ChemicalBook > CAS DataBase List > Methyltriphenylphosphonium iodide

Methyltriphenylphosphonium iodide

Product Name
Methyltriphenylphosphonium iodide
CAS No.
2065-66-9
Chemical Name
Methyltriphenylphosphonium iodide
Synonyms
methyltriphenylphosphonium;MPJ;Methyltriphenylphosp;MethyltriphenylphosphoniuM iod;Triphenylmethylphosphine iodide;METHYLTRIPHENYPHOSPHONIUMIODIDE;Methyltriphenylphosphanium iodid;Triphenylmethylphosphinium iodide;METHYLTRIPHENYLPHOSPHONIUM IODIDE;Methyltriphenylphosphanium iodide
CBNumber
CB3673698
Molecular Formula
C19H18IP
Formula Weight
404.22
MOL File
2065-66-9.mol
More
Less

Methyltriphenylphosphonium iodide Property

Melting point:
183-185 °C(lit.)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Powder
color 
White to light yellow
Water Solubility 
SOLUBLE
Sensitive 
Light Sensitive & Hygroscopic
InChI
InChI=1S/C19H18P.HI/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
InChIKey
JNMIXMFEVJHFNY-UHFFFAOYSA-M
SMILES
[P+](C)(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[I-]
CAS DataBase Reference
2065-66-9(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi,T
Risk Statements 
36/37/38-25
Safety Statements 
26-36-45-37/39-28A
RIDADR 
UN3464
WGK Germany 
3
HazardClass 
6.1
PackingGroup 
III
HS Code 
29319090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
245054
Product name
Methyltriphenylphosphonium iodide
Purity
97%
Packaging
25g
Price
$86.9
Updated
2024/03/01
TCI Chemical
Product number
M0253
Product name
Methyltriphenylphosphonium Iodide
Purity
>98.0%(T)
Packaging
25g
Price
$48
Updated
2024/03/01
TCI Chemical
Product number
M0253
Product name
Methyltriphenylphosphonium Iodide
Purity
>98.0%(T)
Packaging
100g
Price
$153
Updated
2024/03/01
Alfa Aesar
Product number
A15644
Product name
Methyltriphenylphosphonium iodide, 98%
Packaging
25g
Price
$52.65
Updated
2024/03/01
Alfa Aesar
Product number
A15644
Product name
Methyltriphenylphosphonium iodide, 98%
Packaging
100g
Price
$153.65
Updated
2024/03/01
More
Less

Methyltriphenylphosphonium iodide Chemical Properties,Usage,Production

Chemical Properties

WHITE TO LIGHT YELLOW POWDER

Uses

suzuki reaction

Uses

Methyltriphenylphosphonium iodide is as a reactant for synthesis of triphenylamine-based dyes and polyolefinic aromatic molecules with pyrene for use in dye-sensitized solar cells. Used as ligand in coupling reaction. It is also used as a precursor to a Wittig reagent.

Preparation

Methyltriphenylphosphonium iodide was prepared by the following procedure. Triphenylphosphine was recrystallized from ethanol and dried over phosphorus pentoxide under reduced pressure for 12 hr. A solution of 39 g (0.15 mol) of triphenylphosphine and 10.0 mL (22.8 g, 0.16 mol) of iodomethane in 105 mL of benzene was allowed to stir at room temperature for 12 hr. The precipitate was filtered, washed with benzene, and dried over phosphorus pentoxide under reduced pressure for 12 hr. The yield was 57 g (94%), mp 189°C (lit.2 mp 182°C).

Methyltriphenylphosphonium iodide Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Methyltriphenylphosphonium iodide Suppliers

HBCChem, Inc.
Tel
+1-510-219-6317
Fax
+1-650-486-1361
Email
sales@hbcchem.com
Country
United States
ProdList
10648
Advantage
60
AbaChemScene
Tel
732-484-9848
Fax
888-484-5008
Email
sales@chemscene.com
Country
United States
ProdList
3982
Advantage
60
Alfa Chemistry
Tel
Fax
1-516-927-0118
Email
Info@alfa-chemistry.com
Country
United States
ProdList
24072
Advantage
58
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
United States Biological
Tel
--
Fax
--
Email
sales@advtechind.com
Country
United States
ProdList
6075
Advantage
58
MD Chemicals
Tel
--
Fax
--
Email
info@mdchemicals.net
Country
United States
ProdList
158
Advantage
58
Moravek, Inc.
Tel
--
Fax
--
Email
info@moravek.com
Country
United States
ProdList
279
Advantage
58
Alichem Inc.
Tel
--
Fax
--
Email
sales@alichem.com
Country
United States
ProdList
6167
Advantage
58
Narchem Corporation
Tel
--
Fax
--
Email
sales@narchem.com
Country
United States
ProdList
2813
Advantage
60
Oakwood Products, Inc.
Tel
--
Fax
--
Email
sales@oakwoodchemical.com
Country
United States
ProdList
6193
Advantage
74
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
Advantage
69
SynQuest Laboratories, Inc.
Tel
--
Fax
--
Email
info@synquestlabs.com
Country
United States
ProdList
6871
Advantage
62
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Frontier Scientific, Inc.
Tel
--
Fax
--
Email
sales@frontiersci.com
Country
United States
ProdList
6222
Advantage
86
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
Ryan Scientific, Inc.
Tel
--
Fax
--
Email
ryan.reichlyn@ryansci.com
Country
United States
ProdList
6439
Advantage
60
HONEST JOY HOLDINGS LIMITED
Tel
--
Fax
--
Email
sales@honestjoy.cn
Country
United States
ProdList
6675
Advantage
54
AK Scientific, Inc.
Tel
--
Fax
--
Email
sales@aksci.com
Country
United States
ProdList
6347
Advantage
65
More
Less

View Lastest Price from Methyltriphenylphosphonium iodide manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Methyltriphenylphosphonium iodide 2065-66-9
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-23
Hebei Weibang Biotechnology Co., Ltd
Product
Methyltriphenylphosphonium iodide 2065-66-9
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-29
Hebei Chuanghai Biotechnology Co,.LTD
Product
Methyltriphenylphosphonium iodide 2065-66-9
Price
US $9.00/KG
Min. Order
1KG
Purity
99.9
Supply Ability
1 ton
Release date
2024-08-21

2065-66-9, Methyltriphenylphosphonium iodideRelated Search:


  • METHYLTRIPHENYLPHOSPHONIUM IODIDE
  • MPJ
  • TRIPHENYLMETHYL PHOSPHONIUM IODIDE
  • Methyl triphenylphosphonium iodide, 98+%
  • METHYLTRIPHENYPHOSPHONIUMIODIDE
  • Methyltriphenylphosphanium iodide
  • Phosphonium, methyltriphenyl-, iodide
  • Triphenylmethylphosphine iodide
  • Triphenylmethylphosphinium iodide
  • methyltriphenylphosphonium
  • Methyltriphenylphosphonium iodide,97%
  • Methyl(trisphenyl)phosphonium iodide
  • Methyltriphenylphosp
  • MethyltriphenylphosphoniuM iod
  • MethylTriphenyl phosphoniuM iodine
  • Methyl(trisphenyl)phosphonium iodide 97%
  • MethyltriphenylphosphoniuM Iodide , 98.0%(T)
  • Methyltriphenylphosphonium iodide 97%
  • METHYL TRIPHENYL PHOSPHONIUM IODIDE MTPPI
  • Methyltriphenylphosphanium iodid
  • MethyltriphenylphosphoniumIodide&gt
  • 2065-66-9
  • C19H19IP
  • C19H18PI
  • C6H53PCH3I
  • Wittig Reagents
  • Synthetic Reagents
  • Olefination
  • Wittig Reaction
  • Wittig & Horner-Emmons Reaction
  • Phosphonium Compounds
  • C-C Bond Formation
  • C-C Bond Formation
  • Olefination
  • Wittig Reagents
  • Phosphonium Compounds
  • Synthetic Organic Chemistry
  • Wittig & Horner-Emmons Reaction
  • Wittig Reaction