N-BENZYLCINCHONINIUM CHLORIDE

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N-BENZYLCINCHONINIUM CHLORIDE

Product Name: N-BENZYLCINCHONINIUM CHLORIDE
CAS No.: 69221-14-3
Chemical Name: N-BENZYLCINCHONINIUM CHLORIDE
Synonyms: BCNC;(1S,2R,4S,5R);N-Benzylcinchonium chloride;chiralphase-transfercatalyst;N-BENZYLCINCHONINUM CHLORIDE);N-BENZYLCINCHONINIUM CHLORIDE;1-Benzylcinchoninium chloride;(+)-N-Benzylcinchone chloride;iNi-BenzylcinchoniniumChloride;(+)-1-Benzylcinchoninium chloride
CBNumber: CB3487095
Molecular Formula: C26H29ClN2O
Formula Weight: 420.97
MOL File: 69221-14-3.mol

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N-BENZYLCINCHONINIUM CHLORIDE Property

Melting point:: 256 °C (dec.)(lit.)
refractive index: 168.5 ° (C=0.4, MeOH:H2O=1:5)
storage temp.: Inert atmosphere,Room Temperature
solubility: slightly sol. in Methanol
form: powder to crystaline
color: White to Almost white
optical activity: [α]20/D +169°, c = 0.4 in H2O
BRN: 5232950
CAS DataBase Reference: 69221-14-3(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
HS Code: 29339900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 366188
Product name: N-Benzylcinchoninium chloride
Purity: 98%
Packaging: 10g
Price: $157.2
Updated: 2024/03/01

TCI Chemical

Product number: B1689
Product name: N-Benzylcinchoninium Chloride [Chiral Phase-Transfer Catalyst]
Purity: >99.0%(T)
Packaging: 5g
Price: $96
Updated: 2024/03/01

TRC

Product number: B130413
Product name: N-Benzylcinchoninium chloride
Packaging: 100mg
Price: $60
Updated: 2021/12/16

TRC

Product number: B130413
Product name: N-Benzylcinchoninium chloride
Packaging: 500mg
Price: $75
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB59906
Product name: N-Benzylcinchoninium Chloride
Packaging: 5G
Price: $86
Updated: 2021/12/16

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N-BENZYLCINCHONINIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Solid

Uses

Phase-transfer catalyst involved in:

Enantioselective alkylation of malonic diester with alkyl halides
Hydrolysis of enol esters
Asymmetric 6π electrocyclization for synthesis of functionalized indolines
Asymmetric Michael addition
Alkylation of monosubstituted indolinones with alkylhalides
Asymmetric destruction and kinetic resolution of 1-benzylated Reissert compounds

Purification Methods

Recrystallise the chloride from isoPrOH, toluene or small volumes of H2O. It is a good chiral phase transfer catalyst [Julia et al. J Chem Soc, Perkin Trans 1 574 1981, Hughes et al. J Am Chem Soc 106 446 1984, Hughes et al. J Org Chem 52 4745 1987].

N-BENZYLCINCHONINIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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N-BENZYLCINCHONINIUM CHLORIDE Suppliers

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View Lastest Price from N-BENZYLCINCHONINIUM CHLORIDE manufacturers

Career Henan Chemical Co

Product: N-BENZYLCINCHONINIUM CHLORIDE 69221-14-3
Price: US $3.00/KG
Min. Order: 1KG
Purity: 90%-99.9%
Supply Ability: 10kg
Release date: 2019-07-04

69221-14-3, N-BENZYLCINCHONINIUM CHLORIDERelated Search:

Benzyltriethylammonium chloride Mepiquat chloride N-BENZYLQUINIDINIUM CHLORIDE N-BENZYLCINCHONINIUM CHLORIDE (R)(-)-2-BENZYLAMINO-1-BUTANOL N-Benzyl-N-methylpiperidinium chloride Tetraethylammonium Chloride Benzyltripropylammonium chloride Cinchonine 4-BUTYLPIPERIDINE CINCHONINE HYDROCHLORIDE 2,4-Dimethylpiperidine (R)-(+)-1-(4-PYRIDYL)ETHANOL N-Benzylcinchoninium chloride ,99% Methyltripropyl ammonium chloride 6-BENZYLAMINO-1-HEXANOL 2-HYDROXY-4-PYRIDYLETHYLAMINE 2-(3-METHYLPIPERIDIN-1-YL)PROPAN-1-OL

N-BENZYLCINCHONINIUM CHLORIDE

BCNC

(9S)-1-benzyl-9-hydroxycinchonanium chloride

chiralphase-transfercatalyst

N-BENZYLCINCHONINUM CHLORIDE)

(9S)-9-Hydroxy-1-(phenylmethyl)cinchonanium chloride

(+)-1-Benzylcinchoninium chloride

(+)-N-Benzylcinchone chloride

(9S)-9-Hydroxy-1-(phenylmethyl)cinchonan-1-ium·chloride

1-Benzylcinchoninium chloride

N-Benzylcinchoninium Chloride [Chiral Phase-Transfer Catalyst]

N-Benzylcinchonium chloride

Cinchonanium,9-hydroxy-1-(phenylmethyl)-, chloride, (9S)-

[5-ethenyl-1-(phenylmethyl)-1-azoniabicyclo[2.2.2]octan-2-yl]-(4-quinolinyl)methanol chloride

(1S,2R,4S,5R)-1-Benzyl-2-(hydroxy(quinolin-4-yl)methyl)-5-vinylquinuclidin-1-ium chloride

9-Hydroxy-1-(phenylmethyl)cinchonanium chloride

N-Benzylcinchoninium chloride 98%

(1S,2R,4S,5R)

-1-Benzyl-2-(hydroxy(quinolin-4-yl)

(S)-[(1S,2R,4S,5R)-1-benzyl-5-vinyl-quinuclidin-1-ium-2-yl]-(4-quinolyl)methanol

(9S)-1-Benzyl-9-hydroxycinchonaniumchlorid

N-Benzylcinchoninium Chloride [Chiral Phase-Transfer Catalyst]&gt

iNi-BenzylcinchoniniumChloride

N-BENZYLCINCHONINIUM CHLORIDE ISO 9001：2015 REACH

69221-14-3

C29H32ClN2O

C26H29ClN2O

Quaternary Ammonium Compounds

Asymmetric Synthesis

Ammonium Chlorides (Quaternary)

Quinolines

Chiral Phase-Transfer Catalysts

Alkaloids

Quinolinecarboxylic Acids, etc.

Quinoline Alkaloids

Phase Transfer Reaction

Chiral Catalysts, Ligands, and Reagents

Alkaloids

Ammonium Chlorides (Quaternary)

Asymmetric Synthesis

Biochemistry

Chiral Phase-Transfer Catalysts

Quaternary Ammonium Compounds

Quinoline Alkaloids

Quinolinecarboxylic Acids, etc.

Quinolines

Synthetic Organic Chemistry

chiral