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Benzyl salicylate

Product Name
Benzyl salicylate
CAS No.
118-58-1
Chemical Name
Benzyl salicylate
Synonyms
BENZYL 2-HYDROXYBENZOATE;118-58;FEMA 2151;Benzylsalicylat;enzyl salicylate;Benzyl saIicylate;BENZYL SALICYLATE;benzyle salicylate;benzylhydroxybenzoate;SALICILATO DE BENCILO
CBNumber
CB3484524
Molecular Formula
C14H12O3
Formula Weight
228.24
MOL File
118-58-1.mol
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Benzyl salicylate Property

Melting point:
18-20 °C
Boiling point:
168-170 °C5 mm Hg(lit.)
Density 
1.176 g/mL at 25 °C(lit.)
vapor pressure 
0.01Pa at 25℃
FEMA 
2151 | BENZYL SALICYLATE
refractive index 
n20/D 1.581(lit.)
Flash point:
>230 °F
storage temp. 
-20°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
8.11±0.30(Predicted)
form 
Liquid
color 
Thick colorless liquid
Odor
pleasant odor
Odor Type
balsamic
Water Solubility 
Slightly soluble
Merck 
14,1144
JECFA Number
904
BRN 
2115365
Dielectric constant
4.1（20℃）
InChIKey
ZCTQGTTXIYCGGC-UHFFFAOYSA-N
LogP
4
CAS DataBase Reference
118-58-1(CAS DataBase Reference)
NIST Chemistry Reference
Benzoic acid, 2-hydroxy-, phenylmethyl ester(118-58-1)
EPA Substance Registry System
Benzyl salicylate (118-58-1)
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Safety

Hazard Codes 
Xi,N
Risk Statements 
36/37/38-51/53-43
Safety Statements 
26-36-24/25-61-37-24
WGK Germany 
2
RTECS 
VO1750000
TSCA 
Yes
HS Code 
29182900
Hazardous Substances Data
118-58-1(Hazardous Substances Data)
Toxicity
LD50 orl-rat: 2227 mg/kg FCTXAV 11,1029,73
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
77069
Product name
Benzyl salicylate
Purity
reference material
Packaging
100MG
Price
$163
Updated
2022/05/15
TCI Chemical
Product number
S0009
Product name
Benzyl Salicylate
Purity
>99.0%(GC)
Packaging
25g
Price
$22
Updated
2024/03/01
TCI Chemical
Product number
S0009
Product name
Benzyl Salicylate
Purity
>99.0%(GC)
Packaging
500g
Price
$46
Updated
2024/03/01
Alfa Aesar
Product number
A16184
Product name
Benzyl salicylate, 99%
Packaging
100g
Price
$18.65
Updated
2024/03/01
Alfa Aesar
Product number
A16184
Product name
Benzyl salicylate, 99%
Packaging
500g
Price
$48.65
Updated
2024/03/01
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Benzyl salicylate Chemical Properties,Usage,Production

Description

Benzyl salicylate is a salicylic acid benzyl ester, a chemical compound most frequently used in cosmetics. It appears as an almost colorless liquid with a mild odor described as "very faint, sweetfloral, slightly balsamic" by those who can smell it, but many people either can't smell it at all or describe its smell as "musky". Trace impurities can have a significant influence on the odour.[1] It occurs naturally in a variety of plants and plant extracts and is widely used in blends of fragrance materials.
There is some evidence that people can become sensitized to this material and as a result there is a restriction standard concerning the use of this material in fragrances by the International Fragrance Association.
It is used as a solvent for crystalline synthetic musks and as a component and fixative in floral perfumes such as carnation, jasmine, lilac, and wallflower.

Chemical Properties

Benzyl Salicylate occurs in several essential oils, is a colorless, viscous liquid with a weak, sweet, slightly balsamic odor and a sweet, currant-like taste. It is soluble in ethanol, most non-volatile and volatile oils, slightly soluble in propylene glycol, insoluble in glycerin and practically insoluble in water.

Occurrence

It has been reported in small amounts in carnation oil (Dianthus caryophyllus L.) and in larger amounts in the oil of Primula auricula. Also found in American cranberry, clove bud, peppermint oil and buckwheat.

Uses

Benzyl Salicylate is an chemical compound commonly used in the cosmetic industry. Benzyl Salicylate is also found in essential oils from green tea and was shown to exhibit antioxidant and antimicrobia l activity.

Uses

benzyl salicylate is a fragrance found naturally occurring in carnations and in certain members of the primrose family. Although it can be derived for cosmetic use from natural essential oils, such as jasmine oil, neroli, and ylang-ylang, it can also be synthetically manufactured.

Definition

ChEBI: Benzyl salicylate is a benzoate ester and a member of phenols. It is functionally related to a salicylic acid.

Preparation

By esterification of salicylic acid with benzyl alcohol.

General Description

Colorless liquid. Melting point near room temperature (18-20°C). As fixer in perfumery; in sunscreen preparations.

Air & Water Reactions

Slightly water soluble .

Reactivity Profile

Benzyl salicylate may hydrolyze in aqueous acid or basic solutions. Benzyl salicylate can react with oxidizing materials.

Fire Hazard

Flash point data for Benzyl salicylate are not available, but Benzyl salicylate is probably combustible.

Flammability and Explosibility

Non flammable

Contact allergens

Benzyl salicylate is used as fixer in perfumery and sunscreen preparations. As a (weak) perfume sensitizer, it has to be listed by name in cosmetic preparations in the EU.

Safety Profile

Moderately toxic by ingestion. Seealso BENZYL ALCOHOL, SALICYLIC ACID, andESTERS. Combustible when exposed to heat or flame.When heated to decomposition it emits acrid smoke andirritating fumes. Incompatible with oxidizing materials.

Safety

Benzyl salicylate poses dangers to sensitive skin.  Even in very small amounts, it may cause allergic reactions when applied to the skin. Benzyl salicylate can cause contact dermatitis (skin irritation) to people with sensitive skin types. It is also on the European Commission's list of 26 known allergens. Some of the other ingredients on the fragrance allergen list include linalool, coumarin, geraniol, and limonene.

Benzyl salicylate Preparation Products And Raw materials

Raw materials

Sodium salicylate Salicylic acid Benzyl chloride Phenethyl alcohol Diethylamine

Preparation Products

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Benzyl salicylate Suppliers

Australia 2 Belgium 2 Brazil 2 Canada 4 China 271 Czech 1 Europe 4 France 2 Germany 10 Greece 1 India 72 Italy 1 Japan 8 Mexico 1 Poland 1 Slovakia 1 South Africa 1 South Korea 1 Spain 4 Sweden 1 Switzerland 4 United Kingdom 18 United States 81 USA 1 Global 494
Alfa Chemistry
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View Lastest Price from Benzyl salicylate manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
Benzyl Salicylate 118-58-1
Price
US $150.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500kg
Release date
2024-11-20
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
benzyl 118-58-1
Price
US $100.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-04-25
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Benzyl salicylate 118-58-1
Price
US $200.00-95.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-25

118-58-1, Benzyl salicylateRelated Search:

Benzyl chloroformate Benzyl formate 4-Nitrobenzyl chloroformate Phenyl salicylate Benzyl nicotinate Benzyl benzoate Dimethyl succinate Benzyl methacrylate Hexyl salicylate Salicylic acid BUTYL OLEATE Methyl salicylate Isoamyl o-hydroxybenzoate Tris(trimethylsilyl)phosphate Carbobenzoxyhydrazide Benzyl acetate Benzyl alcohol Methyl acrylate

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  • Salicylic Acid Benzyl Ester 2-Hydroxybenzoic Acid Benzyl Ester Benzyl 2-Hydroxybenzoate
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  • Best Price Benzyl Salicylate CAS 118-58-1 with Fast Delivery
  • Fast Delivery Benzyl Salicylate CAS 118-58-1 with Best Price
  • Benzyl salisylate-d4 (Benzyl 2-hydroxybenzoate-3,4,5,6-d4) in isooctane
  • C16903510 SalicyliCacid-benzyLester
  • 118-58-1
  • 115-58-1
  • C6H5CH2OOCC6H4OH
  • 2HOC6H4CO2CH2C6H5
  • ESTER
  • Organic Building Blocks
  • Esters
  • Carbonyl Compounds
  • C12 to C63
  • Building Blocks
  • Used in variety of cosmetic and soap essences.
  • Pharmaceutical Intermediates