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Methyl hex-3-enoate

Product Name
Methyl hex-3-enoate
CAS No.
2396-78-3
Chemical Name
Methyl hex-3-enoate
Synonyms
FEMA 3364;Fema no. 3364;Einecs 219-256-1;METHYL-3-HEXENOATE;METHYL 3 HEXANOATE;88+%trans-isomeres;METHYL T3 HEXENOATE;Methyl hydrosorbate;methyl hex-3-enoate;Methyl (3E)-3-hexenoate
CBNumber
CB3770005
Molecular Formula
C7H12O2
Formula Weight
128.17
MOL File
2396-78-3.mol
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Methyl hex-3-enoate Property

Melting point:
-62.68°C (estimate)
Boiling point:
169 °C (lit.)
Density 
0.913 g/mL at 25 °C (lit.)
refractive index 
1.4260
FEMA 
3364 | METHYL 3-HEXENOATE
Flash point:
115 ºF
storage temp. 
Flammables area
form 
Liquid
color 
Clear colorless to faintly yellow
Odor
at 10.00 % in dipropylene glycol. earthy sweet slightly fruity
Odor Type
earthy
JECFA Number
334
LogP
2.38
NIST Chemistry Reference
3-Hexenoic acid, methyl ester(2396-78-3)
EPA Substance Registry System
3-Hexenoic acid, methyl ester (2396-78-3)
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Safety

Risk Statements 
10
Safety Statements 
16
RIDADR 
UN 3272
WGK Germany 
3
HS Code 
29161900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W336408
Product name
Methyl trans-3-hexenoate
Purity
≥97%, FG
Packaging
sample-k
Price
$59.8
Updated
2024/03/01
Sigma-Aldrich
Product number
W336408
Product name
Methyl trans-3-hexenoate
Purity
≥97%, FG
Packaging
1kg
Price
$550
Updated
2024/03/01
Sigma-Aldrich
Product number
W336408
Product name
Methyl trans-3-hexenoate
Purity
≥97%, FG
Packaging
100g
Price
$97.5
Updated
2023/01/07
Frontier Specialty Chemicals
Product number
JK743874
Product name
Methyl trans-3-hexenoate
Purity
98%
Packaging
5g
Price
$54
Updated
2021/12/16
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Methyl hex-3-enoate Chemical Properties,Usage,Production

Description

Prepared by selective hydrogenation of methyl sorbate; from 3-hexenoic acid and methanol in the presence of BF3.

Chemical Properties

Clear colorless to faintly yellow liquid

Occurrence

Reported found as a volatile component in cayenne and pineapple. Also reported found in prickly pear, soursop, mountain papaya, guava and Virginia tobacco.

Aroma threshold values

Aroma characteristics at 1.0%: sweet sharp green, juicy fresh fruity with tropical and vegetative nuances.

Taste threshold values

Taste characteristics at 5 ppm: sweet green, banana-like, slightly acidic with fruity nuances of pineapple, pear, apple and passion fruit

Synthesis Reference(s)

Chemistry Letters, 11, p. 715, 1982
The Journal of Organic Chemistry, 51, p. 537, 1986 DOI: 10.1021/jo00354a027

Methyl hex-3-enoate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl hex-3-enoate manufacturers

Career Henan Chemical Co
Product
Methyl hex-3-enoate 2396-78-3
Price
US $2.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100g , 1kg, 5kg , 50kg
Release date
2020-01-07

2396-78-3, Methyl hex-3-enoateRelated Search:


  • METHYL TRANS-3-HEXENOATE
  • FEMA 3364
  • 3-Hexenoicacid,methylester
  • Hydrosorbic acid, methyl ester
  • METHYL 3-HEXENOATE, PREDOMINANTLY TRANS, 95+%
  • Methyl 3-hexenoate, predominantly trans
  • Methyl 3-hexenoate,95+%,predominantly trans
  • Einecs 219-256-1
  • Fema no. 3364
  • Methyl hydrosorbate
  • METHYL T3 HEXENOATE
  • METHYL-3-HEXENOATE
  • Methyl (3E)-3-hexenoate
  • methyl hex-3-enoate
  • METHYL 3 HEXANOATE
  • 88+%trans-isomeres
  • Methyl hex-3-enoate USP/EP/BP
  • 2396-78-3
  • CH3CH2CHCHCH2CO2CH3
  • 2396783
  • Alphabetical Listings
  • Flavors and Fragrances
  • M-N