ChemicalBook > CAS DataBase List > 2-Methyl-4-nitropyridine

2-Methyl-4-nitropyridine

Product Name
2-Methyl-4-nitropyridine
CAS No.
13508-96-8
Chemical Name
2-Methyl-4-nitropyridine
Synonyms
NSC 170691;4-NITRO-2-PICOLINE;2-Amino-5-hydroxypyr;2-Mehtyl-4-nitropyridine;4-NITRO-2-METHYLPYRIDINE;2-METHYL-4-NITROPYRIDINE;Pyridine, 2-methyl-4-nitro-;2-Methyl-4-nitropyridine ,97%;Pyridine, 2-methyl-4-nitro- (9CI);2-METHYL-4-NITROPYRIDINE,4-NITRO-2-PICOLINE
CBNumber
CB3779886
Molecular Formula
C6H6N2O2
Formula Weight
138.12
MOL File
13508-96-8.mol
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2-Methyl-4-nitropyridine Property

Melting point:
32-34 °C
Boiling point:
241.5±20.0 °C(Predicted)
Density 
1.246±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Chloroform, Dichloromethane
form 
Solid
pka
2.04±0.10(Predicted)
color 
Yellow
CAS DataBase Reference
13508-96-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-41
Safety Statements 
26-39-24/25
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P330Rinse mouth.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

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N-Bromosuccinimide Price

TRC
Product number
M325625
Product name
2-Methyl-4-nitropyridine
Packaging
250mg
Price
$50
Updated
2021/12/16
TRC
Product number
M325625
Product name
2-Methyl-4-nitropyridine
Packaging
2g
Price
$105
Updated
2021/12/16
Usbiological
Product number
M3526-70
Product name
2-Methyl-4-nitropyridine
Packaging
1g
Price
$531
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0021364
Product name
2-METHYL-4-NITROPYRIDINE
Purity
95.00%
Packaging
1G
Price
$624.07
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0021364
Product name
2-METHYL-4-NITROPYRIDINE
Purity
95.00%
Packaging
5G
Price
$902.1
Updated
2021/12/16
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2-Methyl-4-nitropyridine Chemical Properties,Usage,Production

Chemical Properties

Yellow Solid

Uses

2-Methyl-4-nitropyridine (cas# 13508-96-8) is a compound useful in organic synthesis.

Synthesis

5470-66-6

13508-96-8

a) To a chloroform solution of 4-nitro-2-methylpyridine-N-oxide (11 g, 71.5 mmol) was slowly added a chloroform solution of phosphorus trichloride (PCl3, 33 mL, 0.37 mmol) at 0 °C and under argon protection. The reaction mixture was stirred at room temperature for 3 hours. Upon completion of the reaction, the mixture was poured into ice water and neutralized with ammonium hydroxide solution to neutral, followed by extraction with dichloromethane. The organic phases were combined and concentrated to give a yellow solid product. The solid was washed with a mixed ether-petroleum ether solvent to give 7.8 g of 2-methyl-4-nitropyridine in 79% yield with a melting point of 35 °C.

References

[1] Organic Letters, 2000, vol. 2, # 22, p. 3525 - 3526
[2] Chemical and Pharmaceutical Bulletin, 1998, vol. 46, # 10, p. 1656 - 1657
[3] Chemical and Pharmaceutical Bulletin, 1990, vol. 38, # 9, p. 2446 - 2458
[4] Journal of Organic Chemistry, 1998, vol. 63, # 15, p. 5013 - 5030
[5] Synlett, 2009, # 18, p. 2927 - 2930

2-Methyl-4-nitropyridine Preparation Products And Raw materials

Raw materials

Chloroform Phosphorus trichloride 4-Nitro-2-picoline N-oxide Dichloromethane

Preparation Products

4-Chloropyridine-2-carboxylic acid
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View Lastest Price from 2-Methyl-4-nitropyridine manufacturers

Dideu Industries Group Limited
Product
2-Methyl-4-nitropyridine 13508-96-8
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons min
Release date
2021-09-08
Career Henan Chemical Co
Product
2-Methyl-4-nitropyridine 13508-96-8
Price
US $100.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2018-08-03

13508-96-8, 2-Methyl-4-nitropyridineRelated Search:

Methyl salicylate 4-Methylpyridine 2-Picoline Methyl acetate Pirimiphos-methyl Tribenuron methyl METSULFURON METHYL Chromium picolinate 2-Methyl-3-nitropyridine DIMETHYLAMINOPYRIDINE, POLYMER-BOUND Kresoxim-methyl 2-Chloro-5-chloromethylpyridine 2,6-Lutidine 2,4,6-Collidine 4-Nitropyridine 2,5-Dimethylpyridine Thiophanate-methyl 21203-68-9 2-Methyl-5-nitropyridine,2-Methyl-5-nitropyridine Hydrochloride

  • 2-METHYL-4-NITROPYRIDINE
  • 4-NITRO-2-METHYLPYRIDINE
  • 4-NITRO-2-PICOLINE
  • Pyridine, 2-methyl-4-nitro- (9CI)
  • 2-METHYL-4-NITROPYRIDINE,4-NITRO-2-PICOLINE
  • Pyridine, 2-methyl-4-nitro-
  • 2-Methyl-4-nitropyridine ,97%
  • 2-Mehtyl-4-nitropyridine
  • NSC 170691
  • 2-Amino-5-hydroxypyr
  • 2-Methyl-4-nitropyridine ISO 9001：2015 REACH
  • 13508-96-8
  • 3508-96-8
  • Aromatics
  • Bases & Related Reagents
  • Nucleotides
  • Pyridine series
  • Pyridines derivates
  • Building Blocks
  • Aromatics Compounds
  • NITRO
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  • NitroCompounds
  • Pyridines
  • Pyridine