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N-BENZYLCINCHONINIUM CHLORIDE

Product Name
N-BENZYLCINCHONINIUM CHLORIDE
CAS No.
69221-14-3
Chemical Name
N-BENZYLCINCHONINIUM CHLORIDE
Synonyms
BCNC;(1S,2R,4S,5R);N-Benzylcinchonium chloride;chiralphase-transfercatalyst;N-BENZYLCINCHONINUM CHLORIDE);N-BENZYLCINCHONINIUM CHLORIDE;1-Benzylcinchoninium chloride;(+)-N-Benzylcinchone chloride;iNi-BenzylcinchoniniumChloride;(+)-1-Benzylcinchoninium chloride
CBNumber
CB3487095
Molecular Formula
C26H29ClN2O
Formula Weight
420.97
MOL File
69221-14-3.mol
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N-BENZYLCINCHONINIUM CHLORIDE Property

Melting point:
256 °C (dec.)(lit.)
refractive index 
168.5 ° (C=0.4, MeOH:H2O=1:5)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
slightly sol. in Methanol
form 
powder to crystaline
color 
White to Almost white
optical activity
[α]20/D +169°, c = 0.4 in H2O
BRN 
5232950
CAS DataBase Reference
69221-14-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
366188
Product name
N-Benzylcinchoninium chloride
Purity
98%
Packaging
10g
Price
$157.2
Updated
2024/03/01
TCI Chemical
Product number
B1689
Product name
N-Benzylcinchoninium Chloride [Chiral Phase-Transfer Catalyst]
Purity
>99.0%(T)
Packaging
5g
Price
$96
Updated
2024/03/01
TRC
Product number
B130413
Product name
N-Benzylcinchoninium chloride
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
B130413
Product name
N-Benzylcinchoninium chloride
Packaging
500mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB59906
Product name
N-Benzylcinchoninium Chloride
Packaging
2g
Price
$43
Updated
2021/12/16
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N-BENZYLCINCHONINIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Solid

Uses

Phase-transfer catalyst involved in:

  • Enantioselective alkylation of malonic diester with alkyl halides
  • Hydrolysis of enol esters
  • Asymmetric 6π electrocyclization for synthesis of functionalized indolines
  • Asymmetric Michael addition
  • Alkylation of monosubstituted indolinones with alkylhalides
  • Asymmetric destruction and kinetic resolution of 1-benzylated Reissert compounds

Purification Methods

Recrystallise the chloride from isoPrOH, toluene or small volumes of H2O. It is a good chiral phase transfer catalyst [Julia et al. J Chem Soc, Perkin Trans 1 574 1981, Hughes et al. J Am Chem Soc 106 446 1984, Hughes et al. J Org Chem 52 4745 1987].

N-BENZYLCINCHONINIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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N-BENZYLCINCHONINIUM CHLORIDE Suppliers

Americas 1 Belgium 1 China 67 Europe 1 France 1 Germany 3 India 2 Japan 2 Switzerland 1 The Netherlands 1 United Kingdom 4 United States 10 Global 94
Interchim SA
Tel
--
Fax
--
Email
him@interchim.com
Country
France
ProdList
2725
Advantage
58
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View Lastest Price from N-BENZYLCINCHONINIUM CHLORIDE manufacturers

Career Henan Chemical Co
Product
N-BENZYLCINCHONINIUM CHLORIDE 69221-14-3
Price
US $3.00/KG
Min. Order
1KG
Purity
90%-99.9%
Supply Ability
10kg
Release date
2019-07-04

69221-14-3, N-BENZYLCINCHONINIUM CHLORIDERelated Search:

Benzyltriethylammonium chloride Mepiquat chloride N-BENZYLQUINIDINIUM CHLORIDE N-BENZYLCINCHONINIUM CHLORIDE (R)(-)-2-BENZYLAMINO-1-BUTANOL N-Benzyl-N-methylpiperidinium chloride Tetraethylammonium Chloride Benzyltripropylammonium chloride Cinchonine 4-BUTYLPIPERIDINE CINCHONINE HYDROCHLORIDE 2,4-Dimethylpiperidine (R)-(+)-1-(4-PYRIDYL)ETHANOL N-Benzylcinchoninium chloride ,99% Methyltripropyl ammonium chloride 6-BENZYLAMINO-1-HEXANOL 2-HYDROXY-4-PYRIDYLETHYLAMINE 2-(3-METHYLPIPERIDIN-1-YL)PROPAN-1-OL

  • N-BENZYLCINCHONINIUM CHLORIDE
  • BCNC
  • (9S)-1-benzyl-9-hydroxycinchonanium chloride
  • chiralphase-transfercatalyst
  • N-BENZYLCINCHONINUM CHLORIDE)
  • (9S)-9-Hydroxy-1-(phenylmethyl)cinchonanium chloride
  • (+)-1-Benzylcinchoninium chloride
  • (+)-N-Benzylcinchone chloride
  • (9S)-9-Hydroxy-1-(phenylmethyl)cinchonan-1-ium·chloride
  • 1-Benzylcinchoninium chloride
  • N-Benzylcinchoninium Chloride [Chiral Phase-Transfer Catalyst]
  • N-Benzylcinchonium chloride
  • Cinchonanium,9-hydroxy-1-(phenylmethyl)-, chloride, (9S)-
  • [5-ethenyl-1-(phenylmethyl)-1-azoniabicyclo[2.2.2]octan-2-yl]-(4-quinolinyl)methanol chloride
  • (1S,2R,4S,5R)-1-Benzyl-2-(hydroxy(quinolin-4-yl)methyl)-5-vinylquinuclidin-1-ium chloride
  • 9-Hydroxy-1-(phenylmethyl)cinchonanium chloride
  • N-Benzylcinchoninium chloride 98%
  • (1S,2R,4S,5R)
  • -1-Benzyl-2-(hydroxy(quinolin-4-yl)
  • (S)-[(1S,2R,4S,5R)-1-benzyl-5-vinyl-quinuclidin-1-ium-2-yl]-(4-quinolyl)methanol
  • (9S)-1-Benzyl-9-hydroxycinchonaniumchlorid
  • N-Benzylcinchoninium Chloride [Chiral Phase-Transfer Catalyst]&gt
  • iNi-BenzylcinchoniniumChloride
  • N-BENZYLCINCHONINIUM CHLORIDE ISO 9001：2015 REACH
  • 69221-14-3
  • C29H32ClN2O
  • C26H29ClN2O
  • Quaternary Ammonium Compounds
  • Asymmetric Synthesis
  • Ammonium Chlorides (Quaternary)
  • Quinolines
  • Chiral Phase-Transfer Catalysts
  • Alkaloids
  • Quinolinecarboxylic Acids, etc.
  • Quinoline Alkaloids
  • Phase Transfer Reaction
  • Chiral Catalysts, Ligands, and Reagents
  • Alkaloids
  • Ammonium Chlorides (Quaternary)
  • Asymmetric Synthesis
  • Biochemistry
  • Chiral Phase-Transfer Catalysts
  • Quaternary Ammonium Compounds
  • Quinoline Alkaloids
  • Quinolinecarboxylic Acids, etc.
  • Quinolines
  • Synthetic Organic Chemistry
  • chiral