ChemicalBook > CAS DataBase List > METHYL 3-THIOPHENECARBOXYLATE 97

METHYL 3-THIOPHENECARBOXYLATE 97

Product Name
METHYL 3-THIOPHENECARBOXYLATE 97
CAS No.
22913-26-4
Chemical Name
METHYL 3-THIOPHENECARBOXYLATE 97
Synonyms
THOO1;3-Methoxycarbonylthiophene;Methyl 3-thiophenecarboxylate;Methyl thiophene-3-carboxylate;METHYL 3-THIOPHENECARBOXYLATE 97;Methyl Thiophene-3-carboxylate >3- thiophene carboxylic acidMethyl ester;Thiophene-3-carboxylic acid methyl ester;METHYL 3-THIOPHENECARBOXYLATE 97 ISO 9001:2015 REACH
CBNumber
CB3505384
Molecular Formula
C6H6O2S
Formula Weight
142.18
MOL File
22913-26-4.mol
More
Less

METHYL 3-THIOPHENECARBOXYLATE 97 Property

Boiling point:
98 °C/10 mmHg (lit.)
Density 
1.174 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.5380(lit.)
Flash point:
172 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
clear liquid
color 
Colorless to Light yellow
λmax
239nm(Hexane)(lit.)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-43
Safety Statements 
26-36/37
RIDADR 
NA 1993 / PGIII
WGK Germany 
2
HS Code 
29349990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

TCI Chemical
Product number
M2627
Product name
Methyl Thiophene-3-carboxylate
Purity
>97.0%(GC)
Packaging
5g
Price
$49
Updated
2025/07/31
TCI Chemical
Product number
M2627
Product name
Methyl Thiophene-3-carboxylate
Purity
>97.0%(GC)
Packaging
25g
Price
$195
Updated
2025/07/31
TRC
Product number
B486260
Product name
Methyl Thiophene-3-carboxylate
Packaging
50mg
Price
$60
Updated
2021/12/16
AK Scientific
Product number
Z3263
Product name
Methyl Thiophene-3-carboxylate
Packaging
5g
Price
$87
Updated
2021/12/16
Ark Pharm
Product number
P000260257
Product name
Methyl thiophene-3-carboxylate
Purity
98%
Packaging
5g
Price
$25
Updated
2021/12/16
More
Less

METHYL 3-THIOPHENECARBOXYLATE 97 Chemical Properties,Usage,Production

Chemical Properties

Colorless to yellow liquid

Synthesis

67-56-1

88-13-1

22913-26-4

A catalytic amount of concentrated sulfuric acid (0.5 mL) was added to a solution of 3-thiophenecarboxylic acid (2.0 g, 15.60 mmol) in methanol (30 mL), and the reaction mixture was heated to reflux for 2 hours. After completion of the reaction, the solvent was removed by distillation under reduced pressure. The residue was poured into ice-cold water and extracted with ethyl acetate (3 × 20 mL). The organic layers were combined, washed with saturated brine and dried over anhydrous sodium sulfate. After filtration, the organic phase was concentrated under reduced pressure to give methyl 3-thiophenecarboxylate (1.8 g, 81% yield) as a colorless oil.

References

[1] Patent: WO2006/123145, 2006, A1. Location in patent: Page/Page column 44
[2] Recueil des Travaux Chimiques des Pays-Bas, 1934, vol. 53, p. 643,648
[3] Recueil des Travaux Chimiques des Pays-Bas, 1936, vol. 55, p. 991
[4] Patent: WO2016/115013, 2016, A1. Location in patent: Page/Page column 70
[5] Patent: WO2006/108701, 2006, A1. Location in patent: Page/Page column 61

METHYL 3-THIOPHENECARBOXYLATE 97 Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

METHYL 3-THIOPHENECARBOXYLATE 97 Suppliers

TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
More
Less

View Lastest Price from METHYL 3-THIOPHENECARBOXYLATE 97 manufacturers

Career Henan Chemical Co
Product
METHYL 3-THIOPHENECARBOXYLATE 97 22913-26-4
Price
US $0.01/KG
Min. Order
1KG
Purity
98%; 99%
Supply Ability
1kg; 5kg; 10kg;25kg
Release date
2020-01-07