ChemicalBook > CAS DataBase List > (4-BROMOBENZYL)METHYLAMINE

(4-BROMOBENZYL)METHYLAMINE

Uses

Product Name: (4-BROMOBENZYL)METHYLAMINE
CAS No.: 699-03-6
Chemical Name: (4-BROMOBENZYL)METHYLAMINE
Synonyms: Aids107181;Aids-107181;(4-BROMOBENZYL)METHY;874-73-7 (Hydrochloride);(4-BROMOBENZYL)METHYLAMINE;4-BROMO-N-METHYLBENZYLAMINE;N-Methyl-4-bromobenzylamine;(4-Bromobenzyl)methylamine95%;(4-Bromobenzyl)Methylamine 95%;4-Bromo-N-methylbenzylamine 97%
CBNumber: CB3478655
Molecular Formula: C8H10BrN
Formula Weight: 200.08
MOL File: 699-03-6.mol

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(4-BROMOBENZYL)METHYLAMINE Property

Boiling point:: 218-219 °C(lit.)
Density: 1.00 g/mL at 25 °C(lit.)
refractive index: n20/D 1.5650(lit.)
Flash point:: >230 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
pka: 9.52±0.10(Predicted)
Appearance: Colorless to light yellow Liquid
Sensitive: Air Sensitive
InChIKey: URFJXIULELMVHV-UHFFFAOYSA-N
CAS DataBase Reference: 699-03-6

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Safety

Hazard Codes: Xn
Risk Statements: 22
Safety Statements: 36
WGK Germany: 2

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 631140
Product name: 4-Bromo-N-methylbenzylamine
Purity: 97%
Packaging: 1g
Price: $76.3
Updated: 2025/07/31

Sigma-Aldrich

Product number: 631140
Product name: 4-Bromo-N-methylbenzylamine
Purity: 97%
Packaging: 5g
Price: $256
Updated: 2025/07/31

TRC

Product number: B700243
Product name: 1-(4-Bromophenyl)-N-methylmethanamine
Packaging: 100mg
Price: $75
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB129598
Product name: (4-Bromobenzyl)methylamine hydrochloride
Packaging: 100mg
Price: $58
Updated: 2021/12/16

Matrix Scientific

Product number: 071762
Product name: (4-Bromobenzyl)methylamine
Purity: 95+%
Packaging: 1g
Price: $70
Updated: 2021/12/16

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(4-BROMOBENZYL)METHYLAMINE Chemical Properties,Usage,Production

Uses

N-Methyl-4-bromobenzylamine is an important chemical raw material and pharmaceutical intermediate, such as being used to prepare benzofuran-based poly(ADP-ribose) polymerase (PARP) inhibitors.

Synthesis

1122-91-4

74-89-5

699-03-6

General procedure for the synthesis of N-methyl-4-bromobenzylamine: In an autoclave, 4-bromobenzaldehyde (2.08 g, 11.55 mmol) was mixed with a methanolic solution of 2 M methylamine (25 mL, 33.44 mmol) and the reaction was stirred at 65 °C for 4 hours. After completion of the reaction, cooled to room temperature, sodium borohydride (633 mg, 16.72 mmol) was added in batches. Stirring was continued for 30 minutes at room temperature, followed by vacuum concentration. The residue was dissolved in ethyl acetate (30 mL) and the organic layer was washed with saturated aqueous sodium bicarbonate. The aqueous phase was adjusted to pH 13 with a few drops of 1 N sodium hydroxide solution and then extracted twice with ethyl acetate. The organic extracts were combined, washed with brine, dried over anhydrous magnesium sulfate, filtered and concentrated under reduced pressure to give N-methyl-4-bromobenzylamine as a colorless oil (2.04 g, 91% yield), which was used directly in the next step of the reaction.LC-MS analysis (Analytical Condition A, Zorbax SB-AQ columns, Acidic conditions): retention time t R = 0.61 min; [M + H]+ = 241.06 (acetonitrile adduct).

References

[1] Patent: WO2010/58353, 2010, A1. Location in patent: Page/Page column 77-78
[2] Patent: US2011/224210, 2011, A1. Location in patent: Page/Page column 54
[3] Phosphorus, Sulfur and Silicon and the Related Elements, 1993, vol. 78, # 1-4, p. 141 - 152
[4] Organic Letters, 2014, vol. 16, # 2, p. 358 - 361

(4-BROMOBENZYL)METHYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (4-BROMOBENZYL)METHYLAMINE manufacturers

Career Henan Chemical Co

Product: (4-BROMOBENZYL)METHYLAMINE 699-03-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 150KG
Release date: 2019-07-01

699-03-6, (4-BROMOBENZYL)METHYLAMINERelated Search:

STATIL 3,4,5,6-TETRABROMOPHTHALIMIDE 4-Bromo-3,5-dihydroxy-N-methylbenzamide (3-BROMOBENZYL)METHYLAMINE,(3-Bromobenzyl)methylamine95% (4-BROMOBENZYL)DIMETHYLAMINE Halofuginone Lactate (2-Bromobenzyl)methylamine95%,(2-BROMOBENZYL)METHYLAMINE 4-Bromobenzylamine 4-bromo-N-(4-methylphenyl)benzamide 4-BROMO-N,N-DIISOPROPYLBENZYLAMINE, 95 N-(4-BROMO-2-METHOXYBENZYL)-4-(TRIFLUOROMETHOXY)ANILINE 4,5,6,7-TETRABROMO-2-(OXIRAN-2-YLMETHYL)ISOINDOLINE-1,3-DIONE N-(4-BROMO-2-METHOXYBENZYL)-5-FLUORO-2-METHYLANILINE 2-(4-BROMOPHENYL)-5,5-DIMETHYL-1,3-THIAZOLIDINE-4-CARBOXYLIC ACID 5-ACETYL-3-(4-BROMOBENZYL)-1-(4-CHLOROPHENYL)-2,4(1H,3H)-PYRIMIDINEDIONE TIMTEC-BB SBB006035 N,N'-(methylenedi-p-phenylene)bis[3,4,5,6,-tetrabromophthalimide] N-(2,3-DIMETHYL-5-OXO-1-PHENYL(3-PYRAZOLIN-4-YL))(3,4,5-TRIBROMOPHENYL)FORMAMIDE

4-BROMO-N-METHYLBENZYLAMINE

(4-BROMOBENZYL)METHYLAMINE

(4-Bromobenzyl)methylamine95%

N-Methyl-4-bromobenzylamine

874-73-7 (Hydrochloride)

Aids107181

Aids-107181

Benzenemethanamine, 4-bromo-N-methyl-

(4-Bromobenzyl)Methylamine 95%

(4-BROMOBENZYL)METHY

1-(4-broMophenyl)-N-MethylMethanaMine

4-Bromo-N-methylbenzylamine 97%

(4-bromobenzyl)methylamine hydrochloride

4-Bromo-<i>N</i>-methylbenzylamine

699-03-6

BrC6H4CH2NHCH3

Organic Building Blocks

Nitrogen Compounds

Building Blocks

Amines

amine| alkyl bromide

Amines and Anilines