ChemicalBook > CAS DataBase List > N-BENZYLCINCHONINIUM CHLORIDE
N-BENZYLCINCHONINIUM CHLORIDE
- Product Name
- N-BENZYLCINCHONINIUM CHLORIDE
- CAS No.
- 69221-14-3
- Chemical Name
- N-BENZYLCINCHONINIUM CHLORIDE
- Synonyms
- BCNC;(1S,2R,4S,5R);N-Benzylcinchonium chloride;chiralphase-transfercatalyst;N-BENZYLCINCHONINUM CHLORIDE);N-BENZYLCINCHONINIUM CHLORIDE;1-Benzylcinchoninium chloride;(+)-N-Benzylcinchone chloride;iNi-BenzylcinchoniniumChloride;(+)-1-Benzylcinchoninium chloride
- CBNumber
- CB3487095
- Molecular Formula
- C26H29ClN2O
- Formula Weight
- 420.97
- MOL File
- 69221-14-3.mol
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N-BENZYLCINCHONINIUM CHLORIDE Property
- Melting point:
- 256 °C (dec.)(lit.)
- refractive index
- 168.5 ° (C=0.4, MeOH:H2O=1:5)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- slightly sol. in Methanol
- form
- powder to crystaline
- color
- White to Almost white
- optical activity
- [α]20/D +169°, c = 0.4 in H2O
- BRN
- 5232950
- CAS DataBase Reference
- 69221-14-3(CAS DataBase Reference)
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 366188
- Product name
- N-Benzylcinchoninium chloride
- Purity
- 98%
- Packaging
- 10g
- Price
- $157.2
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B1689
- Product name
- N-Benzylcinchoninium Chloride [Chiral Phase-Transfer Catalyst]
- Purity
- >99.0%(T)
- Packaging
- 5g
- Price
- $96
- Updated
- 2024/03/01
TRC
- Product number
- B130413
- Product name
- N-Benzylcinchoninium chloride
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
TRC
- Product number
- B130413
- Product name
- N-Benzylcinchoninium chloride
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FB59906
- Product name
- N-Benzylcinchoninium Chloride
- Packaging
- 5G
- Price
- $86
- Updated
- 2021/12/16
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N-BENZYLCINCHONINIUM CHLORIDE Chemical Properties,Usage,Production
Chemical Properties
Solid
Uses
Phase-transfer catalyst involved in:
- Enantioselective alkylation of malonic diester with alkyl halides
- Hydrolysis of enol esters
- Asymmetric 6π electrocyclization for synthesis of functionalized indolines
- Asymmetric Michael addition
- Alkylation of monosubstituted indolinones with alkylhalides
- Asymmetric destruction and kinetic resolution of 1-benzylated Reissert compounds
Purification Methods
Recrystallise the chloride from isoPrOH, toluene or small volumes of H2O. It is a good chiral phase transfer catalyst [Julia et al. J Chem Soc, Perkin Trans 1 574 1981, Hughes et al. J Am Chem Soc 106 446 1984, Hughes et al. J Org Chem 52 4745 1987].
N-BENZYLCINCHONINIUM CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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N-BENZYLCINCHONINIUM CHLORIDE Suppliers
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- 010-82848833 400-666-7788
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View Lastest Price from N-BENZYLCINCHONINIUM CHLORIDE manufacturers
Career Henan Chemical Co
- Product
- N-BENZYLCINCHONINIUM CHLORIDE 69221-14-3
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 90%-99.9%
- Supply Ability
- 10kg
- Release date
- 2019-07-04
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