Diacetone-D-glucose

Product Name: Diacetone-D-glucose
CAS No.: 582-52-5
Chemical Name: Diacetone-D-glucose
Synonyms: GLUCOFURANOSE;(3aR,5S,6S,6aR)-5-((R)-2,2-DiMethyl-1,3-dioxolan-4-yl)-2,2-diMethyltetrahydrofuro[2,3-d][1,3]dioxol-6-ol;DIACETONEGLUCOSE;1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE;1,2:5,6-DIISOPROPYLENE-ALPHA-D-GLUCOFURANOSE;1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose;1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE;1,2:5,6-O-DI-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSIDE;ucose;NSC 1223
CBNumber: CB3673320
Molecular Formula: C12H20O6
Formula Weight: 260.29
MOL File: 582-52-5.mol

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Diacetone-D-glucose Property

Melting point:: 110-111 °C(lit.)
alpha: -11 º (c=5, EtOH)
Boiling point:: 323.54°C (rough estimate)
Density: 1.1432 (rough estimate)
refractive index: -18.5 ° (C=5, H2O)
storage temp.: Inert atmosphere,Store in freezer, under -20°C
solubility: Chloroform (Slightly), Methanol (Slightly), Water (Slightly, Sonicated)
pka: 13.15±0.60(Predicted)
form: Powder
color: White to yellow
optical activity: [α]20/D 18°, c = 1% in H2O
Water Solubility: slightly soluble
Merck: 14,2965
BRN: 84386
InChIKey: KEJGAYKWRDILTF-YENDLIOYSA-N
EPA Substance Registry System: Diacetone glucose (582-52-5)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 24/25-36/37-26
WGK Germany: 2
RTECS: LZ4958000
F: 3-10
TSCA: Yes
HS Code: 29329970
Toxicity: LD50 oral in mouse: 4gm/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 31460
Product name: 1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose
Purity: purum,≥98.0%(TLC)
Packaging: 25g
Price: $62.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 31460
Product name: 1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose
Purity: purum,≥98.0%(TLC)
Packaging: 100g
Price: $138
Updated: 2024/03/01

Sigma-Aldrich

Product number: S83055
Product name: 5-(2,2-DIMETHYL-(1,3)DIOXOLAN-4-YL)-2,2-DIMETHYL-4H-FURO(2,3-D)(1,3)DIOXOL-6-OL
Purity: AldrichCPR
Packaging: 250MG
Price: $28.6
Updated: 2023/06/20

TCI Chemical

Product number: D1949
Product name: 1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose
Purity: >97.0%(GC)
Packaging: 10g
Price: $16
Updated: 2024/03/01

TCI Chemical

Product number: D1949
Product name: 1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose
Purity: >97.0%(GC)
Packaging: 25g
Price: $40
Updated: 2024/03/01

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Diacetone-D-glucose Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

It is mainly used in biochemical reaction and used as medicine intermediate. It is used in synthesize for below products: L-gulose;1,2:5,6-Di-O-isopropylidene-a-D-gulofuranose; Alllose; ;1,2:5,6-Double-O-Isopropylidene-3-C-(1-Methoxycarbonyl)Ethide-alfa-D-Furanose) ;1,2:5,6-Di-O-isopropylidene-a-D-ribo-hexofuranose-3-ulose;6-deoxy idose.

Uses

1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose is a compound useful in organic synthesis.

Purification Methods

Diacetone-D-glucose crystallises from Et2O, (needles), pet ether or *C6H6 and sublimes in vacuo. It is soluble in 7 volumes of H2O and 200 volumes of pet ether at their boiling points. The solubility in H2O at 17.5o is 4.3%. It precipitates from aqueous solutions on basification with NaOH. [Schmid & Karrer Helv Chim Acta 32 1371 1949, Fischer & Rund Chem Ber 49 90, 93 1916, IR: Kuhn Anal Chem 22 276 1950, Beilstein 19/12 V 318.]

Diacetone-D-glucose Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Diacetone-D-glucose manufacturers

Xinxiang Aurora Biotechnology Co.,Ltd.

Product: Diacetone-D-glucose 582-52-5
Price: US $0.00-0.00/Kg
Min. Order: 1Kg
Purity: 98%
Supply Ability: 20Ton
Release date: 2024-11-01

Baoji Guokang Bio-Technology Co., Ltd.

Product: Diacetone-D-glucose 582-52-5
Price: US $95.00/Kg/Bag
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2021-06-02

Hebei Yanxi Chemical Co., Ltd.

Product: Diacetone-d-Glucose 582-52-5
Price: US $0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 20tons
Release date: 2023-10-10

582-52-5, Diacetone-D-glucoseRelated Search:

Acetylacetone 1,2-O-Isopropylidene-D-glucofuranose D-Glucose monohydrate Calcium pyruvate Pyruvic acid D(+)-Glucose Diacetone acrylamide CORN SYRUP 2,5-Hexanedione Diacetone Alcohol Glucose oxidase 1,2:5,6-Bis-O-(1-methylethylidene)-D-mannitol Propiophenone L-GLUCOSE DIACETONE-D-GLUCOSE Acetone Diacetin Phenylacetone

1,2:5,6-O-DI-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSIDE

1,2:5,6-DIISOPROPYLENE-ALPHA-D-GLUCOFURANOSE

5-(2,2-DIMETHYL-[1,3]DIOXOLAN-4-YL)-2,2-DIMETHYL-TETRAHYDRO-FURO[2,3-D][1,3]DIOXOLE

A-D-GLUCOFURANOSE

Diacetone-D-glucose, 98+%

DIACETONE-D-GLUCOSE

DIACETONEGLUCOSE

DIACETONE-ALPHA-D-GLUCOSE

DIACETONE-ALPHA-D-GLC

D-GLUCOSE DIACETONIDE

DIISOPROPYLIDENEGLUCOFURANOSE

DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE, 1,2,5,6-

GLUCOFURANOSE

.alpha.-D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)-

1,2:5,6-di-o-isopropylidene-à-d-glucofuranose

1,2:5,6-Di-O-isopropylidene-a-L-glucofuranose

1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE,98%

a-D-Glucofuranose, 1,2:5,6-bis-O-(1-methylethylidene)-

Diacetone-D-Glucose/1,2:5,6-Di-O-Isopropylidene-Alpha-D-Glucofuranose

1,2:5,6-Di-isopropylidene-glucofuranose

1,2:5,6-DI-O-ISOPROPYLIDENE-ALFA-D-GLUCOFURANOSE

1,2,5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE (DIACETONE-D-GLUCOSE)

D-Glucose diacetonide, Diacetone-D-glucose

1,2,5,6-diisopropylidene-D-glucose, D-Glucose diacetonide, Diacetone-D-glucose

(3aR,5S,6S,6aR)-5-[(4S)-2,2-Dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[4,5-d][1,3]dioxol-6-ol

Di-O-isopropylidene-a-D-glucofuranose

Glucose bisacetonide

1,2,5,6-Di-O-isopropylidene-|-L-glucofuranose

(3aR,3aα,6aα)-5α-[(4R)-2,2-Dimethyl-1,3-dioxolane-4-yl]-2,2-dimethyltetrahydrofuro[2,3-d]-1,3-dioxole-6α-ol

1-O,2-O:5-O,6-O-Bis(1-methylethylidene)-α-D-glucofuranose

1-O,2-O:5-O,6-O-Bis(isopropylidene)-α-D-glucofuranose

1-O,2-O:5-O,6-O-Diisopropylidene-α-D-glucofuranose

Diacetone-D-g

ucose

1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose, Min. 99%

(3aR,5S,6S,6aR)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-tetrahydro-2H-furo[2,3-d][1,3]dioxol-6-ol

1,2,5,6-DIISOPROPYLIDENE-D-GLUCOSE

1,2:5,6-DIISOPROPYLIDENE-D-GLUCOSE

1,2;5,6-DI-O-ISOPROPYLIDENE-D-GLUCOFURANOSE

1,2,5,6-DI-O-ISO-PROPYLIDENEGLUCOFURANOSE

1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSIDE

1,2:5,6-DI-O-ISOPROPYLDENE-ALPHA-D-GLUCOFURANOSE

1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE

(-)-1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE

1,2,5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE

1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE

1,2:5,6-bis-o-(1-methylethylidene)-alpha-d-glucofuranos

1:2,5:6-di-o-isopropyliden-alpha-d-glucofuranose

5:6-di-o-isopropylidene-1:alpha-d-glucofuranos

Diacetin Glucose

1,2,5,6-Di-O-isopropylidene-alpha-D-glucofuranose (Diacetone-D-g

Diacetone-D-Glucos

1,2:5,6-Bis-O-(1-Methylethylidene)-α-D-glucofuranose

1,2:5,6-Di-O-isopropylidene-D-glucose

NSC 1223

5,6-Di-O-isopropylidene-alpha-D-glucofuranose

(-)-1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUC

1,2:5,6-Bis-O-(1-Methylethylidene)-a-D-Glucofuranose