3-Bromophenylboronic acid
- Product Name
- 3-Bromophenylboronic acid
- CAS No.
- 89598-96-9
- Chemical Name
- 3-Bromophenylboronic acid
- Synonyms
- 3-Bromophenylboronic;M-BBBA;AKOS BRN-0083;RARECHEM AH PB 0076;3-bromophenylboric acid;3-BROMOPHENYLBORONIC ACID;3-BROMOBENZENEBORONIC ACID;3-Bromophenylboronic acid,97%;B-(3-bromophenyl)boronic acid;3-Bromophenylboronic acid ,98%
- CBNumber
- CB3755185
- Molecular Formula
- C6H6BBrO2
- Formula Weight
- 200.83
- MOL File
- 89598-96-9.mol
3-Bromophenylboronic acid Property
- Melting point:
- 164-168 °C (lit.)
- Boiling point:
- 330.5±44.0 °C(Predicted)
- Density
- 1.67±0.1 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- DMSO (Slightly), Methanol (Slightly)
- pka
- 7.55±0.10(Predicted)
- form
- Crystalline Powder
- color
- White
- BRN
- 3127104
- InChI
- InChI=1S/C6H6BBrO2/c8-6-3-1-2-5(4-6)7(9)10/h1-4,9-10H
- InChIKey
- AFSSVCNPDKKSRR-UHFFFAOYSA-N
- SMILES
- B(C1=CC=CC(Br)=C1)(O)O
- CAS DataBase Reference
- 89598-96-9(CAS DataBase Reference)
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 36/37/38-22
- Safety Statements
- 37/39-26
- WGK Germany
- 3
- HazardClass
- IRRITANT
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 441627
- Product name
- 3-Bromophenylboronic acid
- Packaging
- 5g
- Price
- $87.3
- Updated
- 2025/07/31
- Product number
- B2890
- Product name
- 3-Bromophenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 1g
- Price
- $33
- Updated
- 2025/07/31
- Product number
- B2890
- Product name
- 3-Bromophenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 5g
- Price
- $86
- Updated
- 2025/07/31
- Product number
- B2890
- Product name
- 3-Bromophenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 25g
- Price
- $258
- Updated
- 2025/07/31
- Product number
- 261932
- Product name
- 3-Bromophenyl boronic acid
- Packaging
- 5g
- Price
- $345
- Updated
- 2021/12/16
3-Bromophenylboronic acid Chemical Properties,Usage,Production
Chemical Properties
white to light yellow crystal powder
Uses
Reactant involved in a variety of organic reactions including:• ;Oxidative cross coupling1,2• ;Gold salt catalyzed homocoupling3• ;1,4-Addition reactions with α,β-unsaturated ketones4• ;Enantioselective addition reactions5• ;Suzuki-Miyaura coupling for synthesis of anthranilamide-protected arylboronic acids6• ;C-H Functionalization of quinones7
Uses
suzuki reaction
Uses
Reactant involved in a variety of organic reactions including:
- Oxidative cross coupling
- Gold salt catalyzed homocoupling
- 1,4-Addition reactions with α,β-unsaturated ketones
- Enantioselective addition reactions
- Suzuki-Miyaura coupling for synthesis of anthranilamide-protected arylboronic acids
- C-H Functionalization of quinones
Synthesis
121-43-7
591-18-4
89598-96-9
In a 500 mL round bottom flask, 1-bromo-3-iodobenzene (25.0 g, 88 mmol) was dissolved in 200 mL of tetrahydrofuran. The reaction solution was cooled to -78°C under nitrogen protection. n-Butyllithium (60.75 mL, 97 mmol) was slowly added dropwise to the cooled solution over a period of 30 minutes and stirring was continued at the same temperature for 1 hour. Subsequently, trimethyl borate (11 g, 106 mmol) was added dropwise at the same temperature, and then the mixture was gradually warmed to room temperature and stirred overnight. Upon completion of the reaction, 2 equivalents of hydrochloric acid was added dropwise to the reaction solution for acidification and stirring was continued for 1 hour. The reaction mixture was extracted with ethyl acetate, the organic layers were combined and concentrated under reduced pressure. The resulting crystals were dissolved in cold hexane to give Intermediate 11-a (12 g, 67.6% yield).
References
[1] Patent: KR2015/130206, 2015, A. Location in patent: Paragraph 0862-0867
[2] Patent: KR2016/13678, 2016, A. Location in patent: Paragraph 0324-0330
3-Bromophenylboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-Bromophenylboronic acid manufacturers
- Product
- 3-Bromophenylboronic acid 89598-96-9
- Price
- US $34.00-1.20/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-08
- Product
- pharm intermediates 3-Bromophenylboronic acid 89598-96-9
- Price
- US $48.00-40.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200tons
- Release date
- 2021-04-16
- Product
- 3-Bromophenylboronic acid 89598-96-9
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%Min
- Supply Ability
- 1000kg
- Release date
- 2023-03-12