  • Wittig Reagents
  • Phosphonium Compounds
  • Synthetic Organic Chemistry
  • Wittig & Horner-Emmons Reaction
  • Wittig Reaction
  • C-C Bond Formation
  • Olefination
  • Wittig Reagents