3-Bromophenylboronic acid

Product Name: 3-Bromophenylboronic acid
CAS No.: 89598-96-9
Chemical Name: 3-Bromophenylboronic acid
Synonyms: 3-Bromophenylboronic;M-BBBA;AKOS BRN-0083;RARECHEM AH PB 0076;3-bromophenylboric acid;3-BROMOPHENYLBORONIC ACID;3-BROMOBENZENEBORONIC ACID;3-Bromophenylboronic acid,97%;B-(3-bromophenyl)boronic acid;3-Bromophenylboronic acid ,98%
CBNumber: CB3755185
Molecular Formula: C6H6BBrO2
Formula Weight: 200.83
MOL File: 89598-96-9.mol

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3-Bromophenylboronic acid Property

Melting point:: 164-168 °C (lit.)
Boiling point:: 330.5±44.0 °C(Predicted)
Density: 1.67±0.1 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: DMSO (Slightly), Methanol (Slightly)
pka: 7.55±0.10(Predicted)
form: Crystalline Powder
color: White
BRN: 3127104
InChI: InChI=1S/C6H6BBrO2/c8-6-3-1-2-5(4-6)7(9)10/h1-4,9-10H
InChIKey: AFSSVCNPDKKSRR-UHFFFAOYSA-N
SMILES: B(C1=CC=CC(Br)=C1)(O)O
CAS DataBase Reference: 89598-96-9(CAS DataBase Reference)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 36/37/38-22
Safety Statements: 37/39-26
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 441627
Product name: 3-Bromophenylboronic acid
Packaging: 5g
Price: $87.3
Updated: 2025/07/31

TCI Chemical

Product number: B2890
Product name: 3-Bromophenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $33
Updated: 2025/07/31

TCI Chemical

Product number: B2890
Product name: 3-Bromophenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $86
Updated: 2025/07/31

TCI Chemical

Product number: B2890
Product name: 3-Bromophenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 25g
Price: $258
Updated: 2025/07/31

TRC

Product number: B687625
Product name: 3-Bromophenylboronic acid
Packaging: 2.5g
Price: $65
Updated: 2021/12/16

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3-Bromophenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powder

Uses

Reactant involved in a variety of organic reactions including:• ;Oxidative cross coupling1,2• ;Gold salt catalyzed homocoupling3• ;1,4-Addition reactions with α,β-unsaturated ketones4• ;Enantioselective addition reactions5• ;Suzuki-Miyaura coupling for synthesis of anthranilamide-protected arylboronic acids6• ;C-H Functionalization of quinones7

Uses

suzuki reaction

Uses

Reactant involved in a variety of organic reactions including:

Oxidative cross coupling
Gold salt catalyzed homocoupling
1,4-Addition reactions with α,β-unsaturated ketones
Enantioselective addition reactions
Suzuki-Miyaura coupling for synthesis of anthranilamide-protected arylboronic acids
C-H Functionalization of quinones

Synthesis

121-43-7

591-18-4

89598-96-9

In a 500 mL round bottom flask, 1-bromo-3-iodobenzene (25.0 g, 88 mmol) was dissolved in 200 mL of tetrahydrofuran. The reaction solution was cooled to -78°C under nitrogen protection. n-Butyllithium (60.75 mL, 97 mmol) was slowly added dropwise to the cooled solution over a period of 30 minutes and stirring was continued at the same temperature for 1 hour. Subsequently, trimethyl borate (11 g, 106 mmol) was added dropwise at the same temperature, and then the mixture was gradually warmed to room temperature and stirred overnight. Upon completion of the reaction, 2 equivalents of hydrochloric acid was added dropwise to the reaction solution for acidification and stirring was continued for 1 hour. The reaction mixture was extracted with ethyl acetate, the organic layers were combined and concentrated under reduced pressure. The resulting crystals were dissolved in cold hexane to give Intermediate 11-a (12 g, 67.6% yield).

References

[1] Patent: KR2015/130206, 2015, A. Location in patent: Paragraph 0862-0867
[2] Patent: KR2016/13678, 2016, A. Location in patent: Paragraph 0324-0330

3-Bromophenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Bromophenylboronic acid Suppliers

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View Lastest Price from 3-Bromophenylboronic acid manufacturers

Henan Fengda Chemical Co., Ltd

Product: 3-Bromophenylboronic acid 89598-96-9
Price: US $34.00-1.20/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-08

Guangzhou Sunton Biotechnology Co., Ltd.

Product: pharm intermediates 3-Bromophenylboronic acid 89598-96-9
Price: US $48.00-40.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200tons
Release date: 2021-04-16

LY Global chemicals co.,ltd .

Product: 3-Bromophenylboronic acid 89598-96-9
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%Min
Supply Ability: 1000kg
Release date: 2023-03-12

89598-96-9, 3-Bromophenylboronic acidRelated Search:

1,2-Dibromobenzene Bromoxynil 4-Bromobenzaldehyde Triphenylphosphine Folic acid Glycine Phenylboronic acid Ethyl 2-(Chlorosulfonyl)acetate 4-Bromobenzotrifluoride Bromoxynil octanoate 3-Bromofluorobenzene 2-Bromobenzaldehyde Zinc borate 1,4-Dibromobenzene 4-BROMOPHENYLBORONIC ACID,P-BROMOPHENYLBORONIC ACID,4-Bromophenylboronic Acid (contains varying amounts of Anhydride) Phenylacetone 5-BROMO-2-ETHOXYPHENYLBORONIC ACID 1-Bromo-4-nitrobenzene

RARECHEM AH PB 0076

AKOS BRN-0083

3-BROMOBENZENEBORONIC ACID

3-BROMOPHENYLBORONIC ACID

3-Bromophenylboronic

3-Bromophenylboronic Acid (contains varying amounts of Anhydride)

3-Bromobenzeneboronic acid, 98+%

3-Bromophenylboronic acid,97%

3-Bromophenylboronic acid ,98%

3-Bromophenylboronic acid , May contain varying amounts of anhydride, 97%

3-BroMophenylboronic acid, 97% 5GR

Boronic acid, (3-broMophenyl)-

3-BroMophenylboronic acid, 97%, May contain varying aMounts of anhydride

Boronicacid, B-(3-broMophenyl)-

M-BBBA

B-(3-bromophenyl)boronic acid

pharm intermediates 3-Bromophenylboronic acid

Boronic acid, B-(3-bromophenyI)-

3-bromophenylboric acid

meta-bromophenylboronic acid, 98%

3-Bromophenylboronic acid - [B1920]

89598-96-9

C6H6O2BBr

Aryl

Boronic Acids

Boronic Acids and Derivatives

Organometallic Reagents

Aryl Boronic Acids

Boronic Acids and Derivatives

Chemical Synthesis

Monosubstituted Aryl Boronic Acids

Organometallic Reagents

Boronate Ester

Potassium Trifluoroborate

Boronic Acids and Derivatives

blocks

BoronicAcids

Bromides

Boric Acid

Boronic acids

Boronic Acid

B (Classes of Boron Compounds)

Boronic Acids

Aryl

Organoborons