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Ethyl methyl carbonate

Product Name
Ethyl methyl carbonate
CAS No.
623-53-0
Chemical Name
Ethyl methyl carbonate
Synonyms
Methylethylcarbonate;EthylMethylCarbonate(Emc);Carbonic acid methyl ethyl;Carbonic acid ethyl methyl;Ethoxyacetic acid, methyl ester;Carbonic acid methyl ethyl ester;ETHYL METHYL CARBONATE;Ethyl Methyl carbonate 98%;Ethyl Methyl Carbonate >METHYL ETHYL CARBONATE (EMC)
CBNumber
CB3459272
Molecular Formula
C4H8O3
Formula Weight
104.1
MOL File
623-53-0.mol
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Ethyl methyl carbonate Property

Melting point:
-14.5℃
Boiling point:
107 °C
Density 
1.006 g/mL at 25 °C
vapor pressure 
43hPa at 25℃
refractive index 
n20/D 1.378
Flash point:
23°C
storage temp. 
2-8°C
form 
clear liquid
color 
Colorless to Almost colorless
Water Solubility 
46.8-47.1g/L at 20℃
InChI
InChI=1S/C4H8O3/c1-3-7-4(5)6-2/h3H2,1-2H3
InChIKey
JBTWLSYIZRCDFO-UHFFFAOYSA-N
SMILES
C(OC)(=O)OCC
LogP
0.972 at 40℃
CAS DataBase Reference
623-53-0(CAS DataBase Reference)
NIST Chemistry Reference
C2H5OCOOCH3(623-53-0)
EPA Substance Registry System
Carbonic acid, ethyl methyl ester (623-53-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
10-36/37/38
Safety Statements 
16-36/37-26
RIDADR 
3272
WGK Germany 
3
HazardClass 
3
PackingGroup 
III
HS Code 
29209090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
752002
Product name
Ethyl methyl carbonate
Purity
98%
Packaging
10ml
Price
$98.4
Updated
2024/03/01
Sigma-Aldrich
Product number
752002
Product name
Ethyl methyl carbonate
Purity
98%
Packaging
50ml
Price
$186
Updated
2024/03/01
TCI Chemical
Product number
C1342
Product name
Ethyl Methyl Carbonate
Purity
>98.0%(GC)
Packaging
10mL
Price
$59
Updated
2024/03/01
TCI Chemical
Product number
C1342
Product name
Ethyl Methyl Carbonate
Purity
>98.0%(GC)
Packaging
25mL
Price
$116
Updated
2024/03/01
Sigma-Aldrich
Product number
809934
Product name
Ethyl methyl carbonate
Purity
99.9%, acid <10 ppm, H2O <10ppm
Packaging
25g
Price
$272
Updated
2024/03/01
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Ethyl methyl carbonate Chemical Properties,Usage,Production

Description

Ethyl methyl carbonate (EMC) is an asymmetric aliphatic organic carbonate. It is a colorless transparent liquid widely used as an excellent solvent for lithium-ion battery electrolytes. EMC increases the solubility of lithium ions improving the capacity density and power of batteries. This compound has excellent thermal conductivity and low electrical resistance, extending the working temperature range of electrolytes, improving lithium batteries' safety, and prolonging their service life. EMC is usually obtained by metal oxide-catalyzed transesterification over dimethyl carbonate and diethyl carbonate. High percentage yields are obtained if the reaction is carried out in liquid or vapor phase[1].

Uses

Non-aqueous solvent for Li-ion batteries

Uses

Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.

Uses

EMC is majorly utilized as a co-solvent in the nonaqueous electrolyte. It enhances the energy density and discharge capacity of lithium-ion batteries.

General Description

This product has been enhanced for energy efficiency.

Advantages

Ethyl methyl carbonate enables the largest reversible capacity, best cycle stability, highest cycle Coulombic efficiency, lowest onset potential, smallest polarization, lowest self-discharge rate, and best rate performance from graphite compared to dimethyl carbonate and diethyl carbonate. Ethyl methyl carbonate forms a thinner layer of cathode electrolyte interface on the graphite surface with fewer Li–F and ROCO2Li species than with dimethyl carbonate and diethyl carbonate[2].

References

[1] Guido N. Rimondino , Fabio E. Malanca, Jesús A. Vila . “Atmospheric oxidation of ethyl methyl carbonate: Kinetics and reaction mechanism.” Journal of Photochemistry and Photobiology A-chemistry 444 (2023): Article 114994.
[2] Yao Wang. “Unlocking the True Capability of Graphite-Based Dual-Ion Batteries with Ethyl Methyl Carbonate Electrolyte.” ACS Applied Energy Materials 2 10 (2019): 7512–7517.

Ethyl methyl carbonate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Ethyl methyl carbonate manufacturers

Jinan Finer Chemical Co., Ltd
Product
Ethyl methyl carbonate 623-53-0
Price
US $2.00/KG
Min. Order
1KG
Purity
99.9%
Supply Ability
5000mt
Release date
2023-10-13
Henan Fengda Chemical Co., Ltd
Product
Ethyl methyl carbonate 623-53-0
Price
US $50.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-22
Zibo Hangyu Biotechnology Development Co., Ltd
Product
Ethyl methyl carbonate 623-53-0
Price
US $0.10-0.30/kg
Min. Order
1kg
Purity
99.99%
Supply Ability
20 tons
Release date
2024-01-16

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