2,2-Bis[4-(4-aminophenoxy)phenyl]propane

Product Name: 2,2-Bis[4-(4-aminophenoxy)phenyl]propane
CAS No.: 13080-86-9
Chemical Name: 2,2-Bis[4-(4-aminophenoxy)phenyl]propane
Synonyms: BAPP;2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE;4-BAPOPP;4,4'-(4,4'-Isopropyl;2,2’-bis(4-aminophenoxyphenyl)propane;2,2'-Bis(4-aminophenoxyphenyl) propane;2,2-Bis[4-(4-aminophenoxy)phenyl]propan;2,2-Bis[p-(4-aMinophenoxy)phenyl]propane;2,2'-Bis[4-(4-aminophenoxy)pheny]propane;2,2-Bis[p-(p-aminophenoxy)phenyl]propane
CBNumber: CB3780578
Molecular Formula: C27H26N2O2
Formula Weight: 410.51
MOL File: 13080-86-9.mol

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2,2-Bis[4-(4-aminophenoxy)phenyl]propane Property

Melting point:: 127-130 °C(lit.)
Boiling point:: 587.1±50.0 °C(Predicted)
Density: 1.178±0.06 g/cm3(Predicted)
vapor pressure: 0-0Pa at 20-25℃
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: Solid:particulate/powder
pka: 5.16±0.10(Predicted)
Water Solubility: Very slightly soluble in water. Soluble in acetone, Dimethyl sulfoxide(DMSO).
InChI: InChI=1S/C27H26N2O2/c1-27(2,19-3-11-23(12-4-19)30-25-15-7-21(28)8-16-25)20-5-13-24(14-6-20)31-26-17-9-22(29)10-18-26/h3-18H,28-29H2,1-2H3
InChIKey: KMKWGXGSGPYISJ-UHFFFAOYSA-N
SMILES: C(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C)C
LogP: 4.3-4.9 at 35℃ and pH7
CAS DataBase Reference: 13080-86-9(CAS DataBase Reference)
EPA Substance Registry System: Benzenamine, 4,4'-[(1-methylethylidene)bis(4,1-phenyleneoxy)]bis- (13080-86-9)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-36/37/38
Safety Statements: 26-36
WGK Germany: 3
RTECS: CY1062500
TSCA: Yes
HS Code: 29222990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 476331
Product name: 4,4′-(4,4′-Isopropylidenediphenyl-1,1′-diyldioxy)dianiline
Purity: 98%
Packaging: 50g
Price: $82.8
Updated: 2024/03/01

TCI Chemical

Product number: B1551
Product name: 2,2-Bis[4-(4-aminophenoxy)phenyl]propane
Purity: >98.0%(HPLC)(T)
Packaging: 25g
Price: $37
Updated: 2024/03/01

TCI Chemical

Product number: B1551
Product name: 2,2-Bis[4-(4-aminophenoxy)phenyl]propane
Purity: >98.0%(HPLC)(T)
Packaging: 250g
Price: $228
Updated: 2024/03/01

Alfa Aesar

Product number: H55057
Product name: 2,2-Bis[4-(4-aminophenoxy)phenyl]propane, 98%
Packaging: 25g
Price: $34.65
Updated: 2024/03/01

Alfa Aesar

Product number: H55057
Product name: 2,2-Bis[4-(4-aminophenoxy)phenyl]propane, 98%
Packaging: 100g
Price: $112
Updated: 2024/03/01

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2,2-Bis[4-(4-aminophenoxy)phenyl]propane Chemical Properties,Usage,Production

Description

2,2-Bis[4-(4-aminophenoxy)phenyl]propane (BAPP), also known as 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline, is a diamino monomer with a diphenoxy-phenyl core. Since the molecule has two amine groups at both ends, it can be cross-linked with carboxylic acids or carboxylic dianhydrides to synthesize polyimides. It is commonly as a monomer for the preparation of polyimides in application of batteries, fuel cells, low dielectric materials and OLEDs.

Chemical Properties

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline (2,2-Bis[4-(4-aminophenoxy)phenyl]propane) is white solid

Uses

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline is used for preparation polyimide and epoxy resin material.

Uses

It is applied in pharmaceutical industry.

Application

2,2-Bis[4-(4-aminophenoxy)phenyl] propane (BAPP) can be used for:
(1) Preparation of polyimides. The glass transition temperature of this new polyimide is about 225-230°C. It has the typical yield of thermoplastic polymers. It has a typical thermoplastic polymer yield behaviour, which is very different from other polyimides. The elongation at break was 6% and 29% for polyamide and polyimide, respectively.
(2) Curing epoxy resin (ER) and poly(?-caprolactone) (PCL) for the preparation of crystalline thermoset blends.
(3) Constructing dental resin composites.

Synthesis

2,2‐Bis[4‐(4‐aminophenoxy)phenyl] propane (BAPP), as a monomer to prepare polyimide, was synthesized from Bisphenol A and p‐chloronitrobenzene via the nucleophilic substitution reaction^[1].

References

[1] CUILI KONG. Synthesis, Structures and Properties of Polyimide Based on 2,2′‐Bis(4‐aminophenoxy phenyl) Propane[J]. Journal of Macromolecular Science, Part A, 2006. DOI:10.1080/10601320600941086.

2,2-Bis[4-(4-aminophenoxy)phenyl]propane Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2-Bis[4-(4-aminophenoxy)phenyl]propane Suppliers

Americas 1 China 279 Europe 1 France 1 Germany 3 India 3 Japan 2 Switzerland 1 United Kingdom 5 United States 14 Global 310

Portail Substances Chimiques

Tel: --
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Email: webmestre-substances@ineris.fr
Country: France
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Advantage: 58

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View Lastest Price from 2,2-Bis[4-(4-aminophenoxy)phenyl]propane manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline 13080-86-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-24

Henan Research New Materials Co., Ltd.

Product: 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline 13080-86-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1000000KG
Release date: 2021-05-20

Shanghai Daken Advanced Materials Co.,Ltd

Product: 2,2'-Bis(4-aminophenoxyphenyl)propane(BAPP) 13080-86-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.00%
Supply Ability: 1500KG/month
Release date: 2021-11-01

13080-86-9, 2,2-Bis[4-(4-aminophenoxy)phenyl]propaneRelated Search:

Phenyltriethoxysilane 4-Aminobenzoic acid 4-Amino-benzenesulfonic acid monosodium salt Diphenyl ether 2,2-Dimethoxypropane Trimethoxyphenylsilane PHENYL VALERATE Phenyl salicylate Propane PHENYL RESIN Phenylacetic acid Bisphenol A 4-CUMYLPHENOL 4-AMINO-4'-TERT BUTYL DIPHENYL ETHER 4-AMINO-4'-METHYLDIPHENYL ETHER 4-Phenoxyaniline Bis[4-(4-aminophenoxy)phenyl]sulfone Diphenyl sulfone

4,4'-((Propane-2,2-diylbis(4,1-phenylene))bis(oxy))dianiline

2,2'-Di-[4-(4-aminophenyloxy)phenyl]-propane

4,4'-(4,4'-Isopropyl

2,2-Bis[4-(4-aminophenoxy)phenyl]propan

2,2-Bis[p-(4-aMinophenoxy)phenyl]propane

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline 98%

4,4'-(4,4'-isopropylidenediphenyl-1,1'-diyldioxy),BAPP

4,4’-((1-methylethylidene)bis(4,1-phenyleneoxy)bis-benzenamin

4,4’-((1-methylethylidene)bis(4,1-phenyleneoxy)bisbenzenamine)

4,4’-(4,4’-isopropylidenediphenyl-1,1’-diyldioxy)

Bisphenol A Bis(4-aminophenyl) Ether (BAPP)

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline (BAPP)

2,2'-Bis(4-aminophenoxyphenyl)propane(BAPP)

BAPP

2,2'-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE

2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE

4,4'-ISOPROPYLIDENEBIS[(4-AMINOPHENOXY)BENZENE]

4,4'-[ISOPROPYLIDENEBIS(P-PHENYLENEOXY)]DIANILINE

4,4'-(4,4'-ISOPROPYLIDENEDIPHENYL-1,1'-DIYLDIOXY)DIANILINE

2,2’-bis(4-aminophenoxyphenyl)propane

2,2'-Bis(4-[4-amonophenoxy]phenyl)propane

2,2’-Bis[4-(4-aminophenoxy)Phenyl]Propane(BAPP)

Benzenamine, 4,4'-[(1-methylethylidene) bis(4,1-phenyleneoxy)]bis-

2,2''-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE 99.0%

2,2'-Bis[4-(4-aminophenoxy)pheny]propane

4-BAPOPP

2,2-Bis[p-(p-aminophenoxy)phenyl]propane

4,4'-[2,2-Propanediylbis(4,1-phenyleneoxy)]bisaniline

4,4'-[Isopropylidenebis(1,4-phenyleneoxy)]bisaniline

4,4'-[Isopropylidenebis(p-phenyleneoxy)]bis(benzenamine)

4,4'-[Propane-2,2-diylbis(p-phenyleneoxy)]bisaniline

4,4′-(4,4′-Isopropylidenediphenyl-1,1′-diyldioxy)dianiline,2,2-Bis[4-(4-aminophenoxy)phenyl]propane

4,4’-[(1-methylethylidene)bis(4,1-phenyleneoxy)]bis-benzenamin

4,4’-[(1-methylethylidene)bis(4,1-phenyleneoxy)]bis-Benzenamine

4,4’-isopropylidenebis(4,1-phenyleneoxy)dianiline

2,2-Bis[4-(4-aminophenoxy)phenyl]propane &gt

BAPP2.2 bis (4- (4-aminophenoxy) phenyl) propane

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldi

2,2'-Bis(4-aminophenoxyphenyl) propane (BAPP)

4,4'-((Propane-2,2-diylbis(4,1-phenylene))bis(oxy))dianiline

2,2'-Bis(4-aminophenoxyphenyl) propane

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline (BAPP)

2,2'-Bis[4-(4- aMinophenoxy)phenyl]propane(BAPP)

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldi

2,2-Bis[4-(4-aminophenoxy)phenyI]propane (BAPP)

13080-86-9

CH32CC6H4OC6H4NH22

Reagent for High-Performance Polymer Research

Bisphenol A type Compounds (for High-Performance Polymer Research)

fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials

API

fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis

Organics

Miscellaneous

Bisphenol A type Compounds (for High-Performance Polymer Research)

Functional Materials

Reagent for High-Performance Polymer Research