2 6-DICHLORO-4-NITROPYRIDINE 97
- Product Name
- 2 6-DICHLORO-4-NITROPYRIDINE 97
- CAS No.
- 25194-01-8
- Chemical Name
- 2 6-DICHLORO-4-NITROPYRIDINE 97
- Synonyms
- 2,6-Dichloro-4-nitropyridine;benzylsulfonylmethylbenzene;Pyridine,2,6-dichloro-4-nitro-;2 6-DICHLORO-4-NITROPYRIDINE 97;2,6-Dichloro-4-nitropyridine 97%;phenylmethylsulfonylmethylbenzene;25194-01-8;2 6-DICHLORO-4-NITROPYRIDINE 97 ISO 9001：2015 REACH
- CBNumber
- CB3505399
- Molecular Formula
- C5H2Cl2N2O2
- Formula Weight
- 192.99
- MOL File
- 25194-01-8.mol
2 6-DICHLORO-4-NITROPYRIDINE 97 Property
- Melting point:
- 94-98 °C
- Boiling point:
- 282.9±35.0 °C(Predicted)
- Density
- 1.629±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- Gold to faint brown/tan, tiny crystalline flakes
- pka
- -5.10±0.10(Predicted)
- Appearance
- Off-white to light yellow Solid
- InChI
- InChI=1S/C5H2Cl2N2O2/c6-4-1-3(9(10)11)2-5(7)8-4/h1-2H
- InChIKey
- BZYQSSVTQJTUDD-UHFFFAOYSA-N
- SMILES
- C1(Cl)=NC(Cl)=CC([N+]([O-])=O)=C1
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22-37/38-41-43-36/37/38
- Safety Statements
- 26-39-36/37/39
- WGK Germany
- 3
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H317May cause an allergic skin reaction
H318Causes serious eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- 647411
- Product name
- 2,6-Dichloro-4-nitropyridine
- Purity
- 97%
- Packaging
- 5g
- Price
- $115
- Updated
- 2023/06/20
- Product number
- 647411
- Product name
- 2,6-Dichloro-4-nitropyridine
- Purity
- 97%
- Packaging
- 1g
- Price
- $41.7
- Updated
- 2023/01/07
- Product number
- D3531-45
- Product name
- 2,6-Dichloro-4-nitropyridine
- Packaging
- 500mg
- Price
- $425
- Updated
- 2021/12/16
- Product number
- D435625
- Product name
- 2,6-Dichloro-4-nitropyridine
- Packaging
- 10g
- Price
- $1100
- Updated
- 2021/12/16
- Product number
- 083874
- Product name
- 2,6-Dichloro-4-nitropyridine
- Purity
- 97%
- Packaging
- 100g
- Price
- $468
- Updated
- 2021/12/16
2 6-DICHLORO-4-NITROPYRIDINE 97 Chemical Properties,Usage,Production
Uses
2,6-Dichloro-4-nitropyridine (cas# 25194-01-8) is a compound useful in organic synthesis.
Synthesis Reference(s)
Synthetic Communications, 18, p. 659, 1988 DOI: 10.1080/00397918808077351
Synthesis
2587-00-0
25194-01-8
The general procedure for the synthesis of 2,6-dichloro-4-nitropyridine from 2,6-dichloropyridine-N-oxide was as follows: 2,6-dichloropyridine-N-oxide (12.8 g, 78 mmol) was added to a mixed solution consisting of 95% concentrated nitric acid (21 mL) and 98% concentrated sulfuric acid (50 mL). The reaction was stirred at 148 °C for 1 h. The temperature was subsequently raised to 156 °C until no more nitrogen dioxide gas was released. After completion of the reaction, the reaction solution was cooled to room temperature and slowly poured into 150 g of ice water. The pH of the mixture was adjusted to 6 with ammonia, at which point a solid product precipitated. The solid was collected by filtration and the resulting crude product was recrystallized with petroleum ether to give 10 g of yellow solid product in 66.4% yield.
References
[1] Patent: US2012/289497, 2012, A1. Location in patent: Page/Page column 51-52
[2] Patent: EP2524917, 2012, A1. Location in patent: Page/Page column 58-59
[3] Organic Letters, 2004, vol. 6, # 5, p. 659 - 662
[4] Nucleosides, Nucleotides and Nucleic Acids, 2003, vol. 22, # 12, p. 2133 - 2144
2 6-DICHLORO-4-NITROPYRIDINE 97 Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2 6-DICHLORO-4-NITROPYRIDINE 97 manufacturers
- Product
- 2,6-Dichloro-4-nitropyridine 25194-01-8
- Price
- US $1600.00/Kg
- Min. Order
- 0.100Kg
- Purity
- 98
- Supply Ability
- 5000 Kg
- Release date
- 2025-01-22
- Product
- 2 6-DICHLORO-4-NITROPYRIDINE 25194-01-8
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons min
- Release date
- 2021-09-08
- Product
- 2 6-DICHLORO-4-NITROPYRIDINE 97 25194-01-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2019-07-02